수질모델은 수계내 오염물질의 총량관리를 위한 오염물질관리 목표량 및 허용총량 파악, 그리고 삭감계획의 효과분석 등에 효율적으로 사용할 수 있다. 그러나 선정 또는 개발된 모델의 재현성 제고를 위하여 매개변수의 최적화작업이 필요하다. 본 연구에서는 하천수질관리에 가장 광범위하게 사용되고 있는 미국 EPA에서 개발한 QUAL2E 모델의 반응계수 보정을 위하여 최소자승법을 적용하였으며, 계수가 취할 수 있는 범위를 제약조건으로 갖는 최적화모델을 구축하여 해를

The Keum river is one of the important river in Korea and has a drainage area of 9,873 ㎦. The Keum river is deepening pollution state due to development of the lower city and construction of a industrial complex. The water quality of the Keum river come to eutrophication state and belong to Ⅲ grade of water quality standard. The concentration BOD in river is affected by the organic loading from a tributary and the algae biomass that largely happen to under eutrophication state. In the eutrophic water mass such as the Keum river, the autochthonous BOD was very important part for making a decision of water quality management, because it was accounted for majority of the total BOD. The purpose of this study was to survey the characteristics of water quality in summer and to estimate reaction coefficient. Also, we studied to correlationship between chlorophyll a and BOD(COD) for estimation of the autochthonous BOD. The correlationship between chlorophyll a and BOD(COD) were obtained through the culture experiment of phytoplankton in the laboratory. The results of this study may be summarized as follows ; The characteristics of water quality in summer were belong to Ⅲ∼Ⅳgrade of water quality standard as BOD and nutritive condition is very high. The BOD, ammonia nitrogen and phosphate loadings in Miho stream which inflowing untreated sewage from Chungju city was occupied with 64.07%, 26.36%, 46.08%, respectively. Maximum nutrient uptake (Vmax) was 0.4400 μM/hr as substrate of ammonia nitrogen, 0.1652 μM/hr as substrate of phosphate. Maximum specific growth rate (μmax) was 1.2525 hr-1 as substrate of ammonia nitrogen, 1.5177 hr-1 as substrate of phosphate. The correlation coefficient between chlorophyll a and BOD by the culture experiment were found to be 0.911∼0.935 and 0.942∼0.947 in the case adding nutrient and no adding nutrient, respectively. The correlation coefficient between chlorophyll a and COD through the culture experiment were found to be 0.918∼0.977 and 0.880∼0.931 in the case adding nutrient and no adding nutrient, respectively. The autochthonous BOD(COD) was estimated to the relationship between BOD(COD) and chlorophyll a. The regression equation were found to be autochthonous BOD=(0.045∼0.073)×chlorophyll a and autochthonous COD=(0.137∼0.182)×chlorophyll a.

The Keum river has been utilized for drinking water supply of several city including Kunsan city and is deepening pollution state due to numerous municipal and industrial discharges. The concentration BOD in river is affected by the organic loading from a tributary and the algae biomass that largely happen to under eutrophication state. In the eutrophic water mass such as the Keum river, the autochthonous BOD was very important part for making a decision of water quality management, because it was accounted for majority of the total BOD. The predict of water quality has important meaning for management of water quality pollution of the Keum river. The purpose of this study will manage and predict water quality of the Keum river using QUAL-2E model considering the autochthonous BOD. The estimation of autochthonous BOD represented that the relationship between BOD and chlorophyll a. The regression equation was shown to be autochthonous BOD=β5×chlorophyll a. The results of this study may be summarized as followed; The QUAL-2E model was calibrated with the data surveyed in the field of the study area in June, 1998. The calculated value by QUAL-2E model are in good agree to measured value within relative error of 7.80∼20.33%. Especially, in the case of the considering autochthonous BOD, the calculated value of BOD were fairly good coincided with the observed values within relative error of 15%. But the case of not considering autochthonous BOD, relative error of BOD was shown to be 43.2%. In order to attain Ⅱ grade of water quality standard in Puyo station which has a intake facility of water supply, we reduced to the pollutants loading of tributaries. In the case of removed 100% BOD of tributaries, the BOD of Puyo station was 4.07㎎/ℓ, belong to Ⅲ grade of water quality standard. But in the case of removed 88% nutrient of tributaries, it was satisfied to Ⅱ grade of water quality standard as below 3㎎/ℓof BOD. For estimation of autochthonous BOD in Keum river, we are performed simulating in accordance with reduction of nutrient load(50∼100%) under conditions removal 90% organic load. Occupancy of autochthonous BOD according to nutrient loading reductions were varied from 25.97∼79.51%. Occupancy of autochthonous BOD was shown to be a tendency to increasing in accordance with reduction of nutrient loading. Showing the above results, the nutrient that one of the growing factor of algae was important role in decision of BOD in the Keum river. For the water quality management of the Keum river, therefore, it is necessary to considering autochthonous BOD and to construction of advanced sewage treatment plant for nutrient removal.