In this study, organic electroluminescent devices(OELD) with a structure of a glass substrate/ITO/TPD/Tb(ACAC)3(Phen-Cl)/Alq3/Al was fabricated by vacuum evaporation method, where Tb complex was known to have green light emitting property. Electroluminescent(EL) and I-V characteristics of this structure were investigated. This triple-layer structure shows the green EL spectrum at the wavelwngth of 546nm, which is almost the same as the PL spectrum of Pb(ACAC)3(PhenCl). It was found in current-voltage(I-V) characteristics of the devices that the operating voltage was about 12V.