Volatile organic compounds (VOCs) emitted from industrial gas cause equipment failure and fire accidents due to the rapid flow and concentration changes of VOCs. Therefore, it is crucial to attenuate the concentration of VOCs to ensure a constant emission rate before the control process. This study proposed an encapsulation technique to fabricate calcium- alginate gel beads containing paraffin oil as an effective absorbent. The prepared absorbent was physically characterized, and a column test observed its absorption capacity. When the oil content was 30%, the prepared beads showed the best spherical shape, attaining 96% emulsion stability, 0.014 sphericity factor, 62.7% weight variation ratio, and 4.21 ± 0.06mm diameter. In the column test that was packed with the prepared beads, the toluene absorption capacity was 497.6mg/kg. The net effect of the beads was to attenuate the peaks of toluene concentration, and to make the VOC-laden air stream more receptive for the subsequent treatment unit.