간행물

한국방사성폐기물학회 학술논문요약집 Abstracts of Proceedings of the Korean Radioactive Wasts Society

권호리스트/논문검색
이 간행물 논문 검색

권호

2022 추계학술논문요약집 (2022년 10월) 359

101.
2022.10 구독 인증기관·개인회원 무료
The depth of geological disposal of high-level radioactive waste (HLW) varies from country to country, but it is generally considered below 300 m underground. As one of the reliable methods to understand the geological characteristics of these deep areas, the site investigation through drilling is recommended. This paper deals with multidisciplinary research that evaluates the geological characteristics of the site using deep drilling. The deep drilling is 750 m, which is higher than the planned disposal depth. Prior to drilling, literature and surface geological surveys of the target area were conducted, and during drilling, real-time measurement of excavated information for obtaining drilling information, circulating water management and chemical composition through a closed system were monitored. After drilling, field tests such as geophysical borehole logging, deep groundwater sampling, constant pressure injection test, and hydraulic fracturing test were performed. Analysis of the recovered drilling core from a geological point of view such as age dating, rock formation and structural geological analysis, and from geochemical perspectives such as concentration of major/ minor cationic elements, major anions, and trace elements along with the water quality parameters pH, DO, Ec, Eh, etc., from geothermal perspective such as thermal conductivity and coefficient of thermal expansion, from rock mechanical aspects such as physical and mechanical properties of intact rocks and joints, joint distribution, etc. Deep drilling has been completed with 2 holes for granite and 2 holes for sedimentary rocks, and further drilling for gneiss and sedimentary rocks is in progress.
102.
2022.10 구독 인증기관·개인회원 무료
The deep geological disposal system is aimed to permanently isolate the high-level radioactive waste from the biosphere through a multi-barrier system composed of engineered and natural barriers. The buffer material used for the engineered barrier should have the performance to prevent and retard the migration of radionuclides to the outside of the deep disposal facility when radionuclides are released from a disposal canister by infiltration of groundwater after a long period of time. When the hydraulic conductivity of compacted bentonite is sufficiently low, the migration of radionuclides released into the surrounding rock can be significantly reduced since they are sorbed to bentonite during the diffusion process. Therefore, an investigation on diffusion of radionuclides in compacted bentonite is a fundamental task to obtain essential data for the safety assessment of the deep geological disposal system. The migration of radionuclides by diffusion can be evaluated by diffusion coefficient. In order to obtain the apparent diffusion coefficients of Sr, Sm, and Eu in compacted Ca-bentonite (1.6 g/cm3) a through-diffusion experiment have been carrying out. A cylindrical apparatus consists of a source cell with an appropriate concentration of radionuclides and diffusion cell filled with radionuclide free solution where the concentration is gradually increased by diffusion of radionuclides. The compacted bentonite was installed between the both cells. The sample used for the experiment is a Ca-type bentonite named Bentonil-WRK, and the diffusion experiment was performed under an oxidizing condition using a synthetic groundwater simulating KURT groundwater composition. The diffusion experiment will be terminated when an increasing rate of concentration of nuclides in the diffusion cell becomes constant over time. The concentration change with regard to the geochemical characteristic of the nuclide may appear to be apparently slow.In this study, the experimental results of the through-diffusion test of Sr, Sm, and Eu in the initial stage (~4 months) were presented. Through the results of the initial stage, the period of the through-diffusion experiment can be rearranged and also it is expected that the initial results provide the qualitative and quantitative diffusion properties of each nuclide.
103.
