간행물
한국응용과학기술학회지 KCI 등재 The Korean Society of Applied Science and Technology
- 발행기관 한국응용과학기술학회(구 한국유화학회)
- 자료유형 학술지
- 간기 격월간
- ISSN 1225-9098 (Print)2288-1069 (Online)
- 수록기간 1984 ~ 2023
- 주제분류 공학 > 화학공학 공학 분류의 다른 간행물
- 십진분류KDC 575DDC 665
권호리스트/논문검색
Vol.24 No.4 (2007년 12월) 15건
1.
2007.12
구독 인증기관 무료, 개인회원 유료
The aim of this study is to enhance the flame retardancy by the synergism effect of phosphorus and bromine groups. The flame-retardant polyurethane coatings containing phosphorus and bromine compounds were synthesized. After synthesizing the intermediate products of tetramethylene bis(orthophosphate) (TBOP) and trimethylolpropane/2,3-dibromopropionic acid (2,3-DBP) [2,3-DBP-adduct], the condensation polymerization was performed with four different monomers of two intermediate products, 1,4-butanediol, and adipic acid to obtain four-components copolymer. In the condensation polymerization, the content of phosphorus was fixed to be 2wt%, and the content of 2,3-DBP that provides bromine component was varied to be 10, 20, and 30wt%, and we designated the prepared modified polyesters containing phosphorus and bromine as DTBA-10C, -20C, -30C. Average molecular weight and polydispersity index of the preparation of DTBAs were decreased with increasing 2,3-DBP content because of increase of hydroxyl group that retards reaction. We found that the thermal stability of the prepared DTBAs increased with bromine content at high temperature.
4,500원
2.
2007.12
구독 인증기관 무료, 개인회원 유료
Based on the experiment results of laboratory scale modified anoxic-oxic process for leachate treatment, biological nitrogen removal program was verified in terms of SS, COD, and TN concentration. These measured water qualities concentration could be predicted by biological nitrogen removal program with R2 of 0.994, 0.987, 0.990, respectively. No error was occurred between water qualities concentration and quite wide range of water qualities concentration (i.e., 50-4200 mg/L) during the modelling. Each unit and final effluent of simulated concentration was kept good relationship with that of measured concentration therefore this biological nitrogen removal program for sewage or wastewater treatment plants has good reliance.
4,000원
3.
2007.12
구독 인증기관 무료, 개인회원 유료
The influence of adding urea to phenol-formaldehyde (PF) resins as a co-polymer component were investigated aiming at synthesizing useful phenol-urea-formaldehyde resins. Urea was added at 10% by total resin weight. Several methods for the addition of urea to the PF resins during synthesizing resins to see the co-polymerization occurs between urea and PF resins. The urea was added at the beginning, at three different middle stages, and at the end of PF resin synthesis. The copolymerized methylene bridges between phenol and urea molecules were not observed by 13C-NMR; no signal around 50ppm. The curing of urea-modified PF resins, evaluated by dynamic mechanical analysis(DMA), showed some differences among the resins. DMA gel times ranged from 2.75 min to 3.25 min and the resins made with earlier urea additions showed slightly shorter gel times. The longest cure time and gelation time was observed for the resin PFU. Catalyst effects on the DMA cure time values of resins were not significant with different amounts of catalyst or different types of catalyst for all resins tested. Gel times of urea-modified PF resins shortened the most by triacetin catalyst
4,000원
4.
2007.12
구독 인증기관 무료, 개인회원 유료
Fleshing scrap is a kind of wastes produced during leather making process and used in the test of manufacturing biodiesel. The early step of manufacturing biodiesel is fat recovery from fleshing scrap. Hence, we investigated the influence of the way of fat recovery on the fatty acid composition. We used three different recovery ways, that is chemical method by protein decomposition with acid/fat recovering, physical method by protein denaturalization with heat and vacuum/fat pressing, and biodiesel method by protein decomposition/fat recovering. The biological method yielded the best results in terms of appearance transparency. It was most effective to lower acid value. Also the recovered fat by biological method would be favorable methyl-ester reaction raw material for biodiesel because it contains more than 5% of oleic acid among unsaturated fatty acid.
4,000원
5.
