nanopowder has been synthesized by means of the flame method using a precursor of titanium tetraisopropoxide (TTIP, Ti. In order to clarify the effect of cooling rate of hot flame on the formation of crystalline phases, the flame was controlled by varying the mixing ratio and the flow rate of gases. Anatase phase was predominantly synthesized under the condition having the steep cooling gradient in flame, while a slow cooling gradient enabled to form almost rutile nanopowder of above 95%