2022.10 구독 인증기관·개인회원 무료
With the increase of temporarily-stored radioactive waste in Korea, the disposal of radioactive waste in a deep geological repository, which is located in crystalline rock at a depth of hundreds of meters below the ground level, has received great attention nowadays. To ensure the permanent isolation of radionuclides from the human and surrounding ecosystems, the safety assessment for the high-level radioactive waste disposal facilities is essential. For the reliable safety assessment of fractured rock, it is especially important to input proper hydraulic properties of fractures such as aperture and hydraulic conductivity, which can directly affect the fluid flow and radionuclide transport. Meanwhile, it has become important to consider sudden fault behavior caused by an earthquake with the recent occurrence of high-intensity earthquakes in the Korean Peninsula. The sudden fault behavior can induce the changes of the hydraulic properties of fractures. Since the changes of the hydraulic properties directly affects to the radionuclide transport in the fractured rock, it is important to estimate the effect of earthquake-induced stress change on hydraulic properties of fractures in the perspective of long-term safety assessment. In this study, the effect of an earthquake on the hydraulic properties of fractures was explored by a numerical approach. The static Coulomb stress change after the earthquake was calculated using software ‘Coulomb 3’ developed by United States Geological Survey (USGS) with the assumption for several mechanical properties such as Young’s modulus, Poisson’s ratio and effective coefficient of friction. The final stress after earthquake occurrence was calculated as the sum of the initial stress and the stress change. Thereafter, the normalized transmissivity of fracture after the earthquake was calculated using the final stress from the stress-transmissivity relationship. Using the methodology for calculating fracture transmissivity change induced by the earthquake developed in this study, the effect of several factors, such as the earthquake magnitude and the distance between fracture and epicenter, was additionally explored. The newly developed methodology will be applied to the processbased total system performance assessment framework (APro) being developed by KAERI, and this study is expected to be helpful for the safety assessment considering long-term evolution phenomena including earthquakes.
104.
2022.10 구독 인증기관·개인회원 무료
For safety assessment of a high-level radioactive waste disposal system, it is important to predict and analyze the coupled thermo-hydro-mechanical (THM) behaviors of bentonite, which is a buffer candidate material in the engineered barrier system. The Barcelona Basic Model (BBM) is a constitutive model to describe the geomechanical behaviors of partially saturated soils. Complicated tests are required to directly measure BBM parameters of bentonite. In this study, we demonstrate that probable BBM parameters can be sought by calibrating the BBM parameters to match simulation results to observed ones for two kinds of simple tests (swelling pressure test and free swelling test) instead of the complicated direct tests. In the swelling pressure test and free swelling test that were conducted by Japan Atomic Energy Agency (JAEA), water was injected into constrained and unconstrained bentonite core samples, and then swelling pressure and displacements were measured, respectively. We find optimal BBM parameters using a quasi-Newton optimization method that reproduce the observed swelling pressures and displacements in hydro-mechanical simulations. The optimal BBM parameters that are sought in the inversion process can be used to predict the THM behaviors of bentonite barriers in a high-level radioactive waste disposal system.
105.
2022.10 구독 인증기관·개인회원 무료
Recently, the deep geological disposal system isolating a spent nuclear fuel (SNF) is considered a disposal method of high-level radioactive waste for the safety of humans or the natural environment. The one of important requirements for maintaining the thermal stability of these systems is that the temperature of the buffer does not exceed 100°C even though the decay heat is emitted from highlevel radioactive wastes loaded in the disposal container. In 2007, a deep geological disposal system based on the Swedish disposal concept was developed for the SNF in Korea. To respond to the development process, the thermal stability of the deep geological disposal system developed for the disposal of domestic pressurized light water reactor (PWR) SNFs with discharged burn-up of 55 GWD/MTU was evaluated in 2019. The thing is that the recent fuel activity is pursuing to operate further high burn-up fuel conditions, and it leads to emergency core cooling system (ECCS) revision for extending the license for up to 60 or more than 60 GWD/MTU in the world. In this regard, this study evaluates numerically the thermal stability of the deep geological disposal system for the high burn-up PWR SNF having large decay heat compared to previous conditions for two different length disposal containers classified according to the length of PWR SNFs discharged from domestic nuclear power plants. A finite element analysis using a computational program was used to evaluate the thermal design requirements. Results show that both types of disposal containers would increase the temperature which reduces or fails to meet the safety margin of the disposal system. This study suggests that the design of the previous disposal system is needed to be further developed for the high burn-up PWR SNF which would be used in future nuclear power plant systems.
