The solid phase extractant SAN-D2EHPA/TBP containing two extractants of Di-(2-ethylhexyl)phosphoric acid (D2EHPA) and Tri-butyl-phosphate (TBP) was prepared by immobilizing two exractants D2EHPA and TBP in styrene acrylonitrile copolymer (SAN). The prepared SAN-D2EHPA/TBP was characterized by using fourier transform infrared spectrometer (FTIR) and scanning electron microscopy (SEM). The solid phase extractant SAN-D2EHPA/TBP was tested for the removal of Cu(II) from aqueous solution. Experiments were carried out as a function of the pH and Cu(II) concentration in the aqueous phase. The equilibrium time was 180 min and equilibrium experiment data obeyed the pseudo-second-order kinetic model. The Langmuir isotherm model represented the experiment data as well. The maximum removal capacity of Cu(II) calculated from Langmuir isotherm model was 3.1 mg/g.
This study analyzed the climate regime shift using statistical change-point analysis on the time-series tropical cyclone (TC) frequency that affected Japan in July to September. The result showed that there was a significant change in 1995 and since then, it showed a trend of rapidly decreasing frequency. To determine the reason for this, differences between 1995 to 2012 (9512) period and 1978 to 1994 (7894) period were analayzed.
First, regarding TC genesis, TCs during the 9512 period showed a characteristic of genesis from the southeast quadrant of the tropical and subtropical western North Pacific and TCs during the 7894 period showed their genesis from the northwest quadrant. Regarding a TC track, TCs in the 7894 period had a strong trend of moving from the far east sea of the Philippines via the East China Sea to the mid-latitude region in East Asia while TCs in the 9512 period showed a trend of moving from the Philippines toward the southern part of China westward. Thus, TC intensity in the 7894 period, which can absorb sufficient energy from the sea as they moved a long distance over the sea, was stronger than that of 9512.
Large-scale environments were analyzed to determine the cause of such difference in TC activity occurred between two periods. During the 9512 period, anomalous cold and dry anticyclones were developed strongly in the East Asia continent. As a result, Korea and Japan were affected by the anomalous northerlies thereby preventing TCs in this period from moving toward the mid-latitude region in East Asia. Instead, anomalous easterlies (anomalous trade wind) were developed in the tropical western Pacific so that a high passage frequency from the Philippine to the south China region along the anomalous steering flows was revealed. The characteristics of the anomalous cold and dry anticyclone developed in the East Asia continent were also confirmed by the analysis of air temperature, relative humidity and sensible heat net flux showing that most regions in East Asia had negative values.
This study was conducted to investigate the correlation between the distribution chart and input data of the predicted 3-second gust and damage cost, by using the forecast field and analysis field of Regional Data Assimilation Prediction System (RDAPS) as initial input data of Korea risk assessment model (RAM) developed in the preceding study. In this study the cases of typhoon Rusa which caused occurred great damage to the Korean peninsula was analyzed to assess the suitability of initial input data. As a result, this study has found out that the distribution chart from the forecast field and analysis field predicted from the point where the effect due to the typhoon began had similarity in both 3-second gust and damage cost with the course of time. As a result of examining the correlation, the 3-second gust had over 0.8, and it means that the forecast field and analysis field show similar results. This study has shown that utilizing the forecast field as initial input data of Korea RAM could suit the purpose of pre-disaster prevention.
In 2013, International Agency for Research on Cancer (IARC) concluded that outdoor air pollution is carcinogenic to humans, with the particulate matter component of air pollution most closely associated with sufficient evidence of increased cancer incidence by exposure to particulate matter component of air pollution. Motor vehicles are one of a major emission sources of fine particle (PM2.5) in urban areas. A large number of epidemiological studies have reported a positive association of morbidity or mortality with distance from the roadside. We conducted this study to assess the association of PM2.5 concentrations measured at roadside hotspots with those at adjacent residential sites using real-time PM2.5 monitors. We conducted real-time PM2.5 measurements for rush hour periods (08:00∼10:00 and 18:00∼20:00) at 9 roadside air monitoring Hotspot sites in metropolitan Seoul over 3 weeks from October 1 to 21, 2013. Simultaneous measurements were conducted in residential sites within a 100 m radius from each roadside air monitoring site. A SidePak AM510 was used for the real-time PM2.5 measurements. Medians of roadside PM2.5 concentrations ranged from 9.8 μg/m3 to 38.3 μg/m3, while corresponding median values at adjacent residential sites ranged from 4.4 μg/m3 to 37.3 μg/m3. PM2.5 concentrations of residential sites were 0.97 times of hotspot roadside sites. Distributions of PM2.5 concentrations in roadside and residential areas were also very similar. Real-time PM2.5 concentrations at residential sites, (100 m adjacent), showed similar levels to those at roadside sites. Increasing the distance between roadside and residential sites, if needed, should be considered to protect urban resident populations from PM2.5 emitted by traffic related sources.
