In the current concrete structure of the highway is still the major problem most of concrete deterioration caused by the freeze-thaw and de-icing salt, which is of issues that are not completely resolved. In particular, a single freezing event does not cause much harm, durability of concrete under multi-deterioration environment by repeated freeze-thaw and de-icing salt is rapidly degraded and reduce its service life. In this study, to considering environmental characteristics when design and construction of concrete structures, the exposure environmental guidelines were established by investigation the application rates of de-icing salt, temperatures and snowfall characteristics during five years (2004∼2008) by regions. Also, damage condition and chloride content of the structural at regions of moderate and severe environmental exposures were investigated.