106.
2022.10 구독 인증기관·개인회원 무료
The structural integrity of concrete silos is important from the perspective of long-term operation of radioactive waste repository. Recently, the application of acoustic emission (AE) is considered as a promising technology for the systematic real-time health monitoring of concrete-like brittle material. In this study, the characteristics of AE wave propagation through concrete silo of Gyeongju radioactive waste repository were evaluated under the effects of groundwater and temperature for the quantitative damage assessment. The attenuation coefficients and absolute energies of AE waves were measured for the temperature cases of 15, 45, 75°C under dry and saturated concrete specimens, which were manufactured based on the concrete mix same as that of Gyeongju concrete silo. The geometric spreading and material loss were taken into account with regard to the wave attenuation coefficient. The attenuation coefficient shows a decreasing pattern with temperature rise for both dry and saturated specimens. The AE waves in saturated condition attenuate faster than those in dry condition. It is found that the effect of water content has a greater impact on the wave attenuation than the temperature. The results from this study will be used as valuable information for estimating the quantitative damage at the location micro-cracks are generated rather than the AE sensor location.
107.
2022.10 구독 인증기관·개인회원 무료
Uranium (U) is hazardous material can cause chemical and radiological toxicity, e.g., kidney toxicity and health effects associated with radiation. In Korea, where shallow weathered granitic aquifers are ubiquitous, several previous studies have reported high level of radioactivity in shallow groundwater. This eventually led to the closure of 60 out of 4,140 groundwater production wells in South Korea. Here, we examined aquifers currently dedicated for drinking water supply and investigated the 11,225 dataset of 103 environmental parameters. This dataset includes 80 physical parameters associated with the hydraulic system and 23 chemical parameters associated with waterrock interactions. Among hydraulic parameters, coarse loamy texture in subsoil displayed a notable relation with U concentration level, implied it is controlling the leaching of U from host rocks. Fluorine (F), is one of major products from water-rock interaction in granitic aquifer, exhibited high correlation with U concentration distribution. Positive relation of F concentration with uranium level suggested the dissolved U originated from groundwater interacted with granites. Conclusively, we found that infiltration capacity of soil layers and (2) aqueous speciation in groundwater formulated by interaction of groundwater with local solids, played important role for U concentration in granitic aquifer.
108.
2022.10 구독 인증기관·개인회원 무료
Time-resolved laser fluorescence spectroscopy (TRLFS) and excitation-emission matrix (EEM) spectroscopy were used to study the interaction of U(VI) and natural organic matters (NOMs) in groundwater. Various types of groundwaters (DB-1, DB-3 from KURT site and OB-1, OB-3 from a U deposit in Ogcheon metamorphic belt) were used as samples. Pulsed Nd-YAG laser at 266 nm (Continuum Minilite) was used as the light source of TRLFS. The laser pulse energy of 1.0 mJ was fixed for all measurements. The luminescence spectrum was recorded using a gated intensified chargecoupled device (Andor, DH-720/18U03 iStar 720D) attached to the spectrograph (Andor, SR-303i). EEM spectra were measured using a spectrofluorometer (Horiba Scientific, Aqualog) equipped with a 150 W ozone-free xenon arc lamp. Excitation spectra were recorded by scanning the excitation wavelength from 200 to 500 nm. Emission spectra were measured using a CCD in the wavelength range of 242–823 nm. In the case of the recently collected DB-1 samples, it was observed that the U and NOM quantities decreased compared to the samples collected before 2016. For some DB-1 samples, the amount of dissolved organic carbon indicating the presence of NOM was significantly reduced, and changes consistent with this phenomenon were observed in the EEM spectrum. The time-resolved luminescence characteristics (peak wavelengths and lifetime) of U(VI) in the DB-1 samples agree well with those of Ca2UO2(CO3)3(aq). This U(VI) species remains stable, even in samples taken five years ago. The estimated amounts of U and NOM from the spectroscopic data of DB-3, OB-1, and OB-3 samples are relatively low compared to DB-1 samples. When a known amount of U(VI) was mixed in each groundwater, the time-resolved luminescence spectrum exhibited a characteristic spectral shape different from the expected luminescence intensity. This phenomenon is presumed to be due to the interaction between U(VI) and NOM in groundwater. The results of this study suggest that the chemical speciation of NOM as well as U(VI) is required to understand U behavior in groundwater.
