In recent years, environmental pollution by pharmaceuticals and personal care products (PPCPs) in the aquatic environment is of great concern worldwide. Recent studies have been reported to occur in a variety of environmental organisms such as surface, drinking and ground water, soils, sediments and hospitals. The purpose of this study was to evaluate the occurrence and environmental behavior of fourteen human PPCPs in surface waters of Mankyung River in South Korea. We were conducted to field survey for water quality and PPCPs analysis at November, 2006. PPCPs were analyzed by liquid chromatograph coupled with a tandem mass spectrometer (HPLC-MS/MS). The concentration of COD was measured to be 2.37~19.71 mg/L, which was belong to 4~5 grade in water quality criteria of lake. Station 2 that there is no pollution in upper stream, was appeared to lower concentration. The concentration of TN and TP, that is cause matter of eutrophication, were found to be 7.78~35.42 mg/L and 0.08~0.95 mg/L, respectively, which were exceeding 5 grade in Lake water quality criteria. The 11 kind of PPCPs compounds except levofloxacin and triclosan were detected to Mankyung river. PPCPs concentrations of STP(Sewer Treatment Plant) effluents and aquatic environment in Mankyung river have been detected in the range from dozens of ng/L to hundreds of μg/L that by order of atenolol, carbamazepine, propranolol, Ibuprofen, erythromycin, ifenprodil, clarithromycin, mefenamic acid, fluconazole, indomethacin, disopyramide. PPCPs concentration of Station 1 and 5, which was influenced by Jeonju STP and Wanju STP, was detected high values. Station 2 that there is no pollution, showed lower values. Station 3 which joined Gosan stream and Jeonju stream and station 4 which influenced by stock wastewater was detected to low values.
We need water equivalent unit data of snowfall for the purpose of forecast and hydrology related research area. This study developed new method of automatic recording snowfall as weight unit. The instrument designed for measuring weight of snowfall by stain-gauge loadcell. Field test of instrument carried out at Daegwallyeong Obs. Station from 22 Jan. to 22 Feb. 2007. During observation period there is 15.3 cm snow depth and 16.0 mm of accumulated water equivalent depth at Daegwallyeong Obs. Station on 13 to 14 Feb. 2007. But the instrument of this study recorded 22.1 mm of water equivalent depth. It is not easy to explain difference between Daegwallyeong and this study. Because this study is only one case of comparison of snow measurement and there is very little amount of snow observation research. The density of snowfall calculated from 0.09 to 0.15 g/cm3 from the observation data of 13 to 14 Feb. 2007. There is high relation between radar echo and snowfall amount measured by weight unit. It can supports forecast of snowfall and development of numerical model for forecast.
The purpose of this study is to propose an appropriate criterium for proper sound insulation service preventing school classrooms from aircraft noise. The guideline of noise level for school facility by Korean school health law is less than Leq 55 which is less stringent than that of other countries. It has been reported that many students are annoyed and disturbed for their works when they are exposed to the noise level over Leq 55. It is desirable to modify this guideline of indoor noise level for school classroom. The noise level of classroom of which windows are opened was measured relatively high in case the school is located at the outside of the official area damaged by aircraft noise. In order to minimize the influence of aircraft noise on the school classrooms in the vicinity of domestic airport, it is necessary to improve the present criteria of WECPNL 75 for the establishment of the area damaged by aircraft noise from WECPNL 70.
In order to reduce the uncertainties and improve the air flow field, objective analysis using observational data is chosen as a method that enhances the reality of meteorology. To improve the meteorological components, the radius influence and nudging coefficient of the objective analysis should perform a adequate value on complex area for the objective analysis technique which related to data reliability and error suppression. Several numerical experiments have been undertaken in order to clarify the impacts of the radius influence and nudging coefficient of the objective analysis on meteorological environments. By analyzing practical urban ground conditions, we revealed that there were large differences in the meteorological differences in each case. In order to understand the quantitative impact of each run, the Statistical analysis by estimated by MM5 revealed the differences by the synoptic conditions. The strengthening of the synoptic wind condition tends to be well estimated when using quite a wide radius influence and a small nudging coefficient. On the other hand, the weakening of the synoptic wind is opposite.
This is a study on the volatile organic compounds(VOCs) concentrator with zeolite adsorptive honey rotor and catalytic combustion system for abating VOCs emitted from printing industry. VOCs emitted from the printing industry is mainly caused by organic solvent of printing ink. The content of organic solvents in printing ink varies from 40% to 75% and its content in the gravure ink is higher than that in any other ink. The average concentrations of each VOCs are 139 ppm for toluene, 152.1 ppm for MEK, 256.9 ppm for methanol and 42.9 ppm for isopropyl alcohol. We used zeolite honeycomb for absorbent of VOCs concentrator and palladium for catalyst combustion system. This system abated over 96% of emitted total VOCs, 98% of toluene, 100% of MEK, 92% of methanol and 100% of isopropyl alcohol. It is concluded that the low-leveled high-volume VOCs emitted from printing process were removed almost by concentrator with zeolite adsorptive honey rotor and catalytic combustion system.
