Thermoelectric (TE) energy harvesting, which converts available thermal resources into electrical energy, is attracting significant attention, as it facilitates wireless and self-powered electronics. Recently, as demand for portable/wearable electronic devices and sensors increases, organic-inorganic TE films with polymeric matrix are being studied to realize flexible thermoelectric energy harvesters (f-TEHs). Here, we developed flexible organic-inorganic TE films with p-type Bi0.5Sb1.5Te3 powder and polymeric matrices such as poly(3,4-eethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) and poly (vinylidene fluoride) (PVDF). The fabricated TE films with a PEDOT:PSS matrix and 1 wt% of multi-walled carbon nanotube (MWCNT) exhibited a power factor value of 3.96 μW ‧ m-1 ‧ K-2 which is about 2.8 times higher than that of PVDF-based TE film. We also fabricated f-TEHs using both types of TE films and investigated the TE output performance. The f-TEH made of PEDOT:PSS-based TE films harvested the maximum load voltage of 3.4 mV, with a load current of 17.4 μA, and output power of 15.7 nW at a temperature difference of 25 K, whereas the f-TEH with PVDF-based TE films generated values of 0.6 mV, 3.3 μA, and 0.54 nW. This study will broaden the fields of the research on methods to improve TE efficiency and the development of flexible organic-inorganic TE films and f-TEH.
The purpose of this study is to compare the effects of input- and output-based planning (reading a sample passage vs. writing a draft) on the oral performance of L2 learners with low-proficiency. In this study, 16 Korean female junior college students of low English proficiency were divided into two different planning groups. The reading group was required to read a sample passage of the given topic, designed to encourage “noticing” and “focus on form” using input enhancement, while the writing group was asked to write a draft of their speech, using only their own L2 knowledge. After such planning activities, both groups recorded their assigned speaking tasks using Kakao Talk. Eight planning activities and oral performances were completed over the period of the semester. In order to compare the effects of input- and output-based planning on the improvement of overall proficiency, pre- and post-tests, in which the students produced the same narratives, were analyzed using Mann-Whitney U and Wilcoxon signed-rank tests. Furthermore, this study explored any difference in speaking performance after each type of planning and what the learners were actually doing during planning time. The results showed that output-based planning had positive effects on speaking performance and its repeated practice led to the improvement of overall proficiency.
One-dimensional (1D) piezoelectric nanostructures are attractive candidates for energy generation because of their excellent piezoelectric properties attributed to their high aspect ratios and large surface areas. Vertically grown BaTiO3 nanotube (NT) arrays on conducting substrates are intensively studied because they can be easily synthesized with excellent uniformity and anisotropic orientation. In this study, we demonstrate the synthesis of 1D BaTiO3 NT arrays on a conductive Ti substrate by electrochemical anodization and sequential hydrothermal reactions. Subsequently, we explore the effect of hydrothermal reaction conditions on the piezoelectric energy conversion efficiency of the BaTiO3 NT arrays. Vertically aligned TiO2 NT arrays, which act as the initial template, are converted into BaTiO3 NT arrays using hydrothermal reaction with various concentrations of the Ba source and reaction times. To validate the electrical output performance of the BaTiO3 NT arrays, we measure the electricity generated from each NT array packaged with a conductive metal foil and epoxy under mechanical pushings. The generated output voltage signals from the BaTiO3 NT arrays increase with increasing concentration of the Ba source and reaction time. These results provide a new strategy for fabricating advanced 1D piezoelectric nanostructures by demonstrating the correlation between hydrothermal reaction conditions and piezoelectric output performance.
Piezoelectric energy harvesting technology is attracting attention, as it can be used to convert more accessible mechanical energy resources to periodic electricity. Recent developments in the field of piezoelectric energy harvesters (PEHs) are associated with nanocomposites made from inorganic piezoelectric nanomaterials and organic elastomers. Here, we used the BaTiO3 nanoparticles and piezoelectric poly(vinylidene fluoride) (PVDF) polymeric matrix to fabricate the nanocomposites-based PEH to improve the output performance of PEHs. The piezoelectric nanocomposite is produced by dispersing the inorganic piezo-ceramic nanoparticles inside an organic piezo-polymer and subsequently spin-coat it onto a metal plate. The fabricated organic-inorganic piezoelectric nanocomposite-based PEH harvested the output voltage of ~1.5 V and current signals of ~90 nA under repeated mechanical pushings: these values are compared to those of energy devices made from non-piezoelectric polydimethylsiloxane (PDMS) elastomers and supported by a multiphysics simulation software.
구조물에 고유한 진동수,모드형태 및 감쇠비 등과 같은 동적성능치를 추출하기 위하여 25층 및 42층 건물에 대하여 자연진동에 의한 동적계측실험을 수행하였다. 고려된 건물은 주요 횡하중 지지기구로서 코아벽체 혹은 전단벽체가 추가된 철근콘크리트건물이며, 입면 혹은 평면상으로 골조가 혼합된 구조형식을 나타낸다. 특히, 25층 건물은 측면에 위치한 코아벽체 이외에 상부로부터 내려오는 전단벽 구조가 4층 바닥이하에서 골조형식으로 전환되는 복잡한 구조이다. 이와 같은 이유 및 건물 주방향의 유사한 강성배치로 매우 근접하고 혼합된 모드형태가 예상되어 시스템판별 시 어려움이 예상된다. 현재까지 개발된 다양한 시스템판별법을 대상건물의 자연진동 실측기록에 적용하여 모달계수를 유도하였으며, 그 결과를 비교 분석하였다. 3개의 주파수영역 및 4개의 시간영역에 근거한 응답의존 시스템판별법이 고려되었다. 서로 다른 시스템판별법에 의하여 추출된 고유진동수 및 감쇠비는 대체로 상당한 일치를 보였으나, 모드형태는 사용된 방법에 따라 정도가 다르게 불일치를 나타냈다. 실험으로부터 추출한 성능치와 초기 유한요소해석 값을 비교해 본 결과 대상건물 모두 적어도 저차 3개의 고유진동수에서 2배 정도의 차이를 나타냈다. 실험과 해석결과의 일치를 위하여 몇몇 수동모델향상이 시도되었으며, 허용할 만한 결과를 획득하였다. 사용된 시스템판별법에 대하여 각자의 장, 단점에 대하여 기술하였으며, 본 연구와 같은 실제 대형구조물에 대하여 자동모델향상기법을 적용할 시 예상되는 문제점에 대하여 토의하였다.
Enterprise informatization is a complex system made of management philosophy, management methods and information technology. According to Porter's valuechain thinking, enterprise informatization actually builds the foundation platform for the primary activities and secondary activities that create business value. Therefore, performance of enterprise informatization has characteristics of integrity, indirection, long-term and so on. This paper, based the enterprise informatization performance has the charac on the value evaluation and from the input-output process perspective, sets cognitive variables to systematically descript input and output of enterprise informatization and builds a class of cognitive performance evaluation model. The empirical studies have shown that the model can describe the performance of enterprise informatization systematically and provide the quantitative evidence for enterprise informatization management.