109.
2022.10 구독 인증기관·개인회원 무료
Spent nuclear fuel (SNF) is the main source of high-level radioactive wastes (HLWs), which contains approximately 96% of uranium (U). For the safe disposal of the HLWs, the SNF is packed in canisters of cast iron and copper, and then is emplaced within 500 m of host rock surrounded by compacted bentonite clay buffer for at least 100,000 years. However, in case of the failure of the multi-barrier disposal system, U might be migrated through the rock fractures and groundwater, eventually, it could reach to the biosphere. Since the dissolved U interacts with indigenous bacteria under natural and engineered environments over the long storage periods of geologic disposal, it is important to understand the characteristics of U-microbe interactions under the geochemical conditions. In particular, a few of bacteria, i.e., sulfate-reducing bacteria (SRB), are able to reduce soluble U(VI) into insoluble U(IV) under anaerobic conditions by using their metabolisms, resulting in the immobilization of U. In this study, the aqueous U(VI) removal performance and change in bacterial community in response to the indigenous bacteria were investigated to understand the interactions of U-microbe under anaerobic conditions. Three different indigenous bacteria obtained from different depths of granitic groundwater (S1: 44–60 m, S2: 92–116 m, and S3: 234–244 m) were used for the reduction of U(VI)aq. After the anaerobic reaction of 24 weeks, the changes in bacterial community structure in response to the seeding indigenous bacteria were observed by high-throughput 16S rDNA gene sequencing analysis. The highest uranium removal efficiency of 57.8% was obtained in S3 sample, and followed by S2 (43.1%) and S1 (37.7%). Interestingly, SRB capable of reducing U(VI) greatly increased from 4.8% to 44.1% in S3 sample. Among the SRB identified, Thermodesulfovibrio yellowstonii played a key role on the removal of U(VI)aq. Transmission electron microscopy (TEM) analysis showed that the dspacing of precipitates observed in this study was identical with that of uraninite (UO2). This study presents the potential of U(VI)aq removal by indigenous bacteria under deep geological environment.
110.
2022.10 구독 인증기관·개인회원 무료
In Korea, research on the development of safety case, including the safety assessment of disposal facility for the spent nuclear fuel, is being conducted for long-term management planning. The safety assessment procedure on disposal facility for the spent nuclear fuel heavily involves creating scenarios in which radioactive materials from the repository reach the human biosphere by combining Features, Events and Processes (FEP) that describe processes or events occurring around the disposal area. Meanwhile, the general guidelines provided by the IAEA or top-tier regulatory requirements addressed by each country do not mention detailed methods of ‘how to develop scenarios by combining individual FEPs’. For this reason, the overall frameworks of developing scenarios are almost similar, but their details are quite different depending on situation. Therefore, in order to follow up and clearly analyze the methods of how to develop scenarios, it is necessary to understand and compare case studies performed by each institution. In the previous companion paper entitled ‘Research Status and Trends’, the characteristics and advantages/disadvantages of representative scenario development methods were described. In this paper, which is a next series of the companion papers, we investigate and review with a focus on details of scenario development methods officially documented. In particular, we summarize some cases for the most commonly utilized methods, which are categorized as the ‘systematic method’, and this method is addressed by Process Influence Diagram (PID) and Rock Engineering System (RES). The lessons-learned and insight of these approaches can be used to develop the scenarios for enhanced Korean disposal facility for the spent nuclear fuel in the future.
