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폐기물 합성가스 중 염화수소 및 황화수소의 고온 제거 특성 연구 KCI 등재

Study on the Removal of HCl and H2S in Synthesis Gas from Waste Gasification

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한국폐기물자원순환학회지 (Journal of Korea Society of Waste Management)
한국폐기물자원순환학회 (Korea Society Of Waste Management)
초록

We investigated the effect of temperature and pressure in breakthrough performance of various sorbents for dechlorination and desulfurization. Based on the results obtained during the desulfurization (Fe2O3, Fe3O4, ZnO) and the dechlorination (Na2CO3, NaHCO3, trona) screening tests, ZnO and trona were selected as preferred optimum sorbents. H2S breakthrough time corresponds to an effective capacity of approximately 11 g H2S/100 g of sorbent. Also, HCl breakthrough time corresponds to an effective capacity of approximately 5 g HCl/100 g of sorbent. ZnO and trona at high temperature of around 550oC display high sorption performance and removal efficiency for synthsis gas from waste gasification. Although there is an issue of CO2 recovery in hot gas cleanup technology for desulfurization, we have obtained an interesting new alternative hot gas cleanup system with heat budget merit.

저자
  • 김병환((주)대우건설) | Byung-Hwan Kim Corresponding author
  • 김정헌(광운대학교) | Jeong-Heon Kim
  • 김홍열(광운대학교) | Hong-Yeol Kim
  • 유경선(광운대학교) | Kyung-Seun Yoo
  • 구재회(고등기술연구원 플랜트엔지니어링센터) | Jae-Hoi Gu
  • 임용택(고등기술연구원 플랜트엔지니어링센터) | Yong-Teak Lim