This study was conducted in autumn to determine phosphorus (P) fraction in sediments of Daechung Lake, to elucidate controlling factors for sedimentary P, and to compare with the other areas. For this study, sediment samples were collected at 6 sites only once on November 2014 using ponar grab and analyzed for solid-phase P (Loosely adsorbed, Fe-bound, Al-bound, detrital apatite, and refractory organic P) by sequential extraction. Total phosphorus (TP) was relatively high in front of Daechung Dam and Hoinam where fish farm was run until 1997. The dominant sedimentary P form was Al-bound P, followed by Fe-bound P, which could be released from sediment to water column during suboxic state. Based on principal component analysis, Al-bound P, Fe-bound, and TP were controlled by grain size of sediments. Loosely adsorbed, detrital apatite, and refractory organic P were relatively highly accumulated at the mouth of major tributaries where suspended sediments were delivered. Sedimentary P concentrations in Daechung Lake sediments were not higher than in other lake sediments. Therefore, based on these results, major controlling factors were grain size and input of suspended sediments from tributaries.

This study was investigated to improve the phosphorus release and water quality by transformation of sedimentary P fraction for application of CaO2. For the experiment, 0.5% (w/w) of CaO2 was homogenized in the sediment and incubated with the control for 20 days. The analytical results showed that pH increased with CaO2 and redox potential (ORP) was improved in the sediment of the reactor. The growth rate of chlorophyll-a was lower in the CaO2 reactor and Dissolved Oxygen (DO) of overlying water maintained higher than that of the control. Total phosphorus (T-P) concentration in the overlying water increased from the initial concentration to 0.304mg/L in the control at 20 days. The reactor of CaO2 was lowered by 29.3%. Ex-P, Fe-P and Ca-P in sediment P fraction were increased with the CaO2. The formation of bound Fe-P and Ca-P in the sediments seemed to control the release of P by removing the Soluble Reactive Phosphorus (SRP) presented in the pore water. From the result, this indicated that the reduction of P release from the sediments seems to be effective in suppressing the eutrophication of P and improving the oxygen condition in the water quality with the application of CaO2.

Extensive land subsidence and submergence occurred in the coal mining areas (Huainan and Huaibei) in Anhui Province, China. As a result, lots of subsided lakes have been formed due to their unique geological features. Four typical lakes were selected to evaluate the internal phosphorus (P) releasing risk based on the specification of P, Fe and Al from the sediments. Sediment P, Fe and Al in the top 5 cm were extracted sequentially, aiming at obtained fractionation for environmental indicators. Experiments of P isothermal adsorption were conducted to characterize P sorption ability. The results suggested that P internal loading potential was related to Al and Fe compounds in sedimentary environments of soil inundation, primarily determined by regional soil properties. Internal P releasing risk was mainly controlled by the properties of calcareous soils in the Huaibei; whereas controlled by Fe and Al in the Huainan. Overall, the obtained results fit well with the model proposed by Kopáček et al.(2005), which predicted low P flux as molar ratio of [NH4Cl-Al + BD-Al + NaOH-Al] : [NH4Cl-Fe + BD-Fe] >3 or [NaOH-Al] : [NH4Cl-P + BD-P] >25 from sediments when anoxia is developed. However, this threshold has site-specific flexibility, with its lower limit approaching 20:1 applicable for the three lakes in Huainan. Higher loads of external input organic matters or enriched Fe oxides bound P tend to change this limit and lead to internal loading risk with environmental anoxia.