Modularization is an important benefit to overall project cost, such as construction period, manpower and logistics. In order to establish a successful modularization strategy, the optimum cost can be realized based on the Envelope Size which is allowed to be transferred to the plant site through analysis of each shape of the module. Through the analysis of the plant structure, the Envelope Size that can be transported on site in units of sizes suitable for maritime and onshore is provided, and finite element method is applied to the existing materials (A36, A572) and domestic materials (SS400, SM490, SWH400) and analyzed the results of the analysis to obtain domestic materials applicable to the plant structure frame.