In this study, surface particulate matter (PM2.5) concentrations were calculated based on empirical equations using measurements of ceilometer backscatter intensities and meteorological variables taken over 19 months. To quantify the importance of meteorological conditions on the calculations of surface PM2.5 concentrations, eight different meteorological conditions were considered. For each meteorological condition, the optimal upper limit height for an integration of ceilometer backscatter intensity and coefficients for the empirical equations were determined using cross-validation processes with and without considering meteorological variables. The results showed that the optimal upper limit heights and coefficients depended heavily on the meteorological conditions, which, in turn, exhibited extensive impacts on the estimated surface PM2.5 concentrations. A comparison with the measurements of surface PM2.5 concentrations showed that the calculated surface PM2.5 concentrations exhibited better results (i.e., higher correlation coefficient and lower root mean square error) when considering meteorological variables for all eight meteorological conditions. Furthermore, applying optimal upper limit heights for different weather conditions revealed better results compared with a constant upper limit height (e.g., 150 m) that was used in previous studies. The impacts of vertical distributions of ceilometer backscatter intensities on the calculations of surface PM2.5 concentrations were also examined.