The impact of sodium hydroxide, which is one of chemicals of clean in place (CIP) for removing membrane fouling, on the PVDF membrane is reviewed with respect to physical/chemical structural change, the permeability affected therefrom. Based on the cleaning concentration applied in membrane water treatment facilities, 10% of accumulated defluorination was confirmed up to 166g.hr/L which reflects the exposure time. However, membrane resistance was confirmed to be reduced by about 10%. Through FT-IR and EDS analysis, reduction of F and change of are confirmed as factors that affect the permeability of membrane. Membrane resistance, which affects permeability, is affected by loss of additives for hydrophilicity, rather than defluorination of PVDF material. Therefore, in order to check membrane degradation degree, an accelerated test by NaOH was carried out, loss of additives was confirmed, and then PVDF inherent characteristic was observed.
When a new bonding agent using coal ash is utilized as a substitute for cement, it has the advantages of offering a reduction in the generation of carbon dioxide and securing the initial mechanical strength such that the agent has attracted strong interest from recycling and eco-friendly construction industries. This study aims to establish the production conditions of new hardening materials using clean bottom ash and an alkali activation process to evaluate the characteristics of newly manufactured hardening materials. The alkali activator for the compression process uses a NaOH solution. This study concentrated on strength development according to the concentration of the NaOH solution, the curing temperature, and the curing time. The highest compressive strength of a compressed body appeared at 61.24MPa after curing at 60˚C for 28 days. This result indicates that a higher curing temperature is required to obtain a higher strength body. Also, the degree of geopolymerization was examined using a scanning electron microscope, revealing a micro-structure consisting of a glass-like matrix and crystalized grains. The microstructures generated from the activation reaction of sodium hydroxide were widely distributed in terms of the factors that exercise an effect on the compressive strength of the geopolymer hardening bodies. The Si/Al ratio of the geopolymer having the maximum strength was about 2.41.
This is an experimental study on manufacturing of non-cement matrix. Materials like cement and blowing agent in foamed concrete is replaced by by-products from blast furnace slag and paper ash. Sample Plain with density showed lowest. The compressive strength test result, showed a similar trend with density. And it showed that compressive strength of the 4:6 was highest.