This study were to simulate major criteria air pollutants and estimate regional source-receptor relationship using air quality prediction model (TAPM ; The Air Pollution Model) in the Seoul Metropolitan area. Source-receptor relationship was estimated by contribution of each region to other regions and region itself through dividing the Seoul metropolitan area into five regions. According to administrative boundary, region Ⅰ and region Ⅱ were Seoul and Incheon in order. Gyeonggi was divided into three regions by directions like southern(region Ⅲ), northern(Ⅳ) and eastern(Ⅴ) area. Gridded emissions (1km×1km) by Clean Air Pollicy Support System (CAPSS) of National Institute of Environmental Research (NIER) was prepared for TAPM simulation. The operational weather prediction system, Regional Data Assimilation and Prediction System (RDAPS) operated by the Korean Meteorology Administration (KMA) was used for the regional weather forecasting with 30km grid resolution. Modeling period was 5 continuous days for each season with non-precipitation . The results showed that region Ⅰ was the most air-polluted area and it was 3～4 times more polluted region than other regions for NO2, SO2 and PM10. Contributions of SO2 NO2 and PM10 to region Ⅰ, Ⅱ and Ⅲ were more than 50 percent for their own sources. However region Ⅳ and Ⅴ were mostly affected by sources of region Ⅰ, Ⅱ and Ⅲ. When emissions of all regions were assumed to reduce 10 and 20 percent separately, air pollution of each region was reduced linearly and the contributions of reduction scenario were similar to those of base case. As input emissions were reduced according to different ratio - region Ⅰ 40 percent, region Ⅱ and Ⅲ 20 percent, region Ⅳ and Ⅴ 10 percent, air pollutions of region Ⅰ and Ⅲ were decreased remarkably. The contributions to regionⅠ, Ⅱ, Ⅲ were also reduced for their own sources. However, region Ⅰ, Ⅱ and Ⅲ affected more regions Ⅳ and Ⅴ. Shortly, graded reduction of emission could be more effective to control air pollution in emission imbalanced area.

This study was carried out to investigate the emissions of the air pollutants from the automobile in Suwon city. To estimate emissions due to by automobile the data of express highway and the national road used an observation traffic volume, and the other roads used a method by Vehicle kilometer traveled(VKT). In the emissions due to by automobile from Suwon city, CO was highest 36,290.4 ton/year, NOx at 19,392.1 tons, HC 5,095.4 tons and PM 2,788.7 tons was highly order. SOx emissions in the whole Suwon city by fuel types was investigated with 178ton/year from the Diesel motorcar, 26.9 ton/year and 6.2 ton/year from the gasolines and LPG automobiles, respectively. VOC emissions from the automobile was investigated with 366.4 ton/year (29.22%) from Gwonseon-gu, 329.2 ton/year (26.25%) Yeongtong-gu, 319.9 ton/year (25.51%) Jangan-gu, 238.6 ton/year (19.03%) Paldal-gu.

In this study, the environmental behavior of malodor pollutants (MPs:　H2S, CH3SH, DMS, and DMDS) was investigated around areas influenced by strong anthropogenic processes based on observations and modeling study (a CALPUFF dispersion model). The MP emission concentrations were measured from 8 industrial source regions (tire plants (S1-S3), waste water disposal plant (S4), and oil refinery (S5) in an urban center area and paper mill/incineration plant (S6) and livestock feedlots (S7-S8) in Ungsang area) in Yangsan city during a fall period in 2008 (21 October 2008). Overall, the most MPs emitted from the urban center area were found to affect the malodor pollution in their downwind areas during early morning (06:00 LST) and nighttime (18:00 and 21:00 LST), compared with those in the Ungsang area. For malodor intensity, the most MPs in the urban center area (especially S1 and S2) were found to be a significant contributor, whereas CH3SH and H2S in the Ungsnag area (especially S6) were the dominant contributor. The model study showed agreement in the spatial distributions of simulated MPs with those of the observations. The largest impact of MPs in the urban center area on the malodor pollution in its residential areas occurred at S1, S2, and S3 sites during nighttime, while that of MPs in the Ungsang area occurred at S6 and S8 sites. This may be caused mainly by the high MP emissions and in part by wind conditions (prevailing northeasterly winds with low wind speeds of 2-3 m/s).

