Radioactive waste repositories require long-term durability of concrete in contact with ground water. However, contact of the ground water leads to Ca2+ leaching process between pore water and pure water. Therefore, this study is aimed at investigating the effect of the leaching process of concrete based on their physical properties and durabilities. According to results, as the leaching period became longer, the pore volume is greatly increased and the chloride diffusion coefficient of the degraded concrete increased with leaching process.