2007.12
구독 인증기관 무료, 개인회원 유료
The distribution of light in a randomly scattering medium can represent problems found in many area. Particularly, in the clinical application of lasers for Photodynamic therapy(PDT) or in the fluorescence spectroscopy for biological tissue, turbidity plays a very important role. The influences of fluorophor, scatterer, and absorber in turbid material by light scattering were interpreted for the scattered fluorescence intensity and wavelength. The molecular properties have been studied by laser induced fluorescence spectroscopy in scattering medium as tissue. It has been found that the effects of optical properties in scattering media could be investigated by the optical parameters(μs, μa ,μt). Experimental and Monte Carlo simulation method for modelling light transport in tissue was applied. The experimental results using a randomly distributed scattering medium were discussed and compared with those obtained through Monte Carlo simulation. It'll be also important in designing the best model for oil chemistry, medicine and application of medical engineering.
4,000원
6.
2007.12
구독 인증기관 무료, 개인회원 유료
To study the relationship between elementary biochemical states and structural states of the actomyosin crossbridges in muscle, the effects of binding of MgADP to myosin heads in the rigor muscle were examined by X-ray diffraction using synchrotron radiation. X-ray diffraction studies have been made to investigate the effects of binding of ADP on the structure of glycerinated rabbit skeletal muscle in the rigor state. The intensity increase was accompanied by a slight but distinct decrease in the 5.9 am layer-line intensity close to the meridian. These results strongly suggest that myosin heads altered their attached conformation in the proximal end toward the plane perpendicular to the fiber axis when MgADP was bound to them. We found that the intensity of the 14.5 nm-based meridional reflections increase by 20-50% when MgADP was added to the rigor muscle in the presence of hexokinase and myokinase inhibitor.
4,000원
7.
2007.12
구독 인증기관 무료, 개인회원 유료
우리는 마이카, boron nitride, bismuthoxychloride와 같은 판상 분체에 ZnO 나노입자를 코팅한 고 기능성 무기 분체를 합성하였다. 본 실험에서 우리는 수열침전법을 이용하여 합성 분체를 합성하였다. 출발물질은 ZnCl2를 사용하였고 침전제로는 hexamethylenetetramine(HMT)와 urea를 사용하였다. 본 실험의 반응변수로는 출발물질의 농도, 침전제 및 반응온도를 변화시켜 실험하였다. 합성물의 형태, 결정성 및 UV-차단능은FE-SEM, XRD, FT-IR, TGA-DTA, in vitro SPF 테스트를 활용해 분석하였다. 본 실험의 결과, 나토입자 크기를 갖는 ZnO는 동일한 최적의 합성조건하에서 다양한 판상 분체의 종류에 관계없이 균일하게 코팅되었다.
4,000원
8.
2007.12
구독 인증기관 무료, 개인회원 유료
We designed capacitance sensor in order to examine characteristics of W/O type emulsified fuel, so it concluded the following conclusions. The capacitance value of emulsified fuel, using with capacitance sensor, increases as water content increases due to the coalescence. When surfactant increases, the capacitance value decreases, the condition of W/O type emulsified fuel was maintained stably. There was revealed the capacitance value difference of W/O type emulsified fuel in in according to water content. We checked the phase separation of emulsified fuel with the capacitance value difference. The surfactant(HLB=5.4) had better stable condition than surfactant(HLB=4.3). Also, we confirmed that two mixture surfactants were better than one surfactant.
4,000원
9.
2007.12
구독 인증기관 무료, 개인회원 유료
This paper is studied on the efficient purification process of dimethyl carbonate (DMC) from the melt layer crystallization combining crystallization process, sweating process and distillation recovery process. Purity and yield of DMC crystal depended mainly on the crystallization temperature, cooling rate, sweating termperature sweating rate. Through the optimization of crystallization and sweating operation, DMC crystal can be upgraded to very high purity over 99.9% and high yield over 85%.
4,000원
10.
2007.12
구독 인증기관 무료, 개인회원 유료
We investigated heat stability of epoxy resin products and epoxy resin according to the influence hardener. The heat flow which shows the degree of thermal decomposition of the epoxy resin product and epoxy resin measured by using the differential scanning calorimeter (DSC). As a result, we found that in the case of heat stability for epoxy resin as hardener was added, the ratio of one to one (epoxy resin : hardener) was the most suitable in air condition and nitrogen atmosphere.
4,000원
11.
2007.12
구독 인증기관 무료, 개인회원 유료
Characteristics of polyaniline anti-corrosive coatings with various primer coating resins(epoxy resin, urethane resin, and others) and top coating resins(epoxy and acrylic urethane resins) were investigated through adhesion, acid resistance, alkaline resistance, water resistance, and anti-corrosion tests. As a result, the anti-corrosive properties of the prepared coatings using polyaniline varied with the types of primer and top coating resins. In this condition, the properties of adhesion, chemical resistance, and water resistance were found to be very satisfactory when using emeraldine base (EB) of polyaniline blended with single-packaged urethane and acrylic urethane resins as the primer coatings, and using acrylic urethane resin as the top coatings. Also, the anti-corrosive function of these anti-corrosive coatings was well preserved for 1000 hr in the salt spray experiment.
