고형분 70% 아크릴수지를 합성하기 위해 n-butyl methacrylate(BMA), methyl methacrylate(MMA), 2-hydroxyethyl methacrylate(2-HEMA) 및 acetoacetoxyethyl acrylate(AAEA)와 caprolactone acrylate(CLA)를 사용하여 공중합체의 유리전이온도(Tg)를 50 ℃로 조정하여 합성하였으며, 합성한 아크릴수지의 점도와 분자량은 수산기가(OH values)의 증가에 따라 증가되었다. 높은 고형분의 아크릴수지 합성에 적합한 반응개시제는 di-tert-amyl peroxide 이었으며, 최적의 합성조건은 반응 개시제 5 wt%, 연쇄이동제 4 wt%, 반응온도 140 ℃에서 적하시간은 4시간이었다. 합성수지의 구조는 FT-IR과 1H-NMR spectroscopy로 확인하였고, 수평균 분자량은 1900~2600, 분자량 분포도 1.4~2.1을 얻었다. 합성한 아크릴수지와 무황변성 폴리이소시아네이트인 hexamethylene diisocyanate trimer(Desmodur N-3300)의 NCO/OH 당량비를 1.2/1.0으로 조절하여 아크릴-우레탄 투명도료를 제조하였다. 도료의 물리적 특성으로 점도, 부착성, 건조시간, 가사시간, 연필경도 및 광택을 비교 검토한 결과 부착성, 건조시간, 가사시간, 연필경도 및 광택이 양호한 결과를 나타내었고, 특히 CLA를 10 % 도입한 도료는 부착성이 우수하고 낮은 점도와 높은 경도를 나타내었다.

The physical properties of sidewalk pavement material made by combining rectangular chips with urethane resin were reviewed through both an indoor test and an on-site test. To obtain the chips, forest tree by-products were crushed and then passed through a 10mm sieve. The materials that remained in the 2.36 mm sieve are the above mentioned chips. For the indoor test, the mixing ratios of urethane resin to chips, by mass, were set as 30%, 40%, 50%, 75% and 100%, respectively. Then, the mixture obtained by mixing with forced mixing type mixer was formed in an iron mold. Tests for tensile strength, elasticity and permeability coefficient were performed 7 days after forming. For the on-site test, the cross-section of the sidewalk pavement material consisted of sand filter layer, crushed stone subbase, permeable concrete base and surface layer of the forest tree chip mixture. For the surface layer, the mass ratios of urethane resin to the forest tree chip were determined to be 40%, 60% and 80%, respectively. The physical property test like the one performed in the indoor test and the skid resistance test was performed over 7 days after the completion of trial construction. According to the result of the tests, the tensile strength, GB/SB coefficients and permeability coefficient were 0.1 to 0.7MPa, 15 to 43% and 0.3 to 0.5mm/sec, respectively, depending on the mixing ratio. In addition, the skid resistance coefficient was 75BPN with the mass ratio of the urethane resin to the forest tree chips of 80%. Furthermore, it was found through the on-site test that a pavement surface with excellent surface smoothness could be obtained through the application of a construction method using an electric heat roller. It was also confirmed that the mixing ratio of urethane resin to forest trees chips needed to be 60% or more.