111.
2022.10 구독 인증기관·개인회원 무료
The hydro-mechanical behavior of rock mass in natural barriers is a critical factor of interest, and it is mainly determined by the characteristics of the fractures distributed in the rock mass. In particular, the aperture and contact area of the fractures are important parameters directly related to the fluid flow and significantly influence the hydro-mechanical behavior of natural barriers. Therefore, it is necessary to analyze the aperture and contact area of fractures distributed in potential disposal sites to examine the long-term evolution of the natural barriers. This study aims to propose a new technique for analyzing the aperture and contact area using the natural fractures in KURT (KAERI Underground Research Tunnel), an underground research facility for the deep geological disposal of high-level radioactive waste. The proposed technique consists of a matching algorithm for the three-dimensional point cloud of the upper and lower fracture surfaces and a normal deformation algorithm that considers the fracture normal stiffness. In the matching process of upper and lower fracture surfaces, digital images obtained from compression tests with pressure films are used as input data. First, for the primary matching of the upper and lower fracture surfaces, an iterative closest point (ICP) algorithm is applied in which rotation and translation are performed to minimize the distance error. Second, an algorithm for rotation about the x, y, and z axes and translation in the normal direction is applied so that the contact area of the point cloud is as consistent as possible with the pressure film image. Finally, by applying the normal deformation algorithm considering the fracture normal stiffness, the aperture and contact area of the fracture according to the applied normal stress are derived. The applicability of the proposed technique was validated using 12 natural fractures sampled from KURT, and it was confirmed that the initial apertures were derived similarly to the empirical equation proposed in the previous study. Therefore, it was judged that the distribution of apertures and contact areas according to applied normal stress for laboratory-scale fractures could be derived through the technique proposed in this study.
112.
2022.10 구독 인증기관·개인회원 무료
Safety assessment is important for the radioactive waste repositories, and several methods are used to develop scenarios for the management of radioactive waste. The intent of the use of these scenarios is to show how the radio nuclides release can affect the safety of disposal system. It plays an essential role of providing scientific and technical information for performance assessment of safety functions. As important as scenario is, numerous studies for their own scenario development have been conducted in many countries. Scenario development methodology is basically divided into four categories: (1) judgmental, (2) fault/event-tree analysis, (3) simulation, and (4) systematic. Under numerous research, these methods have been developed in ways to strengthen the advantages and make up for the weakness. However, it was hard to find any judgmental or fault/event-tree analysis approach in recent safety assessments since they are not well-systemized and difficult to cover all scenarios. Simulation and systematic approaches are used broadly for their convenience of analyzing needed scenarios. Furthermore, several new methodologies, Process Influence Diagram (PID)/Rock Engineering System (RES)/Hybrid, were developed to reinforce the systematic approach in recent studies. Currently, a government project related to the disposal of spent nuclear fuel is in progress in Korea, and the scenario development for safety case is one of the important tasks. Therefore, it is necessary to identify the characteristics and strengths and weaknesses of the latest scenario development and analysis methods to create a unique methodology for Korea. In this paper, the existing methodologies and cases will be introduced, and the considerations for future scenario development will be summarized by considering those used in the nuclear field other than repository issues. Systematic approach, which is the mostly commonly used method, will be introduced in detail with its use in other countries at the subsequent companion paper entitled ‘Case Study for a Disposal Facility for the Spent Nuclear Fuel’.
113.
2022.10 구독 인증기관·개인회원 무료
The high-level waste disposal system is an underground structure exposed to complex environmental conditions such as high temperature, radiation, and groundwater. The high-level waste disposal causes structural cracks and deterioration over time. However, since the high-level waste disposal system is a structure that should be operated for a very long time, developing a high-durability monitoring sensor to detect cracks and deterioration is essential. The durability of the sensor can be evaluated by predicting the expected life through the accelerated life test, one of the reliability qualification tests. The most important factor in the accelerated life test design is setting the harsh stress level. This study figured out the harsh stress level of the piezoelectric sensor, which is commonly used for underground structure monitoring. It is possible to determine the appropriate stress level for the accelerated life test by investigating the harsh stress level for the temperature factor. It will contribute to more accurate life expectancy prediction.
