Spent nuclear fuel (SNF) is the main source of high-level radioactive wastes (HLWs), which contains approximately 96% of uranium (U). For the safe disposal of the HLWs, the SNF is packed in canisters of cast iron and copper, and then is emplaced within 500 m of host rock surrounded by compacted bentonite clay buffer for at least 100,000 years. However, in case of the failure of the multi-barrier disposal system, U might be migrated through the rock fractures and groundwater, eventually, it could reach to the biosphere. Since the dissolved U interacts with indigenous bacteria under natural and engineered environments over the long storage periods of geologic disposal, it is important to understand the characteristics of U-microbe interactions under the geochemical conditions. In particular, a few of bacteria, i.e., sulfate-reducing bacteria (SRB), are able to reduce soluble U(VI) into insoluble U(IV) under anaerobic conditions by using their metabolisms, resulting in the immobilization of U. In this study, the aqueous U(VI) removal performance and change in bacterial community in response to the indigenous bacteria were investigated to understand the interactions of U-microbe under anaerobic conditions. Three different indigenous bacteria obtained from different depths of granitic groundwater (S1: 44–60 m, S2: 92–116 m, and S3: 234–244 m) were used for the reduction of U(VI)aq. After the anaerobic reaction of 24 weeks, the changes in bacterial community structure in response to the seeding indigenous bacteria were observed by high-throughput 16S rDNA gene sequencing analysis. The highest uranium removal efficiency of 57.8% was obtained in S3 sample, and followed by S2 (43.1%) and S1 (37.7%). Interestingly, SRB capable of reducing U(VI) greatly increased from 4.8% to 44.1% in S3 sample. Among the SRB identified, Thermodesulfovibrio yellowstonii played a key role on the removal of U(VI)aq. Transmission electron microscopy (TEM) analysis showed that the dspacing of precipitates observed in this study was identical with that of uraninite (UO2). This study presents the potential of U(VI)aq removal by indigenous bacteria under deep geological environment.

Mechanism and kinetics of Rhenium complexes as a surrogate of Technetium-99 (99Tc) is worthy of study from radioactive waste safe disposal perspective. Re(IV)-EDTA was synthesized via the reduction of Re(VII) with Sn(II) in the presence of Ethylenediaminetetracetic acid (EDTA). The Re(IV)-EDTA was then degraded by H2O2 (7–30%) at pH of 3–11 in ionic strength I = 0–2 M solution. The Re- EDTA was observed to degrade more rapidly at pH of ≤ 3–4 than one of ≥ 10–11 and remained stable at pH = 7–9. At a low acidic pH, the complex degradation process was facilitated by protonation and corresponded to the exponential model (y = k. e–nt). In contrast, at an alkaline pH, the degradation was facilitated OH– complexation with Re(IV) and corresponded to a linear model (y = –mt + C). Complex degradation followed the zero-order rate kinetics for the H+ and Re-EDTA parameters, apart from a pH of 3, for which degradation was a better fit to first order kinetics. A higher Re(IV)-EDTA stability at a pH of 7–9 demonstrated that Re(IV)-EDTA (or 99Tc(IV)-EDTA) tends to be more persistent in natural environmental conditions.

The criticality analyses considering burnup credit were performed for a spent nuclear fuel (SNF) disposal cell consisting of bentonite buffer and two different types of PWR SNF disposal canister: the KBS-3 type canister and the small standardized transportation, aging and disposal (STAD) canister. The criticality analyses were carried out for four cases as follows: (1) the calculation of isotopic compositions within a SNF using a depletion assessment code and (2) the calculation of the effective multiplication factor (keff) value using a criticality assessment code. Firstly, the KBS-3 type canister containing four SNFs of the initial enrichment of 4.0wt% 235U and discharge burnup of 45,000 MWD/MTU was modelled. The keff values for the cooling times of 40, 50, and 60 years of SNFs were calculated to be 0.74407, 0.74102, and 0.73783, respectively. Secondly, the STAD canister was modelled. The SNFs contained in the STAD canister were assumed to be the enrichment of 4.0wt% and the burnup of 45,000 MWD/MTU. The keff values for the cooling times of 40, 50, and 60 years were estimated to be 0.71448, 0.70982, and 0.70743, respectively. Thirdly, the KBS-3 canister with four SNFs of which the enrichment was 4.5wt% and the burnup was 55,000 MWD/MTU was modelled. The keff values for the cooling times of 40, 50, and 60 years were 0.73366, 0.72880, and 0.72634, respectively. Finally, the calculations were carried out for the STAD canister containing four SNFs of the enrichment of 4.5wt% and the burnup of 55,000 MWD/MTU. The keff values for the cooling times of 40, 50, and 60 years were 0.70323, 0.69946, and 0.69719, respectively. Therefore, all of four cases met the performance target with respect to the keff values, 0.95. The STAD canister showed lower keff values than the KBS-3 canister. This appears to be the neutron absorber plate installed in the STAD canister although the distance among the four SNFs in the STAD canister was shorter than the KBS-3 canister.

