간행물

한국응용과학기술학회지 KCI 등재 The Korean Society of Applied Science and Technology

권호리스트/논문검색
이 간행물 논문 검색

권호

Vol.15 No.3 (1998년 9월) 13

1.
1998.09 구독 인증기관 무료, 개인회원 유료
Skin whitening agents, possible methods of controlling melanogenesis, and future considerations for skin whitening are discussed with respect to active ingredients and related substances in Japan.
4,300원
2.
1998.09 구독 인증기관 무료, 개인회원 유료
This study was carried out to investigate characteristics and Pb(II) removal effect of natural Muan, Seosan, Kangjin clays in the batch mode test to develope the low-priced treatment agent of wastewater which contain heavy metals in order structural, optical properties and chemical compositions of natural clays from domestic have been investigated to have high specific surface area and have minerals such as SiO2 and Al2O3. As a result, removal effects of Pb(II) ions on clays were reached at equilibrium in aqueous solutions by stirring about 20minutes. The removal effect of Pb(II) ions was best for Seosan clay than Muan or Kangjin clays in terms of fixed time. The results show the possibility of continuous treatment system of wastewater which contain heavy metals by using natural clays from domestic.
4,000원
3.
1998.09 구독 인증기관 무료, 개인회원 유료
Polyvinyl alcohol[PVA] is useful for the production of water-soluble packaging, paper, textile sizes. PVA and Chitosan are known as biodegradable polymers. PVA/chitosan blend films were prepared by solution blends method in the weight ratio of chitosan for the purpose of useful biodegradable films. Thermal and mechanical properties of PVA/chitosan blend films such as DSC, impact strength, tensile strength and morphology by SEM were determined. As a result, The ratio of 10.0wt% PVA/chitosan blend films were similar to PVA. Blend films were completely degraded pH 4.0 better than 7.0, 10.0 in the buffer solution. Also, Blend films were rapidly degraded enzyme(β-glucosidase) solution better than pH solution by Enzymolysis.
4,000원
4.
1998.09 구독 인증기관 무료, 개인회원 유료
Antioxodative substances in Mulberry leaves were examined. Antioxidative substances in Mulberry leaves were extracted by 80% methanol agueous solution. Antioxidative activity of extract was determined by examining hydrogen donating ability on 1,1-diphenyl-2-picrylhydrazyl (DPPH) and the inhibitory effect on the formation of the peroxide from Linoleic acid in the test tube at 50℃. Antioxidative substance were, then, separated and indentified by thin layer chromatography(TLC), UV-Vis spectrum and High performance liquid chromatography(HPLC) methods. Hydrogen donating ability on DPPH and antioxidative ability on linoleic acid of the extracted antioxidative substance were higher than those of 100ppm butylated hydroxy toluene(BHT). The extracted antioxidative substances were separated by TLC using ethylacetate : chloroform : formic acid : water(8 : 1 : 1 : 1 v/v) as a solvent, and a spot at Rf=0.35 was detected. The spot was scraped from the plate, and extrated by methanol. The extract was analyzed by UV-Vis spetra and HPLC, and chlorogenic acid was identified as a antioxidative substance.
4,000원
5.
1998.09 구독 인증기관 무료, 개인회원 유료
The hardening test of gelatin with 2,4-dichloro-6-hydroxy-1,3,5-triazine mono sodium salt was studied at pH 5, 7, 8 and about increasing temperature, respectively. The hardener was prepared by the reaction of cyanuric chloride with sodium hydroxide, disodium hydrogenphosphate-12-water and trisodium phosphate-12-water in the presence of water. The product was identified by elemental analyzer. IR spectrophotometer. Novel hardener can be used in photographic emulsion and showed very good hardening effect.
4,000원
6.
1998.09 구독 인증기관 무료, 개인회원 유료
In recent years, there has been considerable interest in the development of new functional surfactant including new type of anionic surfactants. Anionic surfactants, α-sulfo fatty acids that straight long chain alkyl group having from 12 to 18 carbon atoms, were synthesized with sulfur trioxide-dioxane complex to good yield. Xylitol α-sulfo fatty acid esters were obtained by reaction that the acetification and esterification of xylitol, by addition reaction with sodium chloride and hydrolysis respectively. These compounds were a new group of destructible surfactants which readily hydrolyzed and oxidized in natural water reservoirs. Physical properties of these new compounds involved surface tension, critical micelle concentration(cmc), foaming power, emulsion power, and hydrolysis properties, were measured. The cmc values of the compounds by ring method were assumed to 7.0×10-3~3.0×10-2mol/l range and surface tensions at cmc were 25~31dyne/cm respectively.
4,000원
7.
1998.09 구독 인증기관 무료, 개인회원 유료