This study intends to estimate the best model parameters for predicting the water quality and discharge of the study area, and provide the basic data necessary for predicting the water quality and discharge and examining changes in water quality on the basis of the changes hydraulic and hydrological changes and pollutional load of the study area. Nakdong River was selected for analysis, and the water quality survey data necessary for parameter estimation was based on the monthly water quality data (discharge, BOD, T-N and T-P) between December 1, 2002 ~ November 31, 2002. The topographical characteristics factors of the study area were based on the 1/25,000 numerical map published by the National Geographic Information Institute and satellite photographs. The presumed course: It measured the most suitable parameter that could imitate surveyed water quality and discharge using the method of trial and error, in this part the first numerical value was the model parameter presented SWAT. The result of analisys showed that a relative error between surveyed value and the result of water quality imitation about BOD, T-N, T-P that examined by this study, discharge correction : R2=0.912, discharge verification : R2=0.838, correction and verification of BOD : R2=0.847, correction and verification of T-N : R2=0.712 and, correction and verification of T-P : R2=0.726 and, BOD : RK1, RK3, T-N : RS3, RS4, T-P : RS2, RS5, GWSOLP, discharge : ALPAHA_BF, GWQMN, CH_N(2), CN2, SOL_AWC have been considered as the factors of the water quality performed in this water quality simulation, that is, the most effective parameters on BOD, T-N and T-P. It is considered that it will be possible to apply the most optimal parameter to an analysis of the water quality and discharge simulation at study area in the goal year by examining the interaction of the parameters through the parameters sampling which are able to applicable to prediction of the water quality and discharge in the future, also the analysis on the basis of the hydrological conditions: an outflow or the character of a flow will be needed.

The chemical and meteorological effects on the concentration variations of air pollutants (O3 and its precursors) were evaluated based on ground observation data in coastal and inland regions, Busan during springs and summers of 2005-2006. For the purpose of this study, study areas were classified into 5 categories: coastal area (CA), industrial area (IA), downtown area (DA), residential area (RA), and suburban area (SA). Two sites of Dongsam (DS) and Yeonsan (YS) were selected for the comparison purpose between the coastal and inland regions. O3 concentrations in CA and SA were observed to be highest during spring (e.g., 40 ppb), whereas those in DA and RA were relatively low during summer (e.g., 22～24 ppb). It was found that O3 concentrations in IA were not significantly high although high VOCs (especially toluene of about 40 ppb) and NOx (≥ 35 ppb) were observed. On the other hand, the concentration levels of O3 and PM10 at the DS site were significantly higher than those at the YS site, but NOx was slightly lower than that at the YS site. This might be caused by the photochemical activity and meteorological conditions (e.g., sea-land breeze and atmospheric stagnance). When maximum O3 (an index of photochemical activity) exceeds 100 ppb, the contribution of secondary PM10 ((PM10)SEC) to total observed PM10 concentrations was estimated up to 32% and 17% at the DS and YS sites, respectively. In addition, the diurnal variations of (PM10)SEC at the DS site were similar to those of O3 regardless of season, which suggests that they are mostly secondary PM10 produced from photochemical reactions.

가스성 오염물질의 지표를 제공하는 이산화탄소를 시료로 사용하여, 식물의 공기정화 능력을 분석한 실험 결과는 다음과 같다. 공시 6가지 식물 모두 광합성이 활발한 낮 시간 동안에는 식물이 오염원을 흡수함에 따라, 이산화탄소 농도가 빠르게 감소하였다. 호흡작용을 통해 이산화탄소가 방출되므로 빛이 차단되는 밤 시간에는 농도가 다시 증가하였고, 특히 18시 ~ 20시 사이에는 급격한 농도 증가율을 보였다. 다음 날 아침 빛을 쬐기 시작하면 다시 오염원이 흡수되면서 농도가 감소한다. 이러한 이산화탄소 농도의 교환 현상을 통해, 빛의 양이 증가함에 따라 식물의 광합성량이 증가하며 그 결과 이산화탄소 제거율 역시 증가함을 알 수 있었다. 24시간 동안 측정한 식물별 광합성량과 호흡량을 가감한, 식물별 이산화탄소의 정화총량은 엽면적 1000 cm2 당 Ficus benjamina 49 ppm, Epipremnum aureum 99 ppm, Chamaedorea elegans 34 ppm, Fatsia japonica 123 ppm, Spthiphyllum spp. 115 ppm, Hedera helix 42 ppm으로 나타났다. 이산화탄소 순간소모량의 최대치를 보인 시간대는 각 식물별로 상이한데, 대개의 경우 광량 0.67 ~ 1.54 mW/cm3의 조건에서 가장 활발한 이산화탄소 흡수율을 보였다. Epipremnum aureum의 경우, 이산화탄소의 흡수가 비교적 높은 속도로 장기간 지속되었으며, 다른 식물에 비해 상대적으로 낮은 호흡량을 보였다. Fatsia japonica는 매우 대칭적인 이산화탄소 농도변화곡선을 보여, 광합성과 호흡이 일정하게 일어남을 알 수 있었다. 광량의 변화에 그리 민감하지 않아 폭넓은 광량조건의 실내공간에도 적합하다고 판단된다. Spthiphyllum spp. 역시 장기간에 걸쳐 비교적 안정적으로 광합성이 일어났다. Hedera helix는 1.24 mW/cm3이상의 광조건에서 상당히 높은 이산화탄소 흡수율을 보였으나, 1.00 mW/cm3이하에서의 낮은 제거율로 보아 저광도 실내공간보다는 고광도의 전이공간이나 실외에 적합하다고 판단된다. 위의 연구결과를 통하여 이산화탄소 제거에는 Fatsia japonica, Spthiphyllum spp., Epipremnum aureum 순서로 효과적임을 알 수 있었다.

