Nuclear weapon generates huge amount of radioactive fallout which is extremely dangerous. The fallout gradually falls to the ground and then covers every surface in city and nature. A hydrogel decontamination medium has been developed to clean the surface polluted by the fallout. The hydrogel is soluble in water so the used hydrogel can be simply removed from the surface by washing. However, significant amount of waste water, containing the radioactive fallout, is generated with this process. In this respect, it is necessary to secure alternative technical options for the used hydrogel recovery. In this study, a steam-suction process was suggested for the used hydrogel recovery. Contaminated stainless steel surface, with fixed simulated fallout particles, was prepared for test. The simulated fallout particles were obtained by high-temperature treatment of a mixture of natural soil, used concrete, and Fe2O3. The hydrogel, composed of poly-vinyl alcohol and borax, was spread onto the contaminated stainless steel surface. The hydrogel was soft at first and it gradually becomes rigid with time. The used hydrogel was recovered by suction with a simultaneous steam spraying to soften the rigid gel. As a result, the clean surface of the stainless steel without the simulated fallout particles was obtained, showing the feasibility of this technique for the used hydrogel recovery.
이 연구에서는 플라즈마 제염 기술의 실용화를 위해 , , 등의 반응성 플라즈마 기체를 이용하여 원자력 시설의 주요 오염원인 코발트 핵종에 대한 표면 제염 모의실험을 수행하였다. 디스크 형태의 금속코발트에 대하여 시편 표면 온도를 변수로 플라즈마 식각 실험을 수행한 결과 반응율은 에서 기체의 경우 그리고 와 기체의 경우 각각 과 이었으며, 이들 반응의 활성화에너지는 각각 39.4 kJ/mol, 42.1 kJ/mol, 116.0 kJ/mol이었다. 이와 함께 AES (Auger Electron Spectroscopy)를 이용하여 반응 생성물 성분 분석 결과 이들 반응의 주요 반응 기구는 코발트의 불화 반응임이 밝혀졌다. 이 연구를 통해 확보된 의 금속 표면 식각율은 주요 반도체 공정의 식각율을 뛰어넘는 높은 식각율로 플라즈마 제 염 기술의 실용화를 앞당길 수 있는 고무적인 결과라 할 수 있을 것이다.