114.
2022.10 구독 인증기관·개인회원 무료
In this study, we evaluated fracture filling minerals and aperture distribution along the fracture surfaces under the controlled conditions. The fractured granite block which has a single natural fracture of 1 m scale was sampled in a domestic quarry (Iksan), which groundwater had been flowed through. This rock has an interconnected porosity of 0.36 with the specific gravity of 2.57. The experimental setup with the granite block with dimensions of 100×60×60 (cm). The fracture is sealed with rock silicone rubbers when it intersects the outer surfaces of the block and the outer surfaces are coated with the silicone to prevent loss of water by evaporation. Nine boreholes were drilled of orthogonal direction at the fracture surface. A flow of de-ionized water through the fracture between pairs of boreholes was initiated and the pressure required to maintain a steady flow was measured. In additions, fracture filling minerals were sampled and examined by mineralogical and chemical analyses. There are phyllosilicate minerals such as illite, kaolinite, and chlorite including calcite, which are fracture filling minerals. The illite and kaolinite usually coexist in the fracture, where their content ratio is different according to which mineral is predominant. For the evaluation of fracture, surface was divided into an imaginary matrix of 20×20 sub-squares as schematically. The calculated results are expressed as a two dimensional contour and a three dimensional surface plot for the aperture distribution in the fracture. The aperture value is distributed between 0.075 and 0.114 mm and the mean aperture value is 0.082 mm. The fracture volume is about 49 ml. These results will be very useful for the evaluation of environmental factor affecting the nuclides migration and retardation.
115.
2022.10 구독 인증기관·개인회원 무료
It is expected that around 576,000 bundles of CANDU spent nuclear fuels (SNF) will be generated from the four CANDU reactors located at the Wolsong site, according to the 2nd National Plan for the management of High-Level radioactive Waste (HLW). The CANDU SNFs are currently stored at the dry storage facilities at the Wolsong site. The authors proposed KRS+ geological disposal system consisting of two different concepts, Swedish KBS-3V type and Canadian NWMO type, for the final management of CANDU SNF. Both the concepts were designed based on the geological data obtained from the KURT (KAERI Underground Research Tunnel). The NWMO type is an in-room horizontal placement method. In this study, we try to determine the reference concept among the two proposed concepts at 500 meters below the ground surface. Assuming 10,000 tU of CANDU SNF and the KURT site, we design two engineered barrier systems, that is disposal canisters and buffers. The copper disposal canister is designed with a copper thickness of 10 mm based on a cold spray coating technique for both the disposal concepts. The domestic Ca-bentonite is used for the compact bentonite buffer with dry density of 1.6 g/cm3. Two concepts are compared in terms of safety, economics of the engineered barriers, and environment-friendliness. Because the same amounts of CANDU SNF are disposed of at the same depth, the differences in the disposal area are neglected. For the comparison in terms of safety, the corrosion lifetimes of the disposal canisters of two disposal systems are quantitatively calculated, and the capacities for retarding radionuclide releases of the compacted bentonite buffers are assessed. A computer tool developed by the authors is used in order to assess the lifetime of a disposal canister. In this study, the case that corrosion of a copper canister by sulfide from groundwater through intact buffer is analyzed. The sulfide concentration in groundwater is assumed to be 3 ppm. The most important safety function of buffer is to retard the radionuclide release. Twelve long-lived radionuclides are selected to compare the capacities for retarding the radionuclide transport through the buffer using an analytical solution. The retention time by an engineered barrier consisting of a disposal canister and a buffer is compared with twenty times the half-life of each radionuclide for both the disposal systems. The selected reference concept will be compared with the alternative geological concepts through a further study.
