In this paper, the performance evaluation of Al-graphene nanoplatelets (GNP) composites surface engineered by a modified friction stir processing (FSP) is reported. Here, multiple micro channels (MCRF) are used to incorporate GNPs in the aluminium matrix instead of a single large groove (SCRF) that is usually used in conventional FSP. With the MCRF approach, ~ 18% higher peak temperature (compared to SCRF) was observed owing to the presence of aluminium sandwiched between consecutive microgrooves and higher heat accumulation in the stir zone. The MCRF approach have significantly reduced the coefficient of friction and wear rates of the processed composites by ~ 14% and ~ 57%, respectively as compared to the SCRF approach. The proposed reinforcement filling method significantly improves the particle dispersion in the matrix, which in turn changes the adhesion mode of wear in SCRF to abrasive mode in MCRF fabricated composites. The uniformly squeezed out GNP tribolayer prevented the direct metal to metal contact between composite and its counterpart which have effectively reduced the deterioration rates.
Multi-walled carbon nanotube (MWCNT)/polycarbonate (PC) nanocomposite was prepared by direct melt mixing to investigate the effect of the shear rate on the surface resistivity of the nanocomposites. In this study, an experiment was carried out to observe the shear induced orientation of the MWCNT in the polymer matrix using a very simple melt flow indexer with various loads. The compression-molded, should be eliminated. MWCNT/PC nanocomposite sample exhibited lower percolation thresholds (at 0.8 vol%) and higher electrical conductivity values than those of samples extruded by capillary and injection molding. Shear induced orientation of MWCNT was observed via scanning electron microscopy, in the direction of flow in a PC matrix during the extrusion process. The surface resistivity rose with increasing shear rate, because of the breakdown of the network junctions between MWCNTs. For real applications such as injection molding and the extrusion process, the amount of the MWCNT in the composite should be carefully selected to adjust the electrical conductivity.
In this work, the effect of aminized multi-walled carbon nanotubes (NH-MWNTs) on the mechanical interfacial properties of epoxy nanocomposites was investigated by means of fracture toughness, critical stress intensity factor (KIC), and impact strength testing, and their morphology was examined by scanning electron microscope (SEM). It was found that the incorporation of amine groups onto MWNTs was confirmed by the FT-IR and Raman spectra. The mechanical interfacial properties of the epoxy nanocomposites were remarkably improved with increasing the NH-MWNT content. It was probably attributed to the strong physical interaction between amine groups of NH-MWNTs and epoxide groups of epoxy resins. The SEM micrographs showed that NH-MWNTs were uniformly embed and bonded with epoxy resins, resulted in the prevention of the deformation and crack propagation in the NH-MWNTs/epoxy nanocomposites.