The study investigates the characteristics of PM10 concentration in Guducsan air quality observatory and in particular, analyzes the relationship between sudden increase of PM10 concentration in the morning of spring 2014 and meteorological parameters. PM10 concentration in April was 46.9 ㎍/㎥, the highest, followed by 45.5 ㎍/㎥ and 44.6 ㎍/㎥ in March and May, and 21.9 ㎍/㎥ in August. The low concentration in the early morning appeared on 0800 LST in spring, summer, and fall, whereas it emerged on 0900 LST in winter. High concentration in daytime lasted from 1200 LST to 1500 LST in spring and fall, whereas it continued from 1300 LST to 1600 LST in winter. The findings of PM10 concentration and change of meteorological parameters in Guducsan from April 20th to 27th in 2014 are as follows. The low concentration at dawn and in the morning decreased due to strong land breeze. Also, the sudden increase of PM10 concentration in the morning was attributable to low wind speed. Lastly, the sudden decrease of PM10 concentration in the afternoon was attributed to diffusion by strong sea breeze.
This study analyzes the correlation between Western Pacific (WP) teleconnection pattern index (WPI) in April during 1954-2008 and rainfall amounts in the same month. Based on the results, it is identified that there have been strong positive correlations between central China, Korea and the southwestern part of Japan in the East Asian region.
Through differences between 10 positive WP years and 10 negative WP years selected from the April WPI excluding ENSO years, it is found that rainfall amounts increase in April of positive WP years due to the following characteristics. Increases in rainfall amounts are evident in the East Asian middle latitudinal region where the positive correlation between the two variables is the highest and this is because anomalous southwesterlies are strengthened in the East Asian middle latitudinal region due to the spatial pattern of a south-low-north-high anomalous pressure system centered on this region that is made by anomalous anticyclones centered on the southeastern side of the region and other anomalous anticyclones centered on the northeastern side of the region. In addition, anomalous westerlies (jet) are strengthen in the upper troposphere of the East Asian middle latitudinal region and as a result, anomalous upward flows are strengthened in this region and thus anomalous warm air temperatures are formed in the entire level of the troposphere in the region. In addition to atmospheric environments, anomalous warm sea surface temperatures are formed in the seas in the East Asian middle latitudinal region to help the rainfall amount increases in the East Asian middle latitudinal region.
The tap water is generally known to be corrosive in the pH range at 6.5 ~ 7.5. And the degree of corrosion varies depending on the types of raw water such as river surface water or lake water of the dam. Although several corrosion index represents the corrosivity of tap water, the typical corrosion indexes such as Langelier saturation index (LI) and calcium carbonate precipitation potential (CCPP) were calculated to monitoring the corrosive water quality about raw and tap water in water distribution system. To control the corrosive water quality, the correlation between corrosion index and water quality factors were examined. In this study, corrosion index (LI, CCPP) and the pH was found to be most highly correlated.
Styela clava tunic is generated in large amounts as a waste from S. clava processing plants and leads to environmental problems. It destroys the beach scenery and causes a bad smell and pollution by trashing on the seashore. Therefore, purpose of this study was to investigate antioxidant and antihypertensive activities of different solvent extracts from S. clava tunic for recycling of fishery waste. Antioxidant and antihypertensive activities of all extracts were concentration-dependent. Of extracts, hot water extract showed the highest DPPH radical scavenging activity with the lowest effective concentration (EC50) value (0.733 mg/ml). Chloroform extract exhibited the highest metal chelation activity with the lowest EC50 value (2.696 mg/ml). Autoclaved water extract showed the highest NO radical scavenging activity with the lowest EC50 value (0.491 mg/ml) and n-hexane extract showed the highest reducing power (A700=1.897 at 100 mg/ml). And n-butanol extract showed the highest SOD-like activity with the lowest EC50 value (19.116 mg/ml) and ACE inhibition activity with the lowest inhibitory concentration(IC50) value (0.149 mg/ml). These results indicate that extracts obtained from S. clava tunic may potential candidate to reduce diseases caused by various oxidative stresses and hypertension.
