This study developed prediction models of chlorine bulk decay coefficient by each condition of water quality, measuring chlorine bulk decay coefficients of the water and water quality by water purification processes. The second-reaction order of chlorine were selected as the optimal reaction order of research area because the decay of chlorine was best represented. Chlorine bulk decay coefficients of the water in conventional processes, advanced processes before rechlorination was respectively 5.9072 (mg/L)-1d-1 and 3.3974 (mg/L)-1d-1, and 1.2522 (mg/L)-1d-1 and 1.1998 (mg/L)-1d-1 after rechlorination. As a result, the reduction of organic material concentration during the retention time has greatly changed the chlorine bulk decay coefficient. All the coefficients of determination were higher than 0.8 in the developed models of the chlorine bulk decay coefficient, considering the drawn chlorine bulk decay coefficient and several parameters of water quality and statistically significant. Thus, it was judged that models that could express the actual values, properly were developed. In the meantime, the chlorine bulk decay coefficient was in proportion to the initial residual chlorine concentration and the concentration of rechlorination; however, it may greatly vary depending on rechlorination. Thus, it is judged that it is necessary to set a plan for the management of residual chlorine concentration after experimentally assessing this change, utilizing the methodology proposed in this study in the actual fields. The prediction models in this study would simulate the reduction of residual chlorine concentration according to the conditions of the operation of water purification plants and the introduction of rechlorination facilities, more reasonably considering water purification process and the time of chlorination. In addition, utilizing the prediction models, the reduction of residual chlorine concentration in the supply areas can be predicted, and it is judged that this can be utilized in setting plans for the management of residual chlorine concentration.

Three water treatment plants(WTPs) in Jeju island whose source water have different characteristics from those of the mainland of Korea were investigated. Coefficients of bulk water decay(kb ) of free chlorine at 5 ଌ for ES, GJ, NW WTPs were -0.003 hr -1, -0.002 hr -1 and −0.001 hr -1 respectively based on bottle tests.To simulate the free chlorine variations in the distribution system using EPANET, ES WTP was chosen. Free chlorine concentrations of several sites were less than the drinking water quality standards(i.e., 0.1 mg/L); E5(0.03 mg/L), E6(0.02 mg/L), W21(0.02 mg/L) and W25(0.03 mg/L). To maintain more than 0.1 mg/L of free chlorine in the distribution system, at least 1.9 mg/L of chlorine was needed at the WTP, which suggested rechlorination was needed to supply palatable tap water to customers.Two sites, one that diverged into E5 and E6 in the east-line and another located before E21 in the west-line were selected for the appropriate rechlorination locations. The recommended rechlorination dosages were 0.42 mg/L for the east and 0.27 mg/L for the west. The simulated results indicated that the free chlorine could be reduced to 0.4 mg/L at the WTP with rechlorination, and taps with excessive free chlorine could be more stabilized(i.e., 0.1 ~0.4 mg/L).