본 연구는 실내식물의 공기정화능을 연구하기 위하여 Ficus benjamina, Epipremnum aureum, Chamaedorea elegans, Fatsia japonica, Spthiphyllum spp., Hedera helix를 사용하여 동일한 환경조건의 밀폐 챔버 내부에 넣은 후, 250 ppb의 포름알데히드를 투입하여 광합성과 호흡을 통한 두 가스물질의 농도 변화량 및 제거속도를 24시간 동안 일정시간간격으로 측정하였다. 식물별 엽면적 1,000㎠ 당 제거량은 Ficus benjamina 128.6 ppb, Epipremnum aureum 152 ppb, Chamaedorea elegans 127.8 ppb, Fatsia japonica 165.9 ppb, Spthiphyllum spp. 156 ppb, Hedera helix 115 ppb로 나타났으며 포름알데히드의 농도변화곡선을 분석한 결과, Fatsia japonica와 Spthiphyllum spp.가 가장 폭넓은 광조건에서 비교적 높고 안정적인 감소율을 보였다. Epipremnum aureum의 경우, 총 제거량은 높았으나 시간대별 제거율이 불규칙하여 특정범위의 광량조건을 필요로 하는 것을 알 수 있었다. 특히 Hedrera helix의 경우, 매우 불규칙적인 농도변화로 포름알데히드 농도에도 민감함을 알 수 있었다.

The air pollutant emission is mainly caused by line sources in urban area. For example, the annually totaled air pollutant emission is known to consist of about 80% of line sources in Daegu. Hence, the appropriate assessment on the air pollutants of line sources is very important for the atmospheric environmental management in urban area. In this study, we made a comparative study to evaluate suitable dispersion model for estimating the air pollution from line sources. Two air pollution dispersion models, ISCST3 and CALINE4 were the subject of this study. The results were as follows; In the assessment of air pollution model, ISCST3 was found to have 4 times higher concentration than CALINE4. In addition, actual data obtained by measurement and estimated values by CALINE4 were generally identical. The air pollution assessment based on ISC3 model produced significantly lower values than actual data. The air pollution levels estimated by ISCST3 were very low in comparison with the observational values.

Currently, portable equipment for recycling of waste asphalt concrete (ASCON) has been used. However, any air pollution control devices are not attached in the simple portable one. Thus, a lot of air pollutants have been produced from recycling processes of waste ASCON which resulted from aging of paved roads or repavement of roads. This study deals with a preliminary result of concentration analysis of air pollutants obtained from a pilot and a real recycling processes of waste ASCON using simple portable recycling equipment. Air pollutants were taken from 4 steps of the pilot recycling process including an initial heating by liquid petroleum gas (LPG), intermediate heating and melting (H&M) process, final H&M process, and pavement processes using recycled ASCON at the recycling site. Also, air pollutants were taken front 4 steps of the real recycling processes including an initial H&M, final H&M and mixing, loading of recycled ASCON to dump trucks, and at the recycling site after leaving the loaded dump trucks for real pavement sites. The air pollutants measured in this study include volatile organic compounds (VOCs), aldehydes, particulate matter (PM: PM1, PM2.5, PM7, PM10, TSP (total suspended particulate)). The identified concentrations of VOCs increased with increasing time or degree for H&M of waste ASCON. In particular, very high concentrations of the VOCs at the status of complete melting, which is exposed to the air, of the waste ASCON just before paving tv the recycled ASCON at the recycling site. Also, considerable amount of VOCs were identified from the recycling equipment after the dump trucks leaded by recycled ASCON leaved the recycling site for the pavement sites. The relative level of formaldehyde exceeded 80% of the aldehydes Identified in the recycling processes. This is because the waste ASCON is exposed to direct flame of LPG during H&M processes. The PM concentrations measured in the winter recycling processes, such as the loading and rotation processes of waste ASCON into/in the recycling equipment for H&M, were much higher than those in the summer ones. In particular, the concentrations of coarse particles such as PM7 and PM10 during the winter recycling were very high as compared those during the summer one.

