The effects of La addition to Ni/CeO2 methane partial oxidation catalysts were investigated. Catalysts were prepared by the impregnation and urea methods. In the preparation of catalysts, La content was changed from 1 wt% to 3wt%. Catalysts that contain 2wt% La showed the highest methane conversion of about 80% and CO selectivity of 84% and H2 selectivity of 70%. This result may be stemmed from that, when La content is 2wt%, a fluorite oxide-type structure is well formed and carbon deposition is also decreased. Among the catalysts, 2.5wt% Ni/Ce(La)Ox showed the highest catalytic activity. From the experiment of changing reaction temperature with 2.5wt% Ni/Ce(La)Ox catalyst, it was found that the optimum reaction temperature is 750℃ and at this temperature methane conversion was about 90%, CO and H2 selectivities were 94 and 80%, respectively.

The objection of this research is to conform of practicable possibility and recycling of producing junk after citrus fruits is processed. In the middle of practicable possibility, with verification of antibiosis that tactiling sensibility in a microorganism. With extracting d-limonene oil that have 70~90% a component of oil out of junk citrus peel, making certain the about 12000ppm(1.2%) concentration of it. By means of antibiosis property over the a pathogenic bacterium as well as a residence bacterium, considerating the limit of application against daily living supplies needs to antibiosis. Antibiosis effect of a stationing bacterium in the body permanently and by means of antibiosis verification of special bacteria Propionibacterium Acnes that causative skin trouble is selected, in based the antibiotic sencitivity test check up result of minimal inhibitory concentration(MIC).

Today, wastes of much quantity by fast industrialization and increase in population, population concentration etc. of modem society are increasing. Much oyster shell is breeding by character and conduct of oyster-industry for a long time among them. Oyster shell which breed by-product in oyster cultivating industry that specific gravity of domestic seashore cultivating industry is high is causing environmental problem by problem and so on hindrance, nature spectacle's waste and health hygiene on administration if it is pollution of district along the coast fishing ground, number of public ownership being stored in open area in seashore. About new material just-in-time through recycling and he of oyster shell by these problem wide that study. Go forward more and investigate special quality that is oyster shell's physical chemistry red in this research and oyster shell oyster shell which cause several environmental problems developing ability agricultural chemicals that use this encapsulating micro by ability carrier that is environmentally application possibility examine wish to.

Water quality has been deteriorated by the increasing amount of industrial waste water that is due to the better standard of living. In order to lessen the polluted water and substantially reutilize it at factories, a new method is needed. The plasma generator, which uses discharge current below 1,500 voltage and processes at extremely low temperature, has more strong oxidization than current method and an advantage of miniaturizing the apparatus in dealing with waster water by producing carrier gas at room temperature. This study were measured on the 3 kinds of waster water to the plasma generator for 120 minutes. As results, COD was almost decreased and removed in 15 minutes. The results suggest that the plasma generator can be used reduce COD and removal of color for various waster water, which can be reutilized as industrial water, It would be of benefit to the country like Korea in which qualified water is deficient.

In order to improve resistant properties of water-borne acrylic pressure sensitive adhesives(PSAs) for automobiles, this study was carried out. Removable PSAs for automobiles were synthesized by emulsion polymerization of monomers, n-butyl acrylate(BA), n-butyl methacrylate(BMA), acrylonitrile(AN), acrylic acid(AA) and 2-hydroxyethyl methacrylate(2-HEMA), and AA and 2-HEMA could act as functional monomers for crosslink. Emulsion polymerization was carried out in a semi-batch type reactor. Water resistance, heat resistance, acid resistance, alkali resistance and smoke resistance were examined. As a result, water resistance increased with the amount of BMA, however, the effect of BMA content on the water resistance was insignificant at a range of over 14 wt%. The water resistance also increased with the amount of functional monomers, AA and 2-HEMA. The prepared PSAs satisfied all the standard for automobiles except heat resistance. However, the heat resistance comes nearly up to the standard. Also, acid resistance, alkali resistance and smoke resistance of the prepared PSAs satisfied with the standard.

