Magnetically separable and reusable zinc ferrite/reduced graphene oxide ( ZnFe2O4/rGO) nanocomposite has been prepared by hydrothermal method. The results illustrate that the construction of ZnFe2O4 and rGO occur concurrently in a hydrothermal reaction that initiates the formation of rGO-wrapped ZnFe2O4 nanospheres. The morphological and structural features of the ZnFe2O4/ rGO nanocomposites reveal that the rGO nanosheets anchored to the ZnFe2O4 sphere act as a self-protective clamping layer to avoid the photo corrosion effect under photo irradiations. The nanocomposites express the soft magnetic behavior with high saturation magnetization under annealing temperature at 300 °C, which may attribute to the well-defined crystalline structure and surface defects. In addition, the GZF 300 nanocomposites exhibit the enhanced photocatalytic degradation over Rhodamine B dye which is 3.4, 1.15, and 1.32 times higher than that of ZF, GZF, and GZF 600 over under visible irradiation in 120 min. The GZF 300 nanocomposites demonstrate their ability to degrade RhB efficiently, even after several photocatalysis cycles with high catalyst recovery by its magnetically separable behavior. The high densities of oxygen defects improvise electron transfer from ZnFe2O4 to rGO and delay the recombination process of the nanocomposite, resulting in enhanced visible photocatalytic activity. The strong magnetic properties of rGO wrapped ZnFe2O4 nanocomposite catalysts the easy separation from the suspension system for multiple usages in water treatment.

N-doped Na2Ti6O13@TiO2 (denoted as N-NTO@TiO2) composites are successfully synthesized using a simple two-step process: 1) ball-milling of TiO2 with Na2CO3 followed by heat treatment at 900oC; 2) mixing of the prepared Na2Ti6O13 with titanium isopropoxide and calcining with urea at 500oC. The prepared composites are characterized using XRD, SEM, TEM, FTIR, and BET. The N-NTO@TiO2 composites exhibit well-defined crystalline and anatase TiO2 with exposed {101} facets on the external surface. Moreover, dopant N atoms are uniformly distributed over a relatively large area in the lattice of the composites. Under visible light irradiation, ~51% of the aqueous methylene blue is photodegraded by N-NTO@TiO2 composites, which is higher than the values shown by other samples because of the coupling effects of the hybridization of NTO and TiO2, N-doping, and presence of anatase TiO2 with exposed {101} facets.

이 연구는 ‘태양 복사’가 ‘가시광선 복사’로, ‘지구 복사’가 ‘적외선 복사’로 상호 대체될 수 있는 개념인가에 대한 문제 인식에서 출발하였다. 이를 위해 각 개념을 어떻게 인식하고 있는지를 드러낼 수 있는 질문지를 통하여 지 구과학 I을 이수한 고등학생들의 인식을 조사하고, 이들의 인식에 영향을 미칠 수 있는 교과서의 서술 및 삽화를 분석 하였다. 이 연구의 주요 결과는 다음과 같다. 첫째, 조사에 참여한 학생들은 모두 태양 복사를 가시광선 영역에서만 방출되는 복사로 인식하고 있으며, 지구 열수지에서 대류·전도·숨은열을 복사에 의한 에너지 전달로 인식하고 있는 학생 들도 약 35%로 나타났다. 둘째, 2015 개정 교육과정의 지구과학 I 6종 교과서를 분석한 결과, 2종에서는 ‘단파 복사’와 ‘장파 복사’라는 용어를 도입하지만 이들에 대한 설명이 없었으며, 다른 2종에서는 태양 복사를 각각 ‘주로 가시광선 형 태의 복사’ 또는 ‘파장이 짧은 가시광선 복사’로 서술하였다. 그 밖의 2종 교과서에 있는 태양 복사와 지구 복사에 관 하여, 파장 영역에 대한 설명이 없거나 ‘단파장/장파장’이라는 모호한 용어가 사용되었다. 아울러 2종의 교과서에서 열 수지 삽화에 일부 오류가 발견되었다. 따라서 교과서들이 단파 복사와 장파 복사에 관한 정확한 용어 정의 없이 태양 복사와 지구 복사를 설명함에 따라 학습자들은 태양 복사와 지구 복사를 각각 가시광선 복사와 적외선 복사라는 개념 으로 인식할 개연성이 있다. 이를 종합해 보면, 교과서에 기술된 불분명한 진술이나 오류가 학생들의 오개념을 유발하 거나 재생산할 수 있음을 함의한다. 이 연구에서 논의된 바가 지구의 열수지와 복사 평형에 대한 교수·학습 과정의 유 용한 참고 자료로 활용되고, 추후 교과서 집필에서도 합리적인 서술 방안을 제안하는 데 기여할 수 있으리라 기대한다.

