간행물
한국응용과학기술학회지 KCI 등재 The Korean Society of Applied Science and Technology
- 발행기관 한국응용과학기술학회(구 한국유화학회)
- 자료유형 학술지
- 간기 격월간
- ISSN 1225-9098 (Print)2288-1069 (Online)
- 수록기간 1984 ~ 2024
- 주제분류 공학 > 화학공학 공학 분류의 다른 간행물
- 십진분류KDC 575DDC 665
권호리스트/논문검색
Vol.24 No.2 (2007년 6월) 13건
1.
2007.06
구독 인증기관 무료, 개인회원 유료
The cosmetic and toiletries are necessary health care & household for common life. However we need antiseptic which is effecting harmlessly to the human body. There are propolis, Lavender, Lemon, essential oil in the natural antiseptic materials. This work proceeded design Natural-antiseptic system with three materials as above-mentioned. Natural-antiseptic system was accomplished with propolis (2%), Lavender essential oil (0.3%), Lemon essential oil (0.3%) safety out of Polysorbate 20 (0.5%), Polysorbate 80 (0.5%), PEG (60) hydrogenated castor oil (0.45%), ethanol (5%). The antimicrobial test was experimented on E. coli and Bacillus stearothermophilus. In this antimicrobial test, we found that the effect of antisepsis against E. coli and Bacillus stearothermophilus with propolis 0.3%, Lavender essential oil 0.045% and Lemon essential oil 0.045% was improved. Therefore could expect Natural-antiseptic system product for moisturizing skin toner for face, nourishing essence and wet tissue for clean other things.
4,000원
2.
2007.06
구독 인증기관 무료, 개인회원 유료
2-Chlorobenzoyl hydrazine refluxed with benzoyl isothiocyanate and phenyl isothiocyanate in ethanol for 3 hours to give benzamide derivative (1) and anilinederivative (2) on yield of 71%and 95%, respectively. Benzamide derivative (1) reacted with ethanolic sodium hydroxide on reflux to afford cyclization product (3), followed by general substitution reaction of two steps to give acetamide (5), and derivatived acetamides 7a-7k, while aniline derivative (2) reacted with ethanolic sodium hydroxide on reflux to afford another cyclization product (4). Thiol (4) reacted with N-phenyl chloroacetamide in the presence of potassim carbonate to give acetamide derivative (6). Compounds 1-7kwere evaluated for their growth inhibition against five cancer cell lines, including human lung carcinoma (A-549), human prostate cancer (DU145), human colon adenocarcinoma (HT-29), human malignant melanoma (SK-MEL-2) and human ovary malignant ascites (SK-OV-3) with sulforhodamine B (SRB) assay. All compounds (1-7k) showed low inhibition activities under 50% on 100M concentration.
4,000원
3.
2007.06
구독 인증기관 무료, 개인회원 유료
4,000원
4.
2007.06
구독 인증기관 무료, 개인회원 유료
In order to obtain the maximum flame retardancy with the minimal deterioration of physical properties of PU flame-retardant coatings, chlorine and phosphorous functional groups were introduced into the pre-polymer of modified polyesters. In the first step, the tetramethylene bis(orthophosphate) (TBOP) and neohexanediol dichloroacetate (DCA-adduct) intermediates were synthesized. In the second step, 1,4-butanediol and adipic acid monomers were polymerized with the two kind of intermediates to obtain copolymer. The modified polyesters containing chlorine and phosphorous (ATBA-10C, -20C, and -30C) were synthesized by adjusting the contents of chlorine compound (dichloroacetic acid, 10, 20, 30 wt%) with fixed the content of phosphorous compound (2 wt%). The PU flame-retardant coatings (TTBAH -10C, -20C, and -30C) were prepared using the synthesized ATBAs and HDI-trimer as curing agent at room temperature. The physical properties of PU flame-retardant coatings with chlorine and phosphorous were inferior to those with phosphorous only and the properties were getting worse with increasing chlorine content. Flame retardancy was tested with three methods. With the vertical method, Complete combustion time of ATBAHs were 259~347 seconds, which means that the prepared coatings are good flame-retardant. With the 45˚ Meckel burner method, char lengths of the three prepared coatings were less than 2.9 cm, which indicates that the prepared coatings are 1st grade flame retardancy. With the limiting oxygen index (LOI) method, the LOI values of the three prepared coatings were in the range of 30~35%, which proves good flame retardancy of the prepared coatings. From the results of flame retardancy tests of the specimens that contain the same amounts of flame retarding compounds, it was found that the coatings containing both phosphorous and chlorine show higher flame retardancy than the coatings containing phosphorous alone. This indicates that some synergy effect of flame retardancy exists between phosphorous and chlorine.
4,900원
5.