116.
2022.10 구독 인증기관·개인회원 무료
Dry head end process is developing for pyro-processing at KAERI (Korea Atomic Energy Research Institute). Dry processes, which include disassembling, mechanical decladding, vol-oxidation, blending, compaction, and sintering shall be performed in advance as the head-end process of pyro-processing. Also, for the operation of the head-end process, the design of the connecting systems between the down ender and the dismantling process is required. The disassembling process includes apparatus for down ender, dismantling of the SF (Spent Fuel) assembly (16×16 PWR), rod extraction, and cutting of extracted spent fuel rods. The disassembling process has four-unit apparatus, which comprises of a down ender that brings the assembly from a vertical position to a horizontal position, a dismantler to remove the upper and bottom nozzles of the spent fuel assembly, an extractor to extract the spent fuel rods from the assembly, and a cutter to cut the extracted spent fuel rods as a final step to transfer the rod-cuts to the mechanical decladding process. An important goal of dismantling process is the disassembling of a spent nuclear fuel assembly for the subsequent extraction process. In order to design the down ender and dismantler, these systems were analyzed and designed, also concept on the interference tools between down ender and dismantler were considered by using the solid works tool.
117.
2022.10 구독 인증기관·개인회원 무료
In south Korea, most of uranium deposits are distributed in the Ogcheon belt, which is one of two late Precambrian to Paleozoic fold belts (the Imjingang and Ogcheon belts). A study site of the Ogcheon metamorphic belt (OMB) in Hoenam-myun, Boeun-gun was selected for the natural analogue study by preliminary site investigation for several candidate study sites. Three boreholes were drilled in the site and some rock cores and groundwater samples were taken from the boreholes. Various analytical studies for the samples are now being performed. Thus, in this study, various basic characteristics of the study site such as occurrence, geological, mineralogical, and chemical properties were investigated for a future study. Base rocks containing uranium in the OMB are usually black slate and coaly slate. Coaly slate usually shows a higher content of uranium and larger grain size of uranium than black slate. Uranium minerals found in the OMB are uraninite, uranothorite, brannerite, ekanite, coffinite, francevillite, uranophane, autunite, and torbernite depending on the base rock types. Uranothorite is abundant in black slate whereas uraninite is mostly abundant in coaly slate. Chemical compositions of the solid and groundwater samples from the study site were also analyzed by using ICP-MS/OES (Inductively Coupled Plasma Mass Spectrometry) and XRF (X-ray Fluorescence). This will contribute to determine uranium minerals in the solid samples and uranium speciation in the groundwater. The results of this study will contribute to performing future natural analogue studies in domestic uranium deposits and provide basic information and knowledge for understanding long-term geochemical behaviors of radionuclides in a high-level radioactive repository.
118.
2022.10 구독 인증기관·개인회원 무료
Spent nuclear fuels are temporarily stored in nuclear power plant site. When a problem such as cracking of spent nuclear fuel assembly or cladding occurs or uranium that has not been separated during the reprocessing remains, it is necessary to treat it. The borosilicate glasses have been considered to vitrify whole spent nuclear fuel assembly. However, a large amount of Pb addition was necessary to oxidize metals in assembly to make them suitable for oxide glass vitrifcation. Furthermore, these borosilicate glasses need to be melted at high temperatures (> 1,400°C) when UO2 content is more than 20wt%. Iron phosphate glasses can be melted at a relatively low temperature (< 1,300°C) even with a similar UO2 addition. A composition of iron phosphate glass for immobilization of uranium oxide has been developed. The glasses have glass transition temperatures of ~555°C that are high enough to maintain its phase stability in geological repositories. The waste loading of UO2 in the glass is ~33.73wt%. Normalized elemental releases from the product consistency test were well below the US regulation of 2 g/m2. Nuclear criticality safety and heat generation in deep geological repositories were calculated using MCNP and computational fluid dynamics simulation, respectively. The glass had effective neutron multiplication factor (keff) of 0.755, which is smaller than the nuclear- criticality safety regulation of 0.95. Surface temperature of the disposal canister is expected to lower than the limit temperature (< 100°C). Most of the U in the glass is in the 4+state, which is more chemically durable than the 6+state. As a result of long-term dissolution experiment, chemically-durable uranium pyrophosphate (UP2O7) crystals were formed.