This study was performed to identify and quantify the asbestos fibers released from two types of asbestos-cement slate roofs. One is a plant roof installed in 1987 which contained 15% chrysotile, and the other is a residential roof installed before 1983 which contained 12% chrysotile. The concentrations of asbestos fibers in air surrounding asbestos-cement slate roofs and in the falling water harvested from the same roofs on rainy days ranged from 0.0012 to 0.0018 f/mL and from 1,764 f/L to 10,584 f/L, respectively. The concentration of inorganic fibers in the soil around asbestos-cement slate roofs was from 217 to 348 f/g. With the above results, the excess lifetime cancer risk (ELCR) for the risk assessment of the asbestos fibers released from asbestos-cement slate based on US EPA IRIS (Integrated risk information system) model is within 5.5E-06 ~ 6.5E-06 levels which indicates that the levels do not exceed “the acceptable risk(1.0E-05)” recommended by WHO. The asbestos concentration in air, drained rainfall and soil around the plant slate roof was higher than that around residential slate roof, but the excess lifetime cancer risk (ELCR) from residential slate was higher than that from plant slate. This s
Hydraulic conductivity is an important parameter in the analytical model of groundwater. This study analyzed the groundwater movement characteristics by estimating optimal parameters according to hydraulic conductivity input methods with the MODFLOW model which is widely used. It first estimated the optimal parameters by dividing hydraulic conductivity zones by attitude. Next, it estimated optimal parameters by geological characteristic. It analyzed the groundwater movement characteristics by applying the recharge quantity and amount of evapotranspiration of drought periods and flood years with the estimated parameters.
As the result was analyzed that there are differences of observation water level values according to hydraulic conductivity input methods but there is no big differences of overall groundwater movement characteristics by hydraulic conductivity input method, the two methods have found to be applicability in analyses of groundwater. So, it is judged that studies on more exact application of hydraulic conductivity and the application methods are needed.
Dielectric barrier discharge plasma is a new technique in water pollutant degradation, which that is characterized by the production of chemically active species such as hydroxyl radicals, ozone, hydrogen peroxide, etc. If dissolving of plasma gas generated in the plasma reaction has increased, it is possible to increase the contaminant removal capacity. In this study, the improvement on the dissolving performance of plasma gas was evaluated by the indirect method measuring the overall oxygen transfer coefficient. Experiments were conducted to examine the effects of nozzle type, distance from water surface, air supply rate and liquid circulation rate. The experimental results showed that the KLa value of the 3-prong nozzle is 2.67 times higher than the diffuser. The order of KLa value with nozzle type ranked in the following order: 3-prong nozzle (inner diameter, less 1 mm) > circular nozzle (inner diameter, 1.5 mm) > ellipse nozzle (short diameter 1 mm, long diameter 2.5 mm) > circular nozzle (inner diameter, 3 mm). Optimal liquid circulation rate was appeared to be 1.7 L/min, the value of KLa was 0.510 1/min. The value of KLa with increasing air supply rate was revealed in the form of an exponential such as KLa=0.3581e0.2919*air flow rate
A colorimetric chemosensors Sn2+ have been designed and synthesized by three steps. The spirolactam ring-opening process of rhodamine B is one of the most useful mechanisms for controlling fluorescence properties. Herein, new fluorescent chemosensors 1 and 2 based on rhodamine B containing phenothiazine derivertive were synthesized. They exhibit selective fluorescence enhancement behaviour in the presence of Sn2+ ion. Complexation between these compounds and the metal cations were confirmed through continuous variation method. It is observed that compounds 1, 2, and Sn2+ ion are complexed by 1:1 formation. Especially the proposed compounds 1 and 2 exhibit quick, simple and facile synthetic route.
The production of highly concentrated PM10 is in the spotlight as a social issue, and it increases the attack rate of Asthma. This study aimed to analyze the characteristics of concentration and distribution for PM10 from 2000 to 2011, and investigate its correlation with the death from Asthma. Furthermore, this study was designed to analyze it by dividing into two cases like including Asian dust and excluding Asian dust because it presented the high concentration when Asian dust was occurred in the spring. This study has found that the annual average concentration distribution of PM10 in Seoul was higher in the central area than the peripheral area. The annual average concentration of PM10 and death from asthma displayed the tendency to gradually decrease. The correlation coefficient for all period was 0.92(p=0.000), and the correlation was 0.84(p=0.001) in case of remove Asian dust. The monthly average concentration of PM10 has increased in the winter and decreased in the summer. The death from Asthma and correlation coefficient for all period was 0.588(p=0.044) and 0.640(p=0.025) in case of removing Asian dust. Although the causes of Asthma had a great diversity, the similar tendency by a factor of PM10 meant that the correlation was high.