2007.06
구독 인증기관 무료, 개인회원 유료
As an additional high purification method of p-dioxanone monomer for a high molecular weight polymer, the sweating operation of crystalline layer obtained by layered melt crystallization from p-dioxanone-diethylene glycol system was studied. Purity and yield of p-dioxanone crystal depended mainly on the sweating temperature and sweating time. Increasing sweating time and sweating temperature, the purity of p-dioxanone crystal increase, whereas the yield of that decrease, respectively. Through the optimization of sweating operation, p-dioxanone crystal can be upgraded to very high purity over 99.9 % suited to monomer for polymerization.
4,000원
6.
2007.06
구독 인증기관 무료, 개인회원 유료
In order to prepare high-solid coatings, acrylic resins, HSCs [poly (EA/EMA/2-HEMA/CLA)] that contain 90% solid, were synthesized by copolymerization of ethyl acrylate (EA), ethyl methacrylate (EMA), 2-hydroxyethyl methacrylate (2-HEMA) and caprolactone acrylate (CLA). The high-solid coatings named as CHSCs (HSCs/HDI-trimer) were prepared by the curing reaction between the acrylic resins containing 90% solid contents and the isocyanates (HDI-trimer) curing agent room temperature. The curing behavior and various properties were examined on the film coated with the both high-solid coatings. The glass transition temperatures (Tg) of CHSCs increased proportionally with increasing the predicted Tg value by Fox equation, and had nothing to do with the solid contents. The prepared film showed good properties for 60˚ specular gloss, impact resistance, cross-hatch adhesion and heat resistance, and bad properties for pencil hardness, drying time, and pot-life. Among the film properties, the heat resistance was very excellent and could be explained by the introduction of functional monomers of CLA.
4,200원
7.
2007.06
구독 인증기관 무료, 개인회원 유료
The rheological properties and surface tensions of polymer solutions and polymer-surfactant mixed solutions were investigated. The polymers used in this study were a homopolymer of acrylic acid crosslinked with an allyl ether of pentaerythritol, an allyl ether of sucrose, or an allyl ether of propylene (CARBOMER), acylate/C10-30 alkyl acylate crosspolymer (AAAC), and ammonium acryloydimethyltaurate/VP copolymer (ADTV). A solubilizing agent PEG-40 hydrogenated castor oil (HCO-40) and an emulsifying agent polyoxyethylene (20) sorbitan monostearate (POLYSORBATE 60) made the micelles intervening between AAAC polymers, resulting in the increase of viscosity. However, HCO-40 made this behavior over the wider range of surfactant concentration than POLYSORBATE 60. From the view point of surface tensions in the same range of surfactant concentration, AAAC/HCO-40 solution showed the area of increasing surface tension with surfactant concentration in contrast to the AAAC/POLYSORBATE 60 solution showing no increasing area.
4,000원
8.
2007.06
구독 인증기관 무료, 개인회원 유료
The surface of poly(ethylene naphthalate) film applicable to high temerature insulator for convection microwave oven was modified with silicone coating solutions in the presence of silane crosslinking agent. The structure and properties of the PEN films were investigated by using Fourier transform IR spectroscopy, viscometry, microscopy, and tensile tests. The experimental results showed that the coating with silicone enhanced thermal stability up to 200℃, and slightly lowered the tensile strength and elongation of the PEN films. Judging from dimensional stability results the silicone coated PEN films can not be used for higher temperature insulator above 230℃. Serious dimensional contraction of films was obtained during heat treatment at 250℃ even for 1h. However, the surface of those films still have same chemical structure of silicones. Therefore, If we use PEN film prestretched at 230℃ as base one it will be possible to prepare a high temperature insulator up to 230℃. Conclusively, a silicone coated PEN film can be suitable for the application to convection microwave oven door insulator at high temperature up to 230℃.
4,000원
9.
2007.06
구독 인증기관 무료, 개인회원 유료
본 연구에서는 졸-겔 공법을 이용하여 가스 차단 특성을 갖는 SiO2/EVOH(에틸렌 비닐알콜 공중합체) 하이브리드 물질을 제조하였다. 제조된 여러 조성의 하이브리드 졸을 표면 처리한 biaxially oriented polypropylene (BOPP) 기지재에 스핀 코팅 방식을 이용하여 코팅하였다. X선 회절 및 DSC 분석에 의해 하이브리드 내의 EVOH 상과 실리카 상 사이의 결합에 따른 결정화 거동의 변화를 조사하였다. 또한 SiO2/EVOH 하이브리드 겔의 모폴로지 관찰을 통하여, 100nm 이하의 실리카 입자들이 균열하게 분산된 매우 치밀한 상 미세구조를 갖는 하이브리드 물질을 제조하기 위해 필요한 Tetraethylorthosilicate (TEOS) 무기전구체의 최적 함량이 존재함을 알 수 있었다. 첨가된 TEOS 함량이 최적 함량보다 낮거나 높은 경우에는 큰 도메인의 입자 클러스터들이 형성되어 매우 불안정한 모폴로지를 나타내는 상분리 현상이 관찰되었다. 이러한 모폴로지 결과는 하이브리드 코팅 필름의 산소 투과도의 변화 결과와 일치하였는데, TEOS 함량이 0.01 - 0.02mol로 첨가되어 제조된 하이브리드로 코팅된 필름의 경우 매우 우수한 산소 차단 특성을 나타냈으며, 0.04mol 이상으로 첨가되었을 때는 상 분리 및 미세 균열 발생으로 인하여 그 차단 특성이 급격하게 감소하는 것으로 나타났다.