This study was focused on the maximization of flame-retardancy of polyesters by a synergism of simultaneously introduced chlorine and phosphorus into polymer chains of modified polyesters. To prepare modified polyesters, reaction intermediates, TD-adduct (prepared from trimethylolpropane /2,4-dichlorobenzoic acid (2,4-DCBA)) and TMBO (prepared from tetramethlene bis (orthophosphate)), were prepared first, then condensation polymerization of the prepared intermediates, adipic acid, and 1,4-butanediol were carried out. In the condensation polymerization, the content of phosphorus was fixed to be 2wt%, and the content of 2,4-DCBA that provides chlorine component was varied to be 10, 20, and 30wt%, and we designated the prepared modified polyesters containing chlorine and phosphorus as ABTTs. The prepared intermediates and modified polyesters were characterized with FT-IR, NMR, GPC, and TGA analysis. Average molecular weight and polydipersity index of the preparation of ABTTs were decreased with increasing 2,4-DCBA content because of the incease in hydroxyl group that retards reaction. We found that the thermal stability of the prepared ABTTs increased with chlorine content at high temperatures.

The firing reaction and calcination characteristics of the waste shellfish were examined for the future use as absorbent. The weight variation was measured according to thermal-decomposition using TGA and observed variation of the phase. The qualitative and quantitative analysis of the sample were performed using XRD and the structural analysis, SEM. The results of TGA and XRD experiments showed that the almost all of the raw Corbicula Japonica and Ostrea virginjca were changed from calcite to lime by firing and calcination reaction. The result of SEM experiment showed that the plate type of the raw sample was changed to circle type, so the surface area ratio was increased. Above results suggested that waste shellfish were usable as absorbent in the viewpoint of the reuse of resource and the decrease of environmental pollution.

It is a great role that the character of man or woman could be distinguished by hair on the aspect of ornament. Hair will be support of beautifulness of human being in various permanent wave by many kinds of its drugs. Hair is based upon the skin which enroll the body of high living animals and have multiple membrane structure. This study used rat and the effects of commercial permanent wave products to skin which are composed with thioglycolic acid and bases. Results are as follows. Permanent wave penetrated to 4 hours later with steady state in skins and was not significant changeable after 20hr later. In case of neutralizer with thioglycolic acid lag time and permeability coefficient in healthy skin is 3.38hr and 0.094μg/cm2 · hr, it old skin is 3.48hr and 0.129μg/cm2 · hr, and it wounded skin is 4.72hr and 0.158μg/cm2 · hr. In conclusion, lag time and permeability coefficient in old skin and wounded skin are faster than healthy skin. In vivo which was studied by general time and method of permanent wave. We notified that fine rinkle and rash of skin were changeable in the case of treating with permanent wave drugs than normal skin. We can see even rash and eruption by the naked eye.

Antibiotics polymer prepared by chemical bonding and simple blending of antibacterial into polymers have attracted much interest because of their long-lasting and antibacterial activity. Antibiotics polymer can significantly reduce losses associated with dissolution, photolytic decomposition and volatillization. Further more, increased efficiency safety and selectivity are additional benefits which may be realized. In this study, Antibiotics polymer was synthesized by chemical reaction of polyacrylic acid with sulfamethazine by N,N'-dicyclohexylcarbodiimide(DCC) method. Antibacterial susceptibility was determined against Streptococcus pyrogenes[gram(+)] and Esherichia coli.[gram(-)] using a standardized disc test. As a result, the synthetic antibiotics polymer exhibited the broad susceptibilty against Streptococcus pyrogenes and Esherichia coli. Especially, the antibiotic effect of antibacterial polymer against Gram negative(Esherichia coli) was much stronger than that against Gram positive(Streptococcus pyrogenes).

