Recently, with the development of ultra-precision technology, the quality improvement of optical parts and various products is emerging. The need for a difficult-to-cut material that is light and exhibits high hardness and high strength physical properties is being emphasized. Ultra-precision machining processing solutions for these difficult-to-cut materials are being actively developed. In this research, experiments were performed using a DTM machine equipped with a laser-assisted machining module for ultra-precision machining of CaF2 materials that are brittle but exhibit high transmittance in a wide range from ultraviolet to infrared.