The purpose of this study is to clarify the effect of mountain-valley wind on heat island formed in urban area which is located around valley mouth. The meteorological observations were carried out over the Dalbi-valley under a clear summer pressure patterns, and some consideration were tried from the results. In order to make clear the climatological characteristics and air-mass modification process of the mountain-valley wind over the valley, the meteorological observations were done simultaneously at two points. The observational points were located at the breast and valley mouth parts, respectively. The results were as follows: First, it was found that the valley wind was observed through the daytime, and it was replaced by a mountain wind after sunset. Second, the heat budget is also investigated with observation data. The sensible heat flux over the breast of Dalbi-valley reached to about 200during daytime, which is a little more than one third of net radiation. On the other hand, the sensible heat flux represented negative values during nighttime. But the sensible heat flux over the valley mouth covered by asphalt showed plus value(about 20～30) during the nighttime.

The two-stage numerical model was used to study the relation between three-dimensional local wind model, advection/diffusion model of random walk method and second moment method in western coastal area for Korean peninsula. The first stage is three dimensional time-dependent local wind model which gives the wind field and vertical diffusion coefficient. The second stage is advection/diffusion model which uses the results of the first stage as input data. First, wind fields on Korean peninsula for none synoptic scale wind showed typical land and sea breeze circulation, and the emitted particles were transported by sea breeze for daytime, emissions return to sea by land breeze for nighttime.

Numerical simulations of photochemical air pollution (CBM: Carbon-Bond Mechanism) under a theoretical three-dimensional local wind system are carried to clarify the fundamental characteristics of the effects of local wind on photochemical air pollution. According to the AWS data of Pusan coastal area and KMA, the surface wind of Pusan during summertime showed a very remarkable land and sea breeze circulation. The ozone concentration distribution using local wind model showed that high ozone concentration zone near coastal area moved toward inland in the afternoon. This change implies a sea breeze increases the ozone concentration, but a land breeze decreases it in Pusan coastal area