The purpose of this study is to confirm the structural relationship between parental support, relationships with teachers, and stress variables on adolescents' mental health. Among the panel of 7,324 third-year high school students in the 8th survey in 2020 of the ‘Korean Education Longitudinal Study 2013’ conducted by the Korea Educational Development Institute, 6,054 people who participated in the survey were selected as research subjects. Frequency analysis, descriptive statistics, correlation analysis, and Bayesian structural equation model path analysis were performed using SPSS 26.0 and Amos 24.0. First, adolescents' parental support had a statistically significant positive effect on their mental health. Second, the relationship with teachers had a negative effect on stress and a positive effect on mental health. Third, it was confirmed that stress has a negative effect on the mental health of adolescents. Fourth, relationships with teachers had a positive effect on mental health with stress as a mediating variable. This study identified predictors that affect mental health at the point when adolescents' mental health problems become serious, and the research results can serve as data related to policy establishment and program operation in educational settings to improve mental health.