4,000원
10.
2007.06
구독 인증기관 무료, 개인회원 유료
Used polyurethane was chemically degraded by treatments with flame retardants such as tris(3-chloropropyl) phosphate (TCPP), triethyl phosphate (TEP), and trimethyl phosphate (TMP). The structure of degraded products (DEP) was analyzed by FT-IR and P-NMR and it turned out to be phosphorus containing oligourethanes. Rigid polyurethane foam was produced by using the degraded products (DEP) as flame retardants. The flammability of recycled rigid polyurethane was investigated. The recycled polyurethane shows a reduced flammability over virgin polyurethane. In order to evaluate flame retardant properties of the recycled polyurethane foams with various amounts of DEP, the combustion parameters of the foam was measured by a cone calorimeter. Scanning electron micrograph of recycled PU shows the same uniform cell morphology as virgin PU.
4,000원
11.
2007.06
구독 인증기관 무료, 개인회원 유료
The transesterifications of beef tallow and the mixture of beef tallow and rapeseed oil were conducted at 65℃ respectively using TMAH, NaOH and their mixed catalysts. The reactants were emulsified with 1vol% emulsifier and propylene glycol. The overall conversion of beef tallow was 95% at such optimum conditions as the 1:8 of molar ratio and 0.8 wt% TMAH. The overall conversion of mixed fat at the 1:8 of molar ratio and mixed catalyst of 70 wt% TMAH 30 wt% NaOH was close to 97% which appeared at 0.8 wt% TMAH in 80min. And the kinematic viscosity of biodiesel mixture using the mixed catalyst was 6.5mm2/s at 40℃.
4,000원
12.
2007.06
구독 인증기관 무료, 개인회원 유료
The objective of this study was to determine the effect of dietary oils on the levels of the γ-linolenic acid in chicken meat lipids. Three hundred ten five, 1-d old, male, Ross strain, broiler chicks were fed for 35 d to compare diets containing evening primrose oil(EPO) and hemp seed oil(HO) to a control diet. Fatty acid composition of lipid from chicken skin, thigh and breast muscle were determined at the end of the trial. The level of γ-linolenic acid of lipids from chicken meat fed diets containing EPO or HO was significantly higher than that of the control group(p〈0.05). The level of γ-linolenic acid of lipids from chicken skin was highest in the group, which had been fed the EPO 0.85%, followed in order by EPO 0.7%, 0.5%, EPO mixed oil, HO and HO mixed oil. There was a significant difference in the level of γ-linolenic acid of chicken skin between the control and treatment groups(p〈0.05). The level of γ-linolenic acid of lipids from chicken thigh muscle was also similar to skin, and significantly higher than that of the control group(p〈0.05). The level of γ-linolenic acid of lipids from chicken breast muscle was highest in the group, which had been fed the EPO 0.5%, followed in order by EPO 0.7%, 0.85%, HO 0.5% and HO mixed oil. There was a significant difference in the level of γ-linolenic acid of chicken breast muscle between the control and treatment groups(p〈0.05).
4,000원
13.
2007.06
구독 인증기관 무료, 개인회원 유료
In this paper, we describe a study on the relationship between neutral emulsion manufacture and hardening test of films. The hardeners were prepared by condensation of equimolar amounts of trichlorotriazine with benzene- or naphthalene-based amino or oxy acids at 0 to 5℃ and at pH 7, and used as hardening agents for gelatin. The hardening test of neutral emulsion layers was studied at pH 7.0. For example I(R=ONa) had strong hardening properties, I substituted with an aminobenzosulfonate moiety (R=NHC6H4-p-SO3Me where Me = K, Na) was a much weaker gelatin hardener, and when substituted with amino- or oxynaphthalene derivative (II, III) did not harden gelatin at all. Compound with 2 dichlorotriazine groups as IV exhibited hardening properties. The hardener can be used in neutral emulsion layer of film and showed good hardening effect.
4,000원