The timescale for the post-closure safety assessment of a deep geological repository ranges from ten thousand to a million year. In such a long period of time, the biosphere inevitably undergoes changes. Therefore, the long-term evolution of a biosphere is recognized as an important issue in the post-closure safety assessment of a deep geological repository for spent fuels. In this study, we reviewed the approaches to address the long-term evolution of a biosphere. The major drivers of longterm evolution of a biosphere are the climate change and the resulting landscape development. They can affect the hydrogeological and hydrogeochemical characteristics of a biosphere, and then the radionuclide migration through the biosphere followed by the exposure doses for the critical groups. In addition, human activities and the social developments can affect the climate change resulting in the long-term evolution of a biosphere. To make a biosphere assessment, the long-term evolution scenarios for the biosphere should be formulated considering these climate change, landscape development, and human activities. In addition, features, events, and processes (FEPs) that affect the long-term evolution of a biosphere should be used. According to the Safety Case reports of Finland, the major long-term evolution scenario drivers of a biosphere are local sea-level change due to climate change and land use related to crop type, irrigation procedures, livestock, forest management, construction of a well, and demographics. The climate change causing the local sea-level change can be simulated using various earth system models such as CLIMBER-2, MPI/UW, and UVic and an icesheet model such as SICOPOLIS. The review results of this study and FEPs related to the climate change, the landscape development, and human activities will be used to formulate long-term evolution scenarios for the safety assessment of a deep geological repository for spent fuels.

Deep geological disposal with multiple barriers composed of engineered and natural barriers has been considered as the most suitable disposal method for high level nuclear wastes. In terms of the geological evaluation factors, brittle structures such as fractures and faults should be characterized around the repository site, because radionuclides transfer mainly with groundwater in the subsurface and groundwater flows through discontinuous brittle structures. The geological survey for the characterization of deep geological repository sites is widely conducted by narrowing the survey area from regional scale down to local scale, which could be divided into three steps: 1) using remote sense or geophysical survey, 2) trench and drill core logging including field survey based on the first step, 3) detailed geological survey in the tunnel. In this study, we analyzed the distribution of geological structures to derive the history of brittle deformation in and around the KURT (KAERI Underground Research Tunnel) site located in the KAERI (Korea Atomic Energy Research Institute). The bedrock of the KURT site is mainly consist of Jurassic two-mica granite, which is extensively intruded by andesitic dikes of Cretaceous with N-S to NE-SW strikes. The two-mica granite in the study area was deformed in a ductile deformation environment and has been overprinted by major geological structures such as faults, dikes, veins, and joints. From this study, we identified 8 brittle deformation events based on the cross-cutting relationship among the geological structures, which are obtained from the analyses in and around the KURT. In order to evaluate the reactivation and fluid flow potential of brittle structures, it is essential to determine the characteristics and ages of the brittle structures and the composed rocks around the site.

The operational safety assessment is an important part of a safety case for the deep geological repository of spent fuels. It consists of different stages such as the identification of initiating events, event tree analysis, fault tree analysis, and evaluation of exposure doses to the public and radiation workers. This study develops a probabilistic safety assessment method for the operational safety assessment and establishes an assessment framework. For the event and fault tree analyses, we propose the advanced information management system for probabilistic safety assessment (AIMS-PSA Manager). In addition, we propose the Radiological Safety Analysis Computer (RSAC) program to evaluate exposure doses to the public and radiation workers. Furthermore, we check the applicability of the assessment framework with respect to drop accidents of a spent fuel assembly arising out of crane failure, at the surface facility of the KRS+ (KAERI Reference disposal System for SNFs). The methods and tools established through this study can be used for the development of a safety case for the KRS+ system as well as for the design modification and the operational safety assessment of the KRS+ system.