Resource recovery and recycling of materials and products, including polyurethanes is viewed as a necessity in today's society. Most urethane polymers are made from a polyol and a diisocyanate. these and be chemicals such as water, diamines or diols that react with isocyanate groups and add to the polymer backbone. The problems of recycling polyurethane wastes has major technological, economic and ecological significance because polyurethane itself is relatively expensive and its disposal whether by burning is also costly. In general, the recycling methods for polyurethane could be classified as mechanical, chemical and feedstock. In the chemical recycling method, there are hydrolysis, glycolysis, pyrolysis and aminolysis. This study, the work was carried out glycolysis using sonication ant catalyzed reaction. Different kinds of recycled polyols were produced by current method(glycolysis), catalyzed reaction and sonication as decomposers and the chemical properties were analyzed. The reaction results in the formation of polyester urethane diols, the OH value which is determined by the quantity of diol used for the glycolysis conditions. The glycolysis rates by sonication for the various glycols, increased as fallows: PPG <PEG < DEG < EG. The recycled polyol of sonication reaction had much higher OH value, much lower decomposition temperature and time than the recycled polyol of current method in which same glycols and catalyst were used.

Dual-actions are the most recently used delivery system in drug study. Dual-action agents are unique chemical entities comprised of two different type of antibacterial compounds covalently linked together in a single molecule in such a way that both components are able to exert their bactericidal properties. Crosslinked sulfadiazine-sulfanilamide such as antibiotics is synthesized by synthetic handle with glutaraldehyde. As a result, New synthetic antibacterial agent exhibited the broad antibacterial activities against gram(+) and gram(-) of 4 strains and a long durability supposing that the stomach and blood.

PVA blend films were prepared by solution blending method for the purpose of useful antibiotic polymers. Characteristics properties of blending films such as elongation and tensile strength were determined. Tensile strength and elongation were rapidly reduced as increasing the blending ratio of natural polymer. Blend films were found that phase separation was occured as more than 25wt% increasing the blend ratio of chitosan. Also, The antibiotics of blend films were examined against gram(+) and gram(-) by disk susceptibility test. As a result, kind of blending films to show the highest antibiotics was chitosan 20wt% and the selectivity of mold strain was observed.

Drug delivery system(DDS) have been actively studied for the past twenty years. Dual action agents are unique chemical entities comprised of two different types of antibacterial compounds covalently linked together in a single molecule in such a way that both components are able to exert their bactericidal properties. In spite of the advent of the antibacterial agent the sulfa agents are the most widely used antibacterial agent today. In this study, new antibacterials derivative was synthesized using glutaraldehyde such as crosslinking agent for the purpose of dual-action as DDS study. Antibacterial activity of these new synthetic derivative between their structures and activities were examined by disc diffusion method. As a result, new synthetic derivative exhibited the broad antibacterial activities against Gram(+) and Gram(-) bacilli. Especially, the antibacterial effect of new synthetic derivative against Gram negative(Esherichia. coli) was much stronger than that against Gram positive.

Chitosan and Algin are known as a natural polymers. Biodegradable films were prepared by solution blend method in the weight ratio of natural polymer(low, medium, high-Chitosan, Algin) for the purpose of useful bioimplants. The possibility of bioimplants, which were prepared from natural polymers as a skin substitute and food wrapping materials were evaluated by measuring biodegradability. This biodegradable films were inserted in the back of rats and their biodegradability was investigated by hematological change evaluation as a function of time to biotransformation. It was found that these values of biodegradable films give some good results with short period test.

This study was carried out to investigate characteristics and Pb(II) removal effect of natural Muan, Seosan, Kangjin clays in the batch mode test to develope the low-priced treatment agent of wastewater which contain heavy metals in order structural, optical properties and chemical compositions of natural clays from domestic have been investigated to have high specific surface area and have minerals such as SiO2 and Al2O3. As a result, removal effects of Pb(II) ions on clays were reached at equilibrium in aqueous solutions by stirring about 20minutes. The removal effect of Pb(II) ions was best for Seosan clay than Muan or Kangjin clays in terms of fixed time. The results show the possibility of continuous treatment system of wastewater which contain heavy metals by using natural clays from domestic.