4,200원
12.
2007.12
구독 인증기관 무료, 개인회원 유료
Functional cosmetics are intensively investigated for the effectiveness of skin whitening, anti-aging and slimming. For enhancing the effectiveness, active ingredients should be delivered into the cell in the dermis. The amounts of penetration of caffeine and Arbutin® were tested, in vitro, using Franz diffusion cell. Oil-in-water emulsions were used for the vehicles of the transport. For the measuring the amounts of active ingredients delivered into the dermal skin, tape stripping was done after finishing the penetration experiments. The amounts of delivered caffeine were 8.45± 1.26ug/ml before tape stripping and 3.45± 1.80ug/ml after tape stripping, however, the amounts of delivered Arbutin® was quite small to detect. From now on, proper vehicles are considered for enhancing the delivery of Arbutin® Hairless mouse skin was compared with pig skin as a transdermal delivery membrane. The aspects of delivery were similar, but the amount of delivered ingredients using pig skin was larger than that of using hairless mouse skin. Therefore, the pig skin would be considered as a membrane for drug delivery experiments.
4,000원
13.
2007.12
구독 인증기관 무료, 개인회원 유료
Polypropylene (PP) composites with wood flour/wax/coupling agent were manufactured by melt compounding and injection molding. The influence of wood flour(WF), wax, and coupling agent on the mechanical and thermal properties of the composites was investigated. The addition of wood flour to neat PP has the higher tensile modulus and strength compared with neat PP. The presence of wax also improved the tensile modulus. At the same loading of PP and WF, the addition of coupling agent highly decreased the tensile modulus, and increased the tensile strength. From thermogravimetric analysis (TGA), the addition of wax improved the thermal stability of the composites in the later stages of degradation. The presence of MAPP and wood flour in turn decreased thermal stabilities of composites. From differential scanning calorimetry analysis (DSC), neither the loading of wax. nor the presence of MAPP has shown significant effect on the thermal transition of composites.
4,200원
14.
2007.12
구독 인증기관 무료, 개인회원 유료
에너지원으로서 수소를 생산하기 위하여 하니컴 구조를 갖는 모노리스에 10 wt% Ni/CeO2-ZrO2 촉매를 담지한 후 메탄의 수증기 개질 실험을 수행하였다. 다른 CeO2/ZrO2 몰비를 갖는 촉매들 중에서, Ni/CeO2-ZrO2(CeO2/ZrO2=4/1)촉매가 700-800℃에서 높은 메탄의 전환율을 보여 주었다. 10wt% Ni/CeO2-ZrO2 촉매가 담지된 금속 모노리스 촉매체는 높은 열전도도와 비표면적들로 인하여 좋은 촉매 특성을 보여줌을 확인할 수 있었다. 또한, 금속모노리스 촉매체는 반응물에서 과다의 수증기에 의한 수소 수율에서 크게 영향을 받지 않음을 알 수 있었다. GHSV=30,000h-1, 반응물 비(H2O/CH4=3.0) 반응온도 800℃에서 금속모노리스 촉매체는 98%이상의 메탄의 전환율을 보여주었다. 생성물 가스에서 CO2/CO의 비는 수증기/메탄의 반응물비가 증가할수록 수성가스화 반응에 의하여 증가됨을 알 수 있었다.
4,000원
15.
2007.12
구독 인증기관 무료, 개인회원 유료
Anaerobic reductive dehalogenation of perchloroethene (PCE) was studied with lactate as the electron donor in a continuously stirred tank reactor (CSTR) inoculated with a mixed culture previously shown to dehalogenate vinyl chloride (VC). cis-1,2- dichloroethene (cDCE) was the dominant intermediate at relatively long cell retention times (〉56 days) and the electron acceptor to electron donor molar ratio (PCE:lactate) of 1:2. cDCE was transformed to VC completely at the PCE to lactate molar ratio of 1:4, and the final products of PCE dehalogenation were VC (80%) and ethene (20%). VC dehalogenation was inhibited by cDCE dehalogenation. Propionate produced from the fermentation of lactate might be used as electron donor for the dehalogenation. Batch experiments were performed to evaluate the effects of increased hydrogen, VC, and trichloroethene (TCE) on VC dehalogenation which is the rate-limiting step in PCE dehalogenation The addition of TCE increased the VC dehalogenaiton rate more than an increase in the H2 concentration, which suggests that the introduction of TCE induces the production of an enzyme that can comtabolize VC.
4,000원