119.
2022.10 구독 인증기관·개인회원 무료
CYPRUS is a web-based waste disposal research comprehensive information management program developed by the Korea Atomic Energy Research Institute over three years from 2004. This program is stored as existing quality assurance documents and data, and the research results can be viewed at any time. In addition, it helps to perform all series of tasks related to the safety evaluation study of the repository in accordance with the quality assurance system. In the future, it is necessary to improve the user convenience by clarifying the relationship between FEP and scenarios and upgrading output functions such as visualization and automatic report generation. This purpose of this study is to research and develop the advanced program of CYPRUS. This study is based on building FEP, DIM and scenario databases. It is necessary to develop an algorithm to analyze and visualize the FEP, DIM and scenario relationship. This project is an integrated information processing platform for DB management and visualization considering user convenience. The first development goal is to build long-term evolutionary FEP, DIM, and scenarios as a database. The linkage by FEP item was designed in consideration of convenience by using a mixed delimiter of letters and numbers. This design provides information on detailed interactions and impacts between FEP items. Scenario data lists a series of events and characteristic change information for performance evaluation in chronological order. In addition, it includes information on FEP occurrence and mutual nutrition by period, and information on whether or not the repository performance is satisfied by item. The second development goal is to realize the relationship analysis and visualization function of FEP and scenario based on network analysis technique. Based on DIM, this function analyzes and visualizes interactions between FEPs in the same way as PID, RES, etc. In addition, this function analyzes FEP and DIM using network analysis technique and visualizes it as a diagram. The developed platform will be used to construct and visualize the FEP DB covering research results in various disposal research fields, to analyze and visualize the relationship between core FEP and scenarios, and finally to construct scenarios and calculation cases that are the evaluation target of the comprehensive performance evaluation model. In addition, it is expected to support the knowledge exchange of experts based on the FEP and scenario integrated information processing platform, and to utilize the platform itself as a part of the knowledge transfer system for knowledge preservation.
120.
2022.10 구독 인증기관·개인회원 무료
In high-level radioactive waste disposal, a high temperature is generated from the canister containing the waste in the engineered barrier, while groundwater flows into the buffer system from the host rock. The temperature increase and groundwater inflow result in the water phase change and saturation variation. Saturation change is related to the thermal conductivity of buffer material; hence the phase change and saturation strongly interact with the temperature evolution. The complex coupled behavior affects the stability of the whole disposal system, and the security of the repository is critical to human-being life. However, it is difficult to predict the long-term coupled behavior in the disposal system due to the considerable field-test scale, and therefore a numerical simulation is a suitable method having repeatability and cost-effectiveness. DECOVALEX is an international cooperating project for developing numerical methods and models for thermo-hydro-mechanical-chemical (THMC) interaction. DECOVALEX has a four-year cycle with various topics. At the current phase, Task C aims to simulate the full-scale emplacement (FE) experiment performed at Mont Terri underground rock laboratory. Nine research groups are participating in the task, and among them, KAERI simulates the experiment using OGS-FLAC. The simulator combines OpenGeoSys for TH simulation and FLAC3D for M simulation. Through the benchmark simulation, we verified OGS-FLAC for the two-phase flow analysis in the disposal system and finally modeled the FE experiment with a three-dimensional grid. We performed a simple sensitivity analysis to investigate the effect of input parameters on the two-phase flow system and confirmed that the compressibility and permeability affected the flow behavior. We also compared the simulation results to the field data and obtained well-matched results from a series of simulation.