This study is to develop a new synthetic method for the nitroarenes via non-electrophilic substitution. Direct nitration at the C-1 position of isoquinoline has never been reported and substitution in isoquinoline under the normal nitration condition occurs at C-5 and C-8. We have demonstrated a facile one-step sythetic method for the nitration of isoquinolines at the C-1 position, which involves the electrophilic attack of a DMSO-Ac2O complex, followed by nucleophilic addition of nitrate ion to this intermediate. Since the reaction is simple and mild, this method has preparative merit since 1-nitroisoquinolines are not readily accessible by other methods. Application to the synthesis of poly nitroarenes from the corresponding anilines was also described.

Photoresist is defined as substance that makes chemical changes in its solubility, colouring and hardening by light energy. In this study, photosensitive photoresists of the positive type for a printing plate were studied. PF, o-, m-, p-CF resins as a matrix resin were synthesized at an identical condition. Photoresists were prepared by mixing NDS derivatives with a matrix resin at various mixing ratios. Characteristics of photoresists were studied by yield method of residual using solubility and Optical microscope was also analyzed. Prepared photoresist using NDS derivatives shows excellent photosensitivity and solubility compared with commercial product. The mixing ratio of 1:4(by mass) of NDS derivative[III] and m-CF resin shows the highest dissoultion rate among others. In addition, photoresist was obtained at this condition resulted in the superior sensitivity and contrast.

The field of printing use to pressurization ink using screen gassamer that is called screen printing. Existing cleaning solvent using screen printing are the organic solvents including aromatic compounds carried with poisonous and stench. Besides, cleaning method of current screen printing are for the most part mixed cleaning method of dipping and polish. Using 1,1,1-TCE, CFC-113 alternative system cleaning solvent be substituted for existing cleaning solvent against screen printing ink measured the cleaning efficiency according to gravimetric analysis method and property change of gassamer according to Image Analyzer. Also, Cleaning process system carry with excellent cleaning efficiency studied which was proposed new cleaning process including ultrasonic and vibration cleaning process be substituted for existing mixed cleaning method of dipping and polish.

Naphthoquinone-1,2-diazide-5-sulfonyl[NDAS] derivatives members of quinone diazide compound that are utilizable as photosensitive polymer material were synthesized, and photoresist were prepared by mixing these derivatives with m-cresol novolak(a matrix resin) at various weight ratios. Photosensitive characteristics of photoresist were studied by examining UV and IR, relative sensitivity using a Gray scale method, and SEM to analyze if they can be used as photosensitive material in printing process. Experimental results showed that, by UV, NDAS derivatives were photoconverted and developer-soluble photoresist were produced. The mixing ratio of 1:4(by mass) of NDAS+p-ydroxybenzophenone+sensitizer and m-cresol novolak gave rise to the highest dissolution rate. In addition, photoresist obtained at this condition resulted in the most superior sensitivity and contrast.

Fluorenylidene chalcone derivatives were synthesized by condensation. The structure of these compounds were ascertained by means of UV, melting point, IR and 1H-NMR spectra. The nucleophilic addition reaction kinetics of Thioglycolic acid to fluorenylidene chalcone was investigate by UV in 20% dioxane-H2O at 25℃. The rate equation which were applied over a wide pH1.0~13.0 range. On the basis of general base catalysis and confirmation of addition reaction product, the nucleophilic addtion reaction kinetics of thioglycolic acid to fluorenylidene chalcone were measured by the pH change. From the result of the above caption, a plausible nucleophilic addition reaction mechanism of thioglycolic acid to fluorenylidene chalcone was proposed. These compounds may be used as the starting materials for the preparation of the engineering plastics or the germicide.