본 논문에서는 ASTM C 1260을 이용하여 국내산 골재를 대상으로 알칼리-실리카 반응 판정 결과 반응성으로 판정된 골재를 대상으로 알칼리-실리카 반응 억제효과를 고찰하기 위하여 플라이애시와 질산리튬을 사용한 시멘트 경화체의 ASTM C 1260 적용성을 평가하였다. 알칼리-실리카 반응에 의한 팽창현상이 발생하는 지역에서 CaO 함량이 낮은 플라이애시를 시멘트 중량의 10, 20, 30%를 대체하는 경우 ASTM C 1260으로 알칼리-실리카 반응 억제효과를 확인할 수 있었다. 그러나 질산리튬을 사용할 경우는 ASTM C 1260은 시편을 1N NaOH 수용액에 수침하여 80℃의 온도로 길이변화를 유도하므로 시편내에 혼입된 질산리튬 성분이 외부로 용출될 수 있기 때문에 알칼리-실리카 반응 억제효과를 도출하지 못하였다. 따라서 질산리듐의 ASR 억제효과를 확인하기 위해서는 다른 시험방법을 고려해야 한다.
Among many types of flue gas desulfurization (FGD) facilities, wet type FGD using lime or limestone is most popular in the world because of its simplicity of operation and availability of lime and limestone. Seawater desulfurization utilizes the alkalinity of seawater, thus requires no addition of lime and limestone. The efficiency of seawater desulfurization depends on the variation of alkalinity of seawater at different locations. This study presents the effect of gas-water ratio and total alkalinity of absorbing solution on the removal efficiency of sulfur dioxide from the flue gas by means of seawater. Also this study provides an alternative way to increase total alkalinity of seawater by utilizing fly ash from coal-fired power plants. The increase of removal efficiency with increase of alkalinity was measured as 0.26 ± 0.01% per ppm of bicarbonate alkalinity from the set of experiments using seawater, underwater, and distilled water, the alkalinity of which were 111 ppm, 38 ppm, and 1 ppm, respectively. Capability to increase total alkalinity of seawater using fly ash was confirmed.
In this study, it was evaluated the carbonation properties of concrete by replacement of the flyash after it was ground by vibration mill and was modified chemically. Also, it was compared to 1day, 3day, 7day, 28day and 56day-strength of the concrete, respectively.
In this study, it was evaluated the early-strength of mock-up concrete by replacement of the flyash after it was ground by vibration mill and was modified chemically. Also, the early-strength of the specimens for maintaining structure was evaluated on the first, second, third day separately.
The blocks using flyash were prepared in this study. The characteristic of sound absorption of flyash block was investigated. It was revealed that the chemical additives and flyash played an important role to determine the characteristic of sound absorption. Chemical additive affects the capability of sound absorption while flyash affects the characteristic of sound absorption, i.e. high value of the sound absorption coefficient at the specific frequencies(1kHz and 2kHz). The flyash block showed higher sound absorption coefficient than that of the commercial concrete block having carpet on the surface. It was also shown that the sound absorption coefficient increases with increase of the content of flyash in the block. However, it was found that the 70wt% of flyash in the flyash block was the optimum content to obtain the highest sound absorption coefficient.