This study was tried to examine the efficacy of apples that had grown with agrochemical alternatives in an apple orchard. The chlorophyll content of apple leaves was a little higher in the plot of Charcoal powder, Chitosan, and Peat moss treatment among the other agrochemical alternatives. On the contrary, the sugar content of apple fruits was higher in the plot of Amino acids, and Green ion calcium treatment, but there was quite a difference among them. Vitamin C content of apple fruits was high at the cell division period. It became lower at the hypertrophic period and then got higher again at the harvest. Vitamin C content was the highest in the chemical fertilizer plot as well. In an apple orchard where agrochemical alternatives were used only, the commercial grade of ripened apples had declined by 25%, compared to those in customary cultivation. The commercial grade of ripened apples with agricultural chemicals using fertilizers and pesticides was over 90% with over 250g of its weight in the plot of Charcoal powder, Amino acids, and Vitamin C treatment. Therefore, we guessed the environmentfriendly method of cultivation in an apple orchard shall be established by reducing the usage of agricultural chemicals gradually and increasing the agrochemical alternatives at the same time.