The polyimide film surface was modified with KOH aqueous solutions or sulfuric acid. The film thickness was increased by about 10% through the modification of film surface. Hydrolysis of amide bonds and hydration of water induced the increase. The polarity of the film surface increased and identified by contact angle measurement. The depth and roughness of modified was increased. After treatment of surface with water, alkyl and 4-pentyloxyaniline were introduced on the film surface by complex formation between anionic species formed on the imide surface and ammonium ion. The newly introduced alkyl group was identified by FT-IR spectroscopy. Surface polarity reduced dramatically and the roughness was increased after introduction of ammonium salt.
4,000원
8.
1998.09 구독 인증기관 무료, 개인회원 유료
The sodium α-sulfo fatty acid vinyl ester oligomers, which are oligomer type surfactants were prepared by polymerization with fatty acid vinyl acetate. The α-sulfonation of fatty acid vinyl ester oligomers were carried by direct addition of sulfur trioxide. The dispersing performance of oligomer type anionic surfactants and sodium dodecyl sulfate(SDS) in the aqueous suspension of iron oxide and titanium dioxide particles was evaluated by particle size distribution and zeta-potential measurement. As results, the particles of iron oxide and titanium dioxide were flocculated by addition of small amount of oligomer type anionic surfactants and sodium dodecyl sulfate(SDS), then the flocks redispersed by more addition of oligomer type anionic surfactants and SDS. The flocculation, redispersion process was observed in lower concentration range of oligomer type anionic surfactants than SDS. Especially, the dispersing action of sodium α-sulfo palmitic acid vinyl ester oligomer was better than sodium α-sulfo lauric acid vinyl ester oligomer.
4,000원
9.
1998.09 구독 인증기관 무료, 개인회원 유료
Cyclodextrin are obtained from starch by enzymatic degradation. The three best characterize forms are α, β, γ cyclodextrin consisting of 6, 7, and 8 D-glucose units, respectively. Each of the glucose units are in the rigid C1 chair conformation and are linked by α 1,4 bonds. This geometry gives the cyclodextrin the shape of a hollow truncated cone with the wider side formed by the secondary 2- and 3-hydroxy groups and the narrower side by the primary 6-hydroxy group. The most characteristics property of the cyclodextrin is their ability to form inclusion complexes with a wide range of guest moleculars. We syntheses per-6-substituted β-cyclodextrin derivatives and investigate structures, spectrospcopic properties. The substituted materials are piperidine, piperazin, morphorine. The synthetic compound showed a good solubility than natural β cyclodextrin in organic solvents such as methylene chloride, methanol, ethanol, etc.
4,000원
10.
1998.09 구독 인증기관 무료, 개인회원 유료
Polyoxyethylene monooleate was prepared by addition of ethylene oxide to oleic acid. And also, polyoxyethylene monooleate type oil dispersant was prepared by blending polyoxyethylene monooleate, n-paraffine, sorbitan monooleate, sorbitan monopalmitate, and palm oil. Dispersion efficiency test was carried out by vertical shaking flask and swirling flask methods. Low toxic oil dispersant was prepared with polyoxyethylene monooleate, which has high biodegradability and excellent dispersion efficiency on crude oils and weathered W/O emulsions with high viscosity, and its dispersion efficiency was measured to various crude oils and weathered oils.
4,000원
11.
1998.09 구독 인증기관 무료, 개인회원 유료
Two-component polyurethane flame retardant coatings were prepared by blending phosphate-containing modified polyesters(PMPEs) and TDI-adduct. PMPEs were synthesized by polycondensation of dimethyl phenylphosphonate, a flame retardant component, with 1,4-butanediol, adipic acid, and trimethylolpropane. The content of dimethyl phenylphosphonate was varied 10, 15, and 20wt% for the reaction. Various physical properties of these new flame retardant coatings were comparable to non-flame retardant coatings. Coatings with 20wt% dimethyl phenylphosphonate did not burn during the vertical burning test.
4,000원
12.
1998.09 구독 인증기관 무료, 개인회원 유료
In this study, organic electroluminescent devices(OELD) with a structure of a glass substrate/ITO/TPD/Tb(ACAC)3(Phen-Cl)/Alq3/Al was fabricated by vacuum evaporation method, where Tb complex was known to have green light emitting property. Electroluminescent(EL) and I-V characteristics of this structure were investigated. This triple-layer structure shows the green EL spectrum at the wavelwngth of 546nm, which is almost the same as the PL spectrum of Pb(ACAC)3(PhenCl). It was found in current-voltage(I-V) characteristics of the devices that the operating voltage was about 12V.
4,000원
13.
1998.09 구독 인증기관 무료, 개인회원 유료
The saturated fatty acids(arachidic acid, stearic acid, and palmitic acid) were repeatedly applied on water surface, and their π-A isotherms and Maxwell displacement current(MDC) were measured to identify the effect of the number of carbons of fatty acids on the properties of Langmuir films. The saturated fatty which contain higher carbon number showed higher MDC peak, and the less carbon it contains, the higher surface pressure they show. It was found the maximum of MDC peaks was as the molecular area just before the surface pressure increases in compression cycles of saturated fatty acids.
4,000원