In this study, an effervescent atomizer capable of mixing and spraying vegetable oil and kerosene at the same time was proposed to examine the usefulness of vegetable oil and kerosene in terms of recycling of renewable energy and waste resources. The effect of nozzle exit diameter variation on the atomization characteristics such as spray angle, droplet size distribution, cumulative volume distribution, and SMD was investigated using LDPA. The results of this study showed that the spray angles decreased with increasing ALR at the same nozzle exit diameter and increased with increasing nozzle exit diameter under the same ALR condition. SMD was decreased with increasing ALR at all nozzle exit diameters, and SMD was decreased with decreasing nozzle exit diameter even under the same ALR conditions. Also, the droplet was more finely atomized when the nozzle exit diameter is reduced under the same ALR conditions and when the ALR is increased at the same nozzle exit diameter, but the uniformity of the droplets was lowered because the droplet with a larger diameter existed.