간행물

한국환경과학회지 KCI 등재 Journal of Environmental Science International

권호리스트/논문검색
이 간행물 논문 검색

권호

제29권 제1호 (2020년 1월) 11

ORIGINAL ARTICLE

1.
2020.01 서비스 종료(열람 제한)
Recently, a heavy rainfall with high spatial variation occurred frequently in the Korean Peninsula. The meteorological event that occurred in Busan on 3 May 2016 is characterized by heavy rain in a limited area. In order to clarify the reason of large spatial variation associated with mountain height and location of low level jet, several numerical experiments were carried out using the dynamic meteorological Weather Research and Forecasting (WRF) model. In this case study, the raised topography of Mount Geumjeong increased a barrier effect and air uplifting due to topographic forcing on the windward side. As a result, wind speed reduced and precipitation increased. In contrast, on the downwind side, the wind speed was slightly faster and since the total amount of water vapor is limited, the precipitation on the downwind side reduced. Numerical experiments on shifting the location of the lower jet demonstrated that if the lower jet is close to the mountain, its core becomes higher due to the effect of friction. Additionally, the water vapor convergence around the mountain increased and eventually the precipitation also increased in the area near the mountain. Hence, the location information of the lower jet is an important factor for accurately predicting precipitation.
2.
2020.01 서비스 종료(열람 제한)
The determination of soil characteristics is important in the simulation of rainfall runoff using a distributed FLO-2D model in catchment analysis. Digital maps acquired using remote sensing techniques have been widely used in modern hydrology. However, the determination of a representative parameter with spatial scaling mismatch is difficult. In this investigation, the FLO-2D rainfall-runoff model is utilized in the Yongdam catchment to test sensitivity based on three different methods (mosaic, arithmetic, and predominant) that describe soil surface characteristics in real systems. The results show that the mosaic method is costly, but provides a reasonably realistic description and exhibits superior performance compared to other methods in terms of both the amount and time to peak flow.
3.
2020.01 서비스 종료(열람 제한)
The determination of soil parameters is important in predicting the simulated surface runoff using either a distributed or a lumped rainfall-runoff model. Soil characteristics can be collected using remote sensing techniques and represented as a digital map. There is no universal agreement with respect to the determination of a representative parameter from a gridded digital map. Two representative methods, i.e., arithmetic and predominant, are introduced and applied to both FLO-2D and HEC-HMS to improve the model’s accuracy. Both methods are implemented in the Yongdam catchment, and the results show that the former seems to be more accurate than the latter in the test site. This is attributed to the high conductivity of the dominant soil class, which is A type.
4.
2020.01 서비스 종료(열람 제한)
Recently, a variety of modeling studies have been conducted to examine the air quality over South Korea during the Korea United States Air Quality (KORUS-AQ) campaign period (May 1 to June 10, 2016). This study investigates the impact of different meteorological initializations on atmospheric modeling results. We conduct several simulations during the KORUS-AQ period using the Weather Research and Forecasting (WRF) model with two different initial datasets, which is FNL of NCEP and ERA5 of ECMWF. Comparing the raw initial data, ERA5 showed better accuracy in the temperature, wind speed, and mixing ratio fields than those of NCEP-FNL. On the other hand, the results of WRF simulations with ERA5 showed better accuracy in the simulated temperature and mixing ratio than those with FNL, except for wind speed. Comparing the nudging efficiency of temperature and wind speed fields, the grid nudging effect on the FNL simulation was larger than that on the ERA5 simulation, but the results of mixing ratio field was the opposite. Overall, WRF simulation with ERA5 data showed a better performance for temperature and mixing ratio simulations than that with FNL data. For wind speed simulation, however, WRF simulation with FNL data indicated more accurate results compared to that with ERA5 data.
5.
2020.01 서비스 종료(열람 제한)
High-resolution meteorological simulations were conducted using a Weather Research and Forecasting (WRF) model with an Urban Canopy Model (UCM) in the Ulsan Metropolitan Region (UMR) where large-scale industrial facilities are located on the coast. We improved the land cover input data for the WRF-UCM by reclassifying the default urban category into four detailed areas (low and high-density residential areas, commercial areas, and industrial areas) using subdivided data (class 3) of the Environmental and Geographical Information System (EGIS). The urban area accounted for about 12% of the total UMR and the largest proportion (47.4%) was in the industrial area. Results from the WRF-UCM simulation in a summer episode with high temperatures showed that the modeled temperatures agreed greatly with the observations. Comparison with a standard WRF simulation (WRF-BASE) indicated that the temporal and spatial variations in surface air temperature in the UMR were properly captured. Specifically, the WRF-UCM reproduced daily maximum and nighttime variations in air temperature very well, indicating that our model can improve the accuracy of temperature simulation for a summer heatwave. However, the WRF-UCM somewhat overestimated wind speed in the UMR largely due to an increased air temperature gradient between land and sea.