To build a highly active photocatalytic system with high efficiency and low cast of TiO2, we report a facile hydrothermal technique to synthesize Ag2Se-nanoparticle-modified TiO2 composites. The physical characteristics of these samples are analyzed by X-ray diffraction, scanning electron microscopy with energy dispersive X-ray analysis, transmission electron microscopy and BET analysis. The XRD and TEM results show us that TiO2 is coupled with small sized Ag2Se nanoplate, which has an average grain size of about 30 nm in diameter. The agglomeration of Ag2Se nanoparticles is improved by the hydrothermal process, with dispersion improvement of the Ag2Se@TiO2 nanocomposite. Texbrite BA-L is selected as a simulated dye to study the photodegradation behavior of as-prepared samples under visible light radiation. A significant enhancement of about two times the photodegradation rate is observed for the Ag2Se@TiO2 nanocomposite compared with the control sample P25 and as-prepared TiO2. Long-term stability of Ag2Se@TiO2 is observed via ten iterations of recycling experiments under visible light irradiation.

단순 침전법으로 제조한 CdZnS/ZnO 광촉매를 이용하여 가시광선하에서 메틸렌블루의 광분해 반응에 대한 연구를 수행하였다. X선 회절분석법과 UV-vis 확산반사 분광법 등을 이용하여 제조된 촉매들의 물리화학적 특성을 분석하였다. 그리고 CdZnS/ZnO 광촉매의 활성을 조사하고 CdS 및 TiO2와 비교 검토하였다. CdZnS/ZnO 광촉매는 자외선뿐만 아니라 400nm에서 600nm 범위의 가시광선 영역에 있어서도 우수한 광흡수 특성을 나타내었다. 가시광선하에서 메틸렌 블루의 광분해 반응에 대해서 CdZnS/ZnO 광촉매는 CdS 와 TiO2 보다 우수한 광촉매 활성을 나타내는 것을 알 수 있었다. 그리고 가시광선하에서의 메틸렌블루의 광분해 반응에는 광촉매 반응뿐만 아니라 감광반응도 관여하고 있음을 확인할 수 있었다.

In this study, photocatalytic degradation of ammonia in petrochemical wastewater is investigated by solar light photocatalysis. Two-dimensional ultra-thin atomic layer structured MoS2 are synthesized via a simple hydrothermal method. We examine all prepared samples by means of physical techniques, such as SEM-EDX, HRTEM, FT-IR, BET, XRD, XPS, DRS and PL. And, we use fullerene modified MoS2 nanosheets to enhance the activity of photochemically generated oxygen (PGO) species. Surface area and pore volumes of the MoS2-fullerene samples significantly increase due to the existence of MoS2. And, PGO oxidation of MB, TBA and TMST, causing its concentration in aqueous solution to decrease, is confirmed by the results of PL. The generation of reactive oxygen species is detected through the oxidation reaction from 1,5-diphenyl carbazide (DPCI) to 1,5-diphenyl carbazone (DPCO). It is found that the photocurrent density and the PGO effect increase in the case with modified fullerene. The experimental results show that this heterogeneous catalyst has a degradation of 88.43% achieved through visible light irradiation. The product for the degradation of NH3 is identified as N2, but not NO2−or NO3−.