The blue-green algae which caused odor problem in the tap water are difficult to precipitate in sedimentation basin and clogged the filter void rapidly. The studies of this paper were not only oxidation, coagulation and sedimentation processes for effectively removing blue-green algae but yellow clay and polyamine for verification as coagulants aids. The results of this research are summarized as follows: Higher ozone dose(C) and longer contact time(T) were needed for a high degree of removing blue-green algae efficiency. the removal rate of blue-green algae was proportional to the C×T value. The removal percent of chlorophyll-a by sedimentation and filter without pre-ozonation was about 75% but 1 mg/L pre-ozonation could increase the removal percent of chlorophyll-a to 99% and more pre-ozonation could remove completely. Though the removal efficiency of turbidity could increased by high dose of chlorination, the dissolved organic carbon was increased. More chlorine dose from 4 to 10 mg/L dissolved organic carbon was decreased. Using yellow clay as coagulant aids increased density of floc so the settling velocity of floc become rising but polyamine could not increase settling velocity of floc though it could formated large floc.
We manufactured PVA-derived hydrogels using a foam generation technique that has been widely used to prepare colloidal gas aphrons(CGA). These gels were differentiated to the conventional gels such as for medical or pharmaceutical applications, which have tiny pores and some crystalline structure. Rather these should be used in de-pollution devices or adhesion of cells or biomolecules. The crosslinkers used in this work were amino acid, organic acid, sugars and lipids(vitamins). The structures of the gels were observed in a scanned electron microscope. Amino acids gels showed remarkably higher swelling ratios probably because their typical functional groups help constructing a highly crosslinked network along with hydrogen bonds. Boric acid and starch would catalyze dehydration while structuring to result in much lower water content and accordingly high gel content, leading to less elastic, hard gels. Bulky materials such as ascorbic acid or starch produced, in general, large pores in the matrices and also nicotinamide, having large hydrophobic patches was likely to enlarge pore size of its gels as well since the hydrophobicity would expel water molecules, thus leading to reduced swelling. Hydrophilicity(or hydrophobicity), functional groups which are involved in the reaction or physical linkage, and bulkiness of crosslinkers were found to be more critical to gel's crosslinking structure and its density than molecular weights that seemed to be closely related to pore sizes. Microscopic observation revealed that pores were more or less homogeneous and their average sizes were 20 μm for methionine, 10-15 μm for citric acid, 50-70 μm for L-ascorbic acid, 30-40 μm for nicotinamide, and 70-80 μm for starch. Also a sensory test showed that amino acid and glucose gels were more elastic meanwhile acid and nicotinamide gels turned out to be brittle or non-elastic at their high concentrations. The elasticity of a gel was reasonably correlated with its water content or swelling ratio. In addition, the PVA gel including 20% ascorbic acid showed fair ability of cell adherence as 0.257mg/g-hydrogel and completely degraded phenanthrene(10 mM) in 240 h.
A accurate reservoir inflow is very important as providing information for decision making about the water balance and the flood control, as well as for dam safety. The methods to calculate the inflow were divided by the directed method to measure streamflow from upstream reservoirs and the indirected method to estimate using the correlation of reservoir water level and release. Currently, the inflow of multi-purpose dam is being calculated by the indirect method and the reservoir water level to calculate the storage capacity is being used by centimeters(cm) units. Corresponding to the storage volume of 1cm according to scale and water level of multi-purpose dam comes up to from several 10 thousand tons to several million tons. If it converts to inflow during 1 hour, and it comes to several hundred ㎥/sec(CMS). Therefore, the inflow calculated on the hourly is largely deviated along the water level changes and is occurred minus value as the case. In this research, the water level gage has been developed so that it can measure a accurate water level for the improvement for the error and derivation of inflow, even though there might be various hydrology and meteorologic considerations to analyse the water balance of reservoir. Also, it is confirmed that the error and the standard derivation of data observed by the new gage is decreased by 89,6% and 1/3 & 87% and 2/3 compared to that observed by the existing gage of Daecheong and Juam multi-purpose dam.