제8차 전력수급기본계획에 근거하여 현재 운영중이거나 계획중인 원자력발전소에서 발생할 사용후핵연료의 양과 특성을 추정하였다. 본 연구에서 고려된 특성은 핵연료집합체에 대한 제원, 핵연료봉 배열, 235U 초기 농축도, 방출연소도, 냉각기간이다. 이들은 사용후핵연료 처분시스템을 설계하는데 필수적인 항목이다. 2082년까지 가압경수로 사용후핵연료의 예상발 생량은 약 62,500 다발로 추정되었다. 2018년 말까지 발생한 사용후핵연료 중 상대적으로 길이가 짧은 웨스팅하우스형 원전 연료가 약 60%, 상대적으로 길이가 50 cm 정도 긴 한국형 원전 연료가 약 40%를 차지하였다. 235U 초기 농축도 4.5 wt% 이 하를 갖는 사용후핵연료의 비율은 전체 발생량의 약 90%를 차지하였으며, 방출연소도는 98%의 물량이 55 GWd/tU 이하로 나타났다. 2077년을 기준으로 웨스팅하우스형 원전에서 발생한 사용후핵연료의 냉각기간은 50년 이상이 97% 정도를 차지하였으며, 본 논문에서 가정한 처분 완료시점인 2125년을 기준으로 한국형 원전에서 발생한 사용후핵연료의 냉각기간은 45 년 이상이 98% 정도를 차지하는 것으로 나타났다. 이러한 결과를 바탕으로 효율적인 처분시스템 설계를 위해 기준 사용후 핵연료는 제원적 특성을 고려하여 두 가지 형태로 설정하였으며, 웨스팅하우스형 원전 연료의 경우, 집합체 제원으로 KSFA, 초기 농축도 4.5 wt%, 방출연소도 55 GWd/tU, 냉각기간 50년으로, 한국형 원전 연료의 경우, 집합체 제원으로 PLUS7, 초기 농축도 4.5 wt%, 방출연소도 55 GWd/tU, 냉각기간 45년으로 설정하였다.

현재 고려되고 있는 단층 심지층처분장 개념은 부지 소요면적이 지나치게 크기 때문에, 처분밀도를 향상시키기 위한 다층 심지층처분장 개념이 제안되고 있다. 심부암반에 건설된 다층 심지층처분장 주위에 형성된 암반손상대가 심지층처분장의 온도 분포에 미치는 영향이 분석되었다. 다층 심지층처분장의 열해석에는 완충재, 뒤채움재 및 암반에서 일어나는 재포화 현상을 고려한 열-수리 모델이 사용되었다. 암반손상대의 존재는 심지층처분장의 온도 분포에 큰 영향을 미치는 것으로 나 타났으며, 손상대의 크기와 열전도도 저하 정도에 따라 복층 및 삼층 심지층처분장의 최고첨두온도를 각각 최대 7℃와 12℃ 까지 증가시킬 수 있다. 다층 심지층처분장의 첨두온도에 영향을 크게 미치는 인자는 암반손상대에서의 열전도도 저하이며, 처분공 주위에 형성된 암반손상대가 처분터널 주변에 형성된 암반손상대보다 첨두온도에 더 큰 영향을 미친다.

The guarantee of the performance of the engineered barriers in a geological repository is very important for the long-term safety of disposal as well as the efficient design of the repository. Therefore, the performance of the engineered barriers under repository condition should be demonstrated by in-situ experiments conducted in an underground research laboratory. This article provides a review of the major in-situ experiments that have been carried out over the past several decades at underground research laboratories around the world to validate the performance of engineered barriers of a repository, as well as their results. In-situ experiments to study the coupled thermal-hydraulicmechanical behavior of the engineered barrier system used to simulate the post-closure performance of the repository are analyzed as a priority. In addition, in-situ experiments to investigate the performance of the buffer material under a real repository environment have been reviewed. State-of-the art in-situ validations of the buffer-concrete interaction, and the installation of the buffer, backfill and plug, as well as characterization of the near-field rock and the corrosion of the canister materials are, also performed.

본 연구에서는 심지층 처분장 부지선정 시에 고려되는 요소를 지질, 수리지질, 지화학 등으로 분류하고 그 첫 번째 단계로 지질분야의 세부 항목을 지형, 토양층, 암종, 구조지질, 역학적 안정성, 지질학적사건으로 분류하였으며, 이들 항목에 대한 국외 기준분석을 수행하였다. 부지선정요소(Siting factor)에 대한 기준(Criteria)은 각 국가의 처한 지질환경에 따라 다른 조건혹은 값을 제시하고 있다. 화산 및 지진활동이 빈번한 일본에서는 이에 대한 기준을 상대적으로 자세히 기술하고 있으며, 빙하작용이 예상되는 스웨덴에서는 빙하작용에 의한 지반 융기·침식에 대한 영향을 상세히 분석하였다. 따라서, 본 논문 결과는 향후 국내의 심지층 처분장 부지선정 기준 수립시에 중요한 참고자료로 활용될 수 있을 것으로 판단된다.