A colorimetric chemosensors Sn2+ have been designed and synthesized by three steps. The spirolactam ring-opening process of rhodamine B is one of the most useful mechanisms for controlling fluorescence properties. Herein, new fluorescent chemosensors 1 and 2 based on rhodamine B containing phenothiazine derivertive were synthesized. They exhibit selective fluorescence enhancement behaviour in the presence of Sn2+ ion. Complexation between these compounds and the metal cations were confirmed through continuous variation method. It is observed that compounds 1, 2, and Sn2+ ion are complexed by 1:1 formation. Especially the proposed compounds 1 and 2 exhibit quick, simple and facile synthetic route.