In this study, the potential possibility of oxygenates on butyl ether(below BE) was investigated as an combustion activator for a direct injection diesel engine. It tested to estimate change of engine performance and exhaust emission characteristics for the diesel fuel and oxygenates additives blended fuel which has four kinds of blended ratio. The smoke of blended fuel(diesel fuel 80vol-%+BE 20vol-%) was reduced in comparison with diesel fuel, that is, it was reduced approximately 26%. And, power, torque and brake specific fuel consumption(BSFC) didn't have no large differences. But, NOx of BE blended fuel was increased compared with diesel fuel.