Bi2MoO6 (BMO) via the structure-directing role of CO(NH2)2 is successfully prepared via a facile solvothermal route. The structure, morphology, and photocatalytic performance of the nanoflake BMO are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), fluorescence spectrum analysis (PL), UV-vis spectroscopy (UVvis) and electrochemical test. SEM images show that the size of nanoflake BMO is about 50 ~ 200 nm. PL and electrochemical analysis show that the nanoflake BMO has a lower recombination rate of photogenerated carriers than particle BMO. The photocatalytic degradation of tetracycline hydrochloride (TC) by nanoflake BMO under visible light is investigated. The results show that the nanoflake BMO-3 has the highest degradation efficiency under visible light, and the degradation efficiency reached 75 % within 120 min, attributed to the unique hierarchical structure, efficient carrier separation and sufficient free radicals to generate active center synergies. The photocatalytic reaction mechanism of TC degradation on the nanoflake BMO is proposed.

A facile microwave assisted solvothermal process is designed for fabricating SnS nanoparticles decorated on graphene nanosheet, which used as visible light driven photocatalyst. Some typical characterization techniques such as XRD, FT-IR, SEM with EDX analysis, and TEM and BET analysis are used to analyse the physical characteristics of as-prepared samples. Spherical SnS nanoparticles are uniformly dispersed on the surface of graphene nanosheet due to ammonia, which can prevent the aggregation of graphene oxide. Meanwhile, microwave radiation provides fast energy that promotes the formation of spherical SnS nanoparticles within a short time. The visible light photocatalytic activity of as-prepared SnS-GR nanocomposites is analysed through photodegradation efficiency of methylene blue with high concentration. According to the higher photocatalytic property, the as-prepared SnS-GR nanocomposites can be expected to be an efficient visible light driven photocatalyst. After five cycles for decolorization, the rate decreases from 87 % to 78 % (about 9 %). It is obvious that the photocatalytic activity of SnS-GR nanocomposite has good repeatability.

In this paper, AgCl/Ag3PO4/diatomite photocatalyst is successfully synthesized by microemulsion method and anion in situ substitution method. X-ray diffraction (XRD), photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), transmission electron microscopy (TEM), and ultraviolet-visible spectroscopy (UV-Vis) are used to study the structural and physicochemical characteristics of the AgCl/Ag3PO4/diatomite composite. Using rhodamine B (RhB) as a simulated pollutant, the photocatalytic activity and stability of the AgCl/Ag3PO4/diatomite composite under visible light are evaluated. In the AgCl/Ag3PO4/diatomite visible light system, RhB is nearly 100 % degraded within 15 minutes. And, after five cycles of operation, the photocatalytic activity of AgCl/Ag3PO4/diatomite remains at 95 % of the original level, much higher than that of pure Ag3PO4 (40 %). In addition, the mechanism of enhanced catalytic performance is discussed. The high photocatalytic performance of AgCl/Ag3PO4/diatomite composites can be attributed to the synergistic effect of Ag3PO4, diatomite and AgCl nanoparticles. Free radical trapping experiments are used to show that holes and oxygen are the main active species. This material can quickly react with dye molecules adsorbed on the surface of diatomite to degrade RhB dye to CO2 and H2O. Even more remarkably, AgCl/Ag3PO4/diatomite can maintain above 95 % photo-degradation activity after five cycles.