본 연구에서는 식생여과대에 있어서 토양층의 역할에 주목하였으며, 토양 침투량이 증가될 수 있는 구조로 토양층을 변형하여 일반적인 식생여과대에서의 오염저감효과와 비교 분석하였다. 따라서 연구의 최종 목적은 토양층 변화를 통한 식생여과대의 수질개선효과를 일반적인 토양층으로 구성된 식생여과대와 비교, 검토함으로써 보다 효과적인 식생여과대를 조성하고자 하는 것이다. 실험분석 결과, 토양층 변화를 접목시킨 식생여과대는 일반 식생여과대에 비해 표면유출에서 높은 오

The work of hairdressers includes washing, coloring, bleaching, permanent waving, conditioning, and cutting hair. Hairdressers are subjected to a number of physical and toxicological hazards. The toxicological hazards are those resulting from exposure to a wide range of chemicals that are usually classified active processes. In this study, twenty beauty shops were selected to assess the exposure to indoor air pollutants such as VOCs and particulate matter (PM10) during one month from September 1 to September 30, 2003. Indoor air quality of beauty shops might be worse by vehicle emissions because the beauty shops were generally located near roadways. Personal exposures to VOCs and PM10 were related to indoor concentrations of beauty shops. According to the questionnaire, hairdressers complained of sore throat, eye irritation, and nervousness as physical symptoms. The measured mean concentrations of respiratory particulates were 30.5ng/㎥ in indoor, 30.5ng/㎥in outdoor and 44.0ng/㎥ on personal levels. The personal concentration was found higher than indoor and outdoor concentrations. The heavy metals mean concentrations were shown as indoor (Na>Zn>Cr), outdoor (Cr>Zn>Pb), and personal (Na>Cr>Zn) levels. Conclusively, customers as well as workers in the beauty shops might be highly exposed to air pollutants from indoor and outdoor sources. Therefore, proper management should be taken to improve the indoor air quality in beauty shops.

In this study, we try to determine the distributive property in southwest coastal waters, such as Kwang-yang bay, Ka-mak bay, Yeo-ja bay, Wan-do, Hea-nam, Young-gwang, and Mok-po, using simultaneous analytical method of 310 chemicals. The results were detected tens of the organic pollutants in sampling sites, and the major chemicals detected were CH type chemicals such as aliphatic, polycyclic compounds and were CHN(O) type chemicals such as aromatic amines, nitro compounds. In particular, pesticides were mainly detected in summer, phenols and phthalate esters were not seasonal effect. Also, a number of aromatic chemicals were detected in Kwang-yang bay. From the results of this study, we confirmed that it is mainly contaminated in summer and the pesticide chemicals are the major pollutants in southwest coastal waters.

Enormous apartment complexes in urban areas, temporary inversion state and heat island effect occur due to the strong sunshine and weak wind speeds which hinders the dispersion of air pollutants that are emitted from neighboring areas of apartment complexes. In this study, analysis were conducted by using the Fluent code based on the CFD(Computation Fluid Dynamics), including building layout, material, building height from the ground surface, the heat, analysis of flow field in the apartment complex. It was estimated that the temporal radiation inversion phenomenon during the daytime, which was caused by the weak wind speed and higher temperatures in the upper level, contributed to the stagnation of the air pollutants in the lower layer of the apartment complex.

In this study, we investigated PM10, NO2, and 1-hydroxypyrene(1-OHP) in urine at indoor environments which are 35 houses and 20 hospitals for using air cleaner and non-using air cleaner in Seoul metropolitan area and Kyoung-gi province from April, 2003 to February, 2004. Moreover, we examined effect of improvement for indoor air quality and health effect by concentration of 1-OHP also we investigated removal efficiency by air cleaner for PM10, NO2, and 1-OHP that were 28.5%, 27.4%, and 42.1% respectively. Concentration of PM10, NO2, and 1-OHP were 19.02±18.14㎍/m3, 8.66±3.06ppb, and 0.19±0.18㎍/g creatinine when air cleaner was no worked. The concentration for PM10, NO2, and 1-OHP were 13.60±10.79㎍/m3, 6.29±2.71ppb, and 0.11±0.10㎍/g creatinine, respectively. It was significant statistically. Therefore, it is considered using the air cleaner to remove the partial pollutants in indoor environment and is positive effect for health.

