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열유도상분리공정과 비용매유도상분리공정의 중공사막 제조에서 내부 응고액이 중공사막의 구조에 미치는 영향

Effect of internal coagulant on structure and performance of PVDF hollow fiber membrane in Polymer/Diluent/Solvent System

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  • URLhttps://db.koreascholar.com/Article/Detail/344815
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한국막학회 (The Membrane Society Of Korea)
초록

The hollow fiber membranes were prepared via hybrid process of the thermally induced phase separation(TIPS) and the non-solvent induced phase separation(NIPS). The spinning dope solution consisted of poly(vinylidene fluoride) (PVDF) / dibutyl phthalate (DBP) / 1-methyl-2-pyrrolidone (NMP), where DBP was used as a diluent and NMP as a solvent for PVDF. Bore fluids were tested different ratio solvent/ethanol and diluent/ethanol mixture. The membrane structure was analyzed by SEM and FT-IR to confirm phase separation mechanisms. Various structures were obtained due to the different phase separation mechanism. Membrane characterizations were performed such as water flux, pore size, rejection efficiencies and mechanical strength.

저자
  • 윤은정(경희대학교, Kyung Hee University) | Eun Jeong Youn
  • 이소영(경희대학교, Kyung Hee University) | So Young Lee
  • 김성수(경희대학교, Kyung Hee University) | Sung Soo Kim