Bulk graphite is manufactured using graphite scrap as the filler and phenolic resin as the binder. Graphite scrap, which is the by-product of processing the final graphite product, is pulverized and sieved by particle size. The relationship between the density and porosity is analyzed by measuring the mechanical properties of bulk graphite. The filler materials are sieved into mean particle sizes of 10.62, 23.38, 54.09, 84.29, and 126.64 μm. The bulk graphite density using the filler powder with a particle size of 54.09 μm is 1.38 g/cm3, which is the highest value in this study. The compressive strength tends to increase as the bulk graphite density increases. The highest compressive strength of 43.14 MPa is achieved with the 54.09 μm powder. The highest flexural strength of 23.08 MPa is achieved using the 10.62 μm powder, having the smallest average particle size. The compressive strength is affected by the density of bulk graphite, and the flexural strength is affected by the filler particle size of bulk graphite.
Isotropic synthetic graphite scrap and phenolic resin were mixed, and the mixed powder was formed at 300 MPa to produce a green body. New bulk graphite was produced by carbon-izing the green body at 700°C, and the bulk graphite thus produced was impregnated with resin and re-carbonized at 700°C. The bulk density of the bulk graphite was 1.29 g/cm3, and the porosity of the open pores was 29.8%. After one impregnation, the density increased to 1.44 g/cm3 while the porosity decreased to 25.2%. Differences in the pore distribution before and after impregnation were easily confirmedby observing the microstructure. In addition, by using an X-ray diffractometer, the degrees-of-alignment (Da) were obtained for one side perpendicular to the direction of compression molding of the bulk graphite (the “top-face”), and one side parallel to the direction of compression molding (the “side-face”). The anisot-ropy ratio calculated from the Da-values obtained was 1.13, which indicates comparatively good isotropy.