The importance of atmospheric conditions for the assessment of an air pollution situation has been demonstrated by their influence on the various compartments of an air pollution system, comprising all stages from emission to effects. Especially, air pollutants dispersion phenomenon are very sensitive according to wind data. But the discussions of how to apply representative meteorological data in air pollution dispersion model are not frequent in Korean environmental assessment processes. In this study, we investigated the difference of air pollutants dispersion phenomenon using U.S EPA ISCLT3 model according to applying the different meteorological data observed at two points for Seongseo industrial complex of Daegu. Two points are the spot site of Seongseo industrial complex and Daegu meteorological observatory. The winds speed of the spot site were smaller than those of Daegu meteorological observatory. In the winter season, the differences came to about 64% for the period(1 February 2001～31 January 2002). Wind directions were also fairly different at two points. The air pollutants dispersion phenomenon estimated from our numerical experiments were also fairly different owing to the meteorological conditions at two points.

Petroleum refineries have been considered as an important emission source for atmospheric volatile hazardous air pollutants(HAPs). The emission source includes petroleum refinery processes and process equipment. The control strategy for volatile HAPs requires emission estimations of these pollutants. However, systematic methods of volatile HAPs emission from petroleum refineries have not yet been established. Accordingly, present study surveyed the estimation method of volatile HAPs emitted from the petroleum refinery processes and process equipment. The emission estimation methods for the petroleum refinery processes are applied for 11 petroleum refining facilities: fluidized catalytic cracking, thermal cracking, moving bed catalytic cracking, compressed engine, blowdown system, vacuum distilled column condensator, natural gas or distilled boiler, natural gas or distilled heater, oil boiler, oil heater and flare. Four emission estimation methods applied for the petroleum refinery process equipment are as follows: average emission factor approach, screening ranges approach, EPA correlation approach and unit-specific correlation approach. The process equipment for which emission factors are available are valves, pump seals, connectors, flanges and open-ended lines.

Plasma-photocatalytic oxidation process was applied in the decomposition of Triethylamine(TEA) and Methyl ethyl ketone(MEK). Plasma reactor was made entirely of pyrex glass and consists of 24 ㎜ inner diameter, 1,800 ㎜ length and discharge electrode of 0.4 ㎜ stainless steel. And initial concentrations of TEA and MEK for plasma-photocatalytic oxidation are 100 ppm. Odor gas samples were taken by gas-tight syringe from a glass sampling bulb which was located at reactor inlet and outlet, and TEA and MEK were determined by GC-FID. For plasma process, the decomposition efficiency of TEA and MEK were evaluated by varying different flowrates and decomposition efficiency of TEA and MEK increased considerably with decreasing treatment flowrates. For photocatalytic oxidation process, also the decomposition efficiency of TEA and MEK increased considerably with decreasing treatment flowrates. The decomposition efficiency of MEK was 57.8%, 34.2%, 18.8% respectively and the decomposition efficiency of TEA was reached all 100%. This result is higher than that of plasma process only. From this study, the results indicate that plasma-photocatalytic oxidation process is ideal for treatment of TEA and MEK.

Urban air quality is usually worse than that of rural counterpart. The contrasting atmospheric properties seem to be direct result of different urban-rural air pollutant emission. Hence, the emission estimation of air pollutants plays an important role to the atmospheric environmental management. The main purpose of this study is to find out the temporal and spatial distribution of air pollutant emission in Daegu area. For the study, the Daegu statistical yearbook and data of waste facilities and the report on traffic survey issued by Daegu metropolitan city and the statistical yearbook on the road capacity issued by the ministry of construction and transportation are used. Each item for the emission estimation is SO2, CO, HC, NOx, PM-10 from point, line and area source. The result were as follow; (1) The air pollutants with the highest amount of emission from the emission source is CO fllowed by NOx, SO2, PM-10, HC in descending order of magnitude. (2) The annually totaled air pollutant emission consists of 81%(73,185 ton/year) of line, 11%(9,589% ton/year) of area and 8%(7,445 ton/year) of point source in Daegu. Air polluant emission was mainly due to line sources. (3) High-emission of the air pollutants of line source appeared ariond Bukgu, Dalseonggun, Dongu and Seogu ; the areas with highway networks.