PURPOSES : The purpose of this study is to analyze the impact of the level of the light-environment and the driver's visual ability on the change in the driver's perception of a forward curved section at night. The study also aims to identify factors that should be considered to ensure safety while entering curved sections of a road at night. METHODS : Data collected from a virtual driving experiment, conducted by the Korean Institute of Construction Technology (2017), were used. Logistic regression was applied to analyze the effects of changes in the light-environment factors (road surface luminance and glare) and the driver’s visual ability on a driver's perception of the road. Additionally, analysis of the moderated effect of visual ability on light-environment factors indicated that the difference in drivers’ visual abilities impact the influence of light-environment factors on their perception. A driver's ability to perceive, as a response variable, was categorized into 'failure' and 'success' by comparing the perceived distance and minimum reaction sight distance. Covariates were also defined. Road surface luminance levels were categorized into 'unlit road surface luminance' (luminance ≤ 0.1 nt) and 'lit road surface luminance' (luminance > 0.1 nt), based on 0.1 nt, which is the typical level observed on unlit roads. The glare level was categorized as 'with glare' and 'without glare' based on whether the glare was from a high-beam caused by an oncoming vehicle or not. The driver's visual ability level was categorized into 'low visual ability' (age ≥ 50) and 'high visual ability' (age ≤ 49), considering that after the age of 50, the drive’s visual ability sharply declines. RESULTS : The level of road surface luminance, glare, and driver's visual ability were analyzed to be significant factors that impact the driver's ability to perceive curved road sections at night. A driver's perception was found to reduce when the road surface luminance is very low, owing to the lack of road lighting ('unlit road luminance'), when glare is caused by oncoming vehicles ('with glare'), and if the driver's visual ability level is low owing to an older age ('low visual ability'). The driver's ability to perceive a curved section is most affected by the road surface luminance level. The effect is reduced in the order of glare occurrence and the driver's visual ability level. The visual ability was analyzed as a factor that impacts the intensity of the effect of change of the light-environment on the change of the driver's ability to perceive the road. The ability to perceive a curved section deteriorates significantly in 'low visual ability' drivers, aged 50 and above, compared to drivers with 'high visual ability,' under the age of 49, when the light-environment conditions are adverse with regard to the driver’s perception (road surface luminance: 'lit road surface luminance'→'unlit road surface luminance,' glare: 'without glare'→'with glare'). CONCLUSIONS : Supplementation, in terms of road lighting standards that can lead to improvements in the level of light-environment, should be considered first, rather than the implementation of restrictions on the right of movement, such as restricting the passage of low visual ability or aging drivers who are disadvantageous in terms of gaining good perception of the road at night. When establishing alternatives so that safety on roads at night is improved, it is necessary to consider improving drivers' perception by expanding road lighting installation. The road lighting criteria should be modified such that the glare caused by oncoming traffic, which is an influential factor in the linear change in perception, and the level of light-environment thereof are improved.

In this work, a carbon-doped carbon nitride photocatalyst is successfully synthesized through a simple centrifugal spinning method after heat treatment. The morphology and properties of the prepared photo catalyst are characterized by Xray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV–vis spectrophotometer (UV-vis), and specific surface area. The results show that the band gap of the prepared sample, g-CN-10 is 2.1 eV, is significantly lower than that of pure carbon nitride, 2.7 eV. As the amount of cotton candy increased, the absorption capacity of the prepared catalyst for visible light is significantly enhanced. In addition, the degradation efficiency of Rhodamine B (RhB) by sample g-CN-10 is 98.8 % over 2h, which is twice that value of pure carbon nitride. The enhancement of photocatalytic ability is attributed to the increase of specific surface area after the carbon doping modifies carbon nitride. A possible photocatalytic degradation mechanism of carbon-doped carbon nitride is also suggested.

광촉매는 물에서 유기 염료를 분해하는 친환경적 기술이다. 산화 텅스텐은 이산화 티타늄에 비해 더 작은 밴드갭을 지니고 있어 광촉매 나노물질로서 활발히 연구되고 있다. 계층적 구조의 합성, 백금 도핑, 나노 복합물 또는 다른 반도체 와의 결합 등이 광촉매 분해 효율을 향상시키는 방법들로 연구되고 있다. 이들 방법들은 광 파장의 적색편이를 유도하여 전자 이동, 전자-정공 쌍의 형성과 재결합에 영향을 미친다. 산화 텅스텐의 형태 개질을 통해 앞서 언급한 광촉매 분해 효율을 향상시키는 방법들과 합성에 대해 분석하였으며 금속 산화물과 탄소 복합재를 결합하는 방법이 새로운 물질의 합성이 필요 없으며 가장 효율적인 방법으로 조사되었다. 이러한 광촉매 기술은 수처리 분리막기술과 모듈화하여 정수처리 목적으로 사용 될 수 있다.

