Carbon-coated TiO2 was prepared by CCl4 solvent mixing method with the different heat treated temperatures (HTTs). Since the carbon layers derived from pitch on the TiO2 particles were porous, the carbon-coated TiO2 sample series showed a good adsorptivity. The values of BET surface areas measured were shown independently on the HTTs. The surface states by SEM present to the characterization of porous texture on the carbon-coated TiO2 sample and carbon distributions on the surfaces. From XRD data, PT700 and PT750 were shown the X-ray diffraction patterns of the anatase TiO2, but PT800 and PT850 were kept anatase-type structure even after heating at 800℃, though small amount of the rutile-type structure appears. The results of EDX microanalyses were observed for each sample show the spectra corresponding to almost all samples similar to C, O and Ti elements with an increase of HTTs. Finally, the excellent photoactivity of carbon-coated TiO2 (especially, PT700 and PT750) could be attributed to the homogeneous coated carbon on the external surface and the structural anatase phase.