Hydraulic gradient of the landfill soils is estimated by Devlin (2003) method, and its variation characteristics from rainfall and permeability of the aquifer material are analyzed. The study site of 18 m × 12 m is located in front of the Environment Research Center at the Pukyong National University, and core logging, slug/bail test and groundwater monitoring was performed. The slug/bail tests were performed in 9 wells (except BH9 well), and drawdown data with elapsed time for bail tests were analyzed using Bouwer-Rice and Hvorslev methods. The average hydraulic conductivity estimated in each of the test wells was ranged 1.991 ×10-7~4.714×10-6 m/sec, and the average hydraulic conductivity in the study site was estimated 2.376×10-6 m/sec for arithmetic average, 1.655×10-6 m/sec for geometric average and 9.366×10-7 m/sec for harmonic average. The permeability of landfill soils was higher at the east side of the study site than at the west side. Groundwater level in 10 wells was monitored 44 times from October 2 to November 7, 2007. The groundwater level was ranged 1.187~1.610 m, and the average groundwater level range in each of the well showed 1.256~1.407 m. The groundwater level was higher at the east side than at the west side of the study site, and this distribution is identify to it of hydraulic conductivity. The hydraulic gradient and the major flow direction for 10 wells were estimated 0.0072~0.0093 and 81.7618~88.0836°, respectively. Also, the hydraulic gradient and the major flow direction for 9 wells were estimated 0.0102~0.0124 and 84.6822~89.1174°, respectively. The hydraulic gradient of the study site increased from rainfall (83.5 mm) on October 7, causing by that the groundwater level of the site with high permeability was higher. The hydraulic gradient estimated on and after October 16 was stable, due to almost no rainfall. Thus, it was confirmed that the variation of the hydraulic gradient in the landfill soils was controlled by the rainfall.
This study was aimed to behaviour of organics and nitrogen on the upflow anaerobic reactor when a acid fermenter is added. Upflow anaerobic reactor (UAR) reaction will result which operates, COD removal efficiencies of reactor with nitrate loading rate 0.11, 0.66g/L/d were over 77%, but one with 1.0g/L/d was 73.5%. Especially, on NLR 0.11g/L/d, COD removal was 77% and nitrate removal efficiency was 93% simultaneously. The other side upflow anaerobic reactor and acid fermenter (UAR+AF) reaction will result witch operates, COD removal efficiencies of reactor with nitrate loading rate 0.11, 0.66g/L/d were over 85%, but one with 1.0g/L/d was 80%. Especially, on NLR 0.11g/L/d, COD removal was 85% and nitrate removal efficiency was 98% simultaneously. Also, without in reaction condition increase of influent nitrate concentration resulted in the linear decrease of nitrate removal efficiency and nitrate removal efficiency at influent nitrate-nitrogen 800mg/L was 50%. Alkalinity was increased theoretically by denitrification at low nitrate-N concentration, however, it was not increased theoretically at high nitrate-N. 40% nitrate-N of UAR was denitrified until 70% height of reactor and 90% nitrate-N of UAR+AF was denitrified until 30% height of reactor Upflow anaerobic reactor was to occur accumulate acid, which TVA/Alkalinity is 0.3~0.47. Increase of NLR resulted increase of effluent alkalinity and TVA production
This study presents the analysis of an atmospheric flow around a single-doppler radar located in a pseudo-site. The use of a doppler radar in meteorological field of wind engineering has become widespread over the last several decades, but it has generally been recognized that the single-Doppler radar yields only one single velocity component - the radial velocity(Vr) so that some additional hypotheses or simplifications must be necessary to get proper wind forecast. Therefore, in order to get an accurate radial velocity(Vr) in this study, the existing methods such as VAD(Velocity Azimuth Display) and VARD(Velocity Area Display) are reformulated and applied to match the previous study(Waldteufel and Corbin1)), which have been an important indicator for retrieving a radar velocity. The results presented in this study include the results from different assessment methods in a peudo-site of different wind fields. Unless the existing method can consider the proper decomposition of radial velocity in the real site, then authors suggest an appropriate curve-fitting to decrease the uncertainty errors by changing a grid adaptation rate or applying a weighting function with respect to the wind angle. It is concluded that provided properly formulated fitting function are used, the wind retrieval from the Doppler radar using VAD and VARD methods can be a viable tool for use in wind engineering problems searching for the wind resources.
The purpose of this study is to examine the health of beauty salon workers through the utilization of questionnaires concerning the extent of exposure to organic solvents found in the air of some beauty salons and any resultant symptoms in employees. The subjects were 36 employees from 10 beauty salons who agreed to participate in this study. The degree of exposure to organic solvents in the air of beauty salons was measured from September 1, 2008 to September 30, 2008. A survey of symptoms that occurred due to exposure to these solvents was also performed. The results were as follows: questionnaires were collected and analyzed from a total of 36 subjects. Of these, 28(77.8%) were female and 8(22.2%) were male. The mean age was 29.08. The mean working period was 7.13 years. Sixteen subjects attended programs at universities while 11 went to beauty schools for vocational education. When testing the concentration of organic solvents in the air of beauty salons, the highest value found was Isopropyl alcohol 511.85 ppb followed by butyl acetate, toluene, acetone, xylene, ethyl benzene, styrene, and chlorobenzene. A logistic regression analysis was performed as follows: the point of each factor was the dependent variable while sex, age, drinking, smoking, educational level, work experience, hairdresser’s license, and organic solvents were the independent variables. Statistically significant difference (p<0.05) was shown in the hairdresser’s license among Factor 1 and in Xylene among Factor 2; however, difference was not shown in the other variables.