Biodegradable polybutylene succinate(PBS) is an environment friendly plastics for fisheries, because it can mitigate the ghost fishing problem caused by gill-net and trap fisheries. To evaluate photodegradability of PBS monofilament in comparison with polyamide(PA) and polyethylene(PE) monofilament, these 3 types of monofilaments were spun and exposed to ultraviolet light(UV) of weather-ometer for 900 hours, and then their modification, crystal structure, strength, and extensibility were analysed. PBS monofilament did not show any crack and maintained its crystal structure after 900 hour exposure to UV whereas PE monofilament began showing cracks and structure modification after 600 hour exposure. Under UV exposure, the strength and extensibility decreased more rapidly in PBS than in PA and PE. We estimate that gill nets made of PBS monofilament can endure for about 1 year. The breaking strength and elongation decreased linearly with the exposure time for the 3 types of monofilaments. The derived regression equations of the residual tenacity(RT, kg/mm2) and the residual extensibility(RE, %) with the exposure time in year(Y) for each monofilament were; PBS : RT=48.598 - 8.6437Y(R2=0.93), RE=28.165 - 7.3233Y(R2=0.98), P A : RT=59.771 - 8.6437Y(R2=0.98), RE=32.198 - 5.2772Y(R2=0.92), P E : RT=60.898 - 5.6528Y(R2=0.98), RE=11.887 - 0.7188Y(R2=0.98).
Three different weather-resistant coatings were fabricated with the various weight ratios of a mill-base silicone/acrylic resin to let-down silicone /acrylic resin at 2:8, 3:7, and 4:6 respectively. The prepared coatings were tested to investigate the effect of composition of weather-resistant coatings on the physical properties. The thermal stability, salt spray exposure, and weather-resistance were improved with the increased silicone content. It was concluded that the optimum retio of mill-base silicone/acrylic resin to let-down silicone/acrylic resin would be 2:8 and the coating with 30 wt% of silicone content would have high weather-resistance.
In this study, degradation due to the durability of the coating to reduce the check for to determine the deterioration of the durability coating was in parallel to outdoor exposure test and the salt spray test on the marine environment. weatherability paint coating was electrochemical measured using EIS (Electrochemical Impedance Spectroscopy) to evaluate durability. The purpose of the study was to compare the reduced durability of the paint coating.