K-1계열 전차의 전차장 열상조준경은 주야간 및 연막, 안개 등의 상황에서 포수조준경과 독립적으로 360°회전을 통한 전 방향의 표적 관측과 전차가 정지 및 기동 간 발생하는 진동에서도 조준선을 안정화하여 전차장이 표적의 감지, 식별, 조준 및 추적 할 수 있는 장치이다. 이 장치 의 주요기능 중 하나인 가시상 및 열상을 감지하고 처리하여 최종 영상을 전차장에게 전달하는 것으로 이를 위한 핵심 부품은 주간 및 열상 창이다. 이 핵심 부품은 목표물을 관측하는 광행 로 입구에 장착되어 있으며, 목표물에 대해서 주간에는 가시광, 야간에는 적외선을 통과하여 전 차장 열상조준경의 내부 광학계통으로 전달하는 기능을 수행한다. 이와 같은 핵심부품에 대한 정비는 창 정비 품목으로 선정되어 대부분 재생정비가 아닌 신품 교환 정비를 하고 있는 실정 이다. 즉, 재생정비가 가능한 품목임에도 불구하고 신품교환에 따라 군 예산이 낭비되고 있다. 따라서 본 연구는 평면연마장비와 DLC(diamond-like carbon) 코딩장비를 활용하여 주간 및 열상 창을 연마·코팅할 수 있도록 장착치구를 개발하였다. 또한 재생공정에 대한 검사기준 정립을 포함하여 재생품에 대한 성능검증을 위해 기 발간된 창 정비작업요구서(DMWR) 수정(안)을 제시 하였다.

The present study investigated pine trees, which forms a major plantation species in Korea, with the objective of improving the survival rate of pine trees after planting. Growth responses and characteristics were assessed by controlling the level of fertilizer application, which is a basic controlling the growth of pine seedlings, to identify the optimal fertilization treatment. Pine tree seedlings were grown in 104 containers and were examined 8 weeks after planting. Stem height and were measured at 4-week intervals. In terms of fertilization treatment for 1-0 pine seedlings, the treatment group with gradually-increasing fertilizer concentration (500→1000→1000 →1000mg·L-1) had the biggest increase in stem height and diameter at the root. The survey results indicated that the increased concentration treatment group and the gradually-increasing concentration treatment group had more growth compared with that in the fixed concentration treatment group. The gradually-increasing concentration treatment group (500→1000→1000→1000mg·L-1) had the highest total dry matter production. Nine weeks after fertilization, the tips of the pine leaves turned yellow in the fixed concentration treatment group (3000mg·L-1). The same phenomenon was observed in the treatment group in which the concentration was increased to 2000mg·L-1, and in the gradually- increasing concentration treatment group, when the concentration was raised up to 2000mg·L-1. We concluded that the optimal fertilization conditions for producing healthy pine 1-0 seedlings involve fertilizing once a week with Multifeed 19 at 500mg·L-1 during the seedling period, Multifeed 19 at 1000mg·L-1 during the rapid growth period, and Multifeed 32 at 1000mg·L-1 during the maturation period.

Visible and IR windows require a combination of high optical transparency and superior thermal and mechanical properties. Materials, fabrication and characterization of transparent ceramics for visible/IR windows are discussed in this review. The transparent polycrystalline Y2O3, Y2O3-MgO nanocomposites and MgAl2O4 spinel ceramics are fabricated by advanced ceramic processing and the use of special sintering technologies. Ceramic processing conditions for achieveing fully densified transparent ceramics are strongly dependent on the initial powder characteristics. In addition, appropriate use of sintering technologies, including vacuum sintering, hot-pressing and spark plasama sintering methods, results in outstanding thermal and mechanical properties as well as high optical transparency of the final products. Specifically, the elimination of light scattering factors, including residual pores, second phases and grain boundaries, is a key technique for improving the characteristics of the transparent ceramics. This paper discusses the current research issues related to synthesis methods and sintering processes for yttria-based transparent ceramics and MgAl2O4 spinel.