6.
2020.01 서비스 종료(열람 제한)
The purpose of this study is to investigate the relationship of fine dust PM10 and heavy metals in PM10 in Asian dust flowing into Gwangju from 2013 to 2018. The migration pathways of Asian dust was analyzed by backward trajectory analysis using HYSPLIT (Hybrid Single Particle Lagrangian Integrated Trajectory) model, and the change of heavy metal concentration and heavy metal content per 1 μg/m3 of fine dust PM10 in Gwangju area were analyzed. Also, the characteristics of the heavy metals were analyzed using the correlation between the heavy metals in PM10. As a result of analyzing Asian dust entering the Gwangju region for 6 years, the average concentration of PM10 measured in Asian dust was 148 μg/m3, which was about 4.5 times higher than in non-Asian dust, 33 μg/m3. A total of 13 Asian dust flowed into the Gwangju during 6 years, and high concentration of PM10 and heavy metals in that were analyzed in the C path flowing through the Gobi/Loess Plateau-Korean Peninsula. As a result of the correlation analysis, in case of Asian dust, there was a high correlation between soil components in heavy metals, so Asian dust seems to have a large external inflow. On the other hand, in case of non-Asian dust, the correlation between find dust PM10 and artificial heavy metal components was high, indicating that the influence of industrial activities in Gwangju area was high.
7.
2020.01 서비스 종료(열람 제한)
Oxidative degradation of phenol, three monochlorophenols (2-chlorophenol, 2-CP; 3-chlorophenol, 3-CP; 4-chlorophenol, 4-CP), four dichlorophenols (2,3-dichlorophenol, 2,3-DCP; 2,4-dichlorophenol, 2,4-DCP; 2,5-dichlorophenol, 2,5-DCP; 2,6-dichlorophenol, 2,6-DCP), and two trichlorophenols (2,4,5-trichlorophenol, 2,4,5-TCP; 2,4,6-trichlorophenol, 2,4,6-TCP) was conducted with heat activated persulfate. As the number of chlorinations increased, the reaction rate also increased. The reaction rate was relatively well fitted to the zero-order kinetic model, rather than the pseudo-first order kinetic model for the reactions at 60℃, which can be explained by insufficient activation of the persulfate at 60℃, and the oxidation reaction of 2,4,6-TCP at 70℃ was relatively well fitted to the pseudo-first order kinetic model. The oxidation reaction rate generally increased with increase of persulfate concentration in the solution. 2,6-dichloro-2,5-cyclohexadiene-1,4-dione was found as a degradation product in a GC/MS analysis. This compound is a non-aromatic compound, and one chlorine was removed. This result is similar to the result of previous studies. The current study proved that heat activated persulfate activation could be an alternative remediation technology for phenol and chlorophenols in soil and groundwater.
8.
2020.01 서비스 종료(열람 제한)
To determine the size distributions of water-soluble inorganic ionic species (WSIS) in roadside aerosols, sampling experiments were carried out in the urban roadside area of Jeju City on August 2018 and January 2019 by using the eight-stage cascade impactor sampler. The mass of roadside aerosols were partitioned at 57% in fine fraction, 36-37% in coarse fraction, and 6-7% in giant fraction, regardless of summer and winter. The mass concentrations of WSIS except for Na+ and SO42- in roadside aerosols were higher in winter than in summer. The size distributions of Na+, Mg2+, Ca2+ and Cl- were characterized by bimodal types with coarse particle mode peaking around 3.3-4.7㎛ and 5.8-9.0㎛ . The size distributions of NO3 - and K+ shifted from a single fine mode peaking around 0.7-1.1㎛ in winter to bimodal and/or trimodal types with peaks around coarse mode in summer. SO4 2- and NH4 + showed a single fine mode peaking around 0.7-1.1㎛ . The MMAD of roadside aerosols was lower than that of Na+, Mg2+, Ca2+ and Cl-. Based on the marine enrichment factors and the ratio values of WSIS and the corresponding value for sea water, the composition of roadside aerosols in Jeju City may be practically affected by terrestrial sources rather than marine source.
9.
2020.01 서비스 종료(열람 제한)
Silver nanoparticles were loaded onto g-C3N4 (CN) with a nanoroll-type morphology (Ag/CN) synthesized using a co-polymerization method for highly selective conversion of toxic nitrobenzene to industrially-valuable aminobenzene. Scanning electron microscopy and high-resolution transmission electron microscopy (HRTEM) images of Ag/CN revealed the generation of the nanoroll-type morphology of CN. Additionally, HRTEM analysis provided direct evidence of the generation of a Schottky barrier between Ag and CN in the Ag/CN nanohybrid. Photoluminescence analysis and photocurrent measurements suggested that the introduction of Ag into CN could minimize charge recombination rates, enhancing the mobility of electrons and holes to the surface of the photocatalyst. Compared to pristine CN, Ag/CN displayed much higher ability in the photocatalytic reduction of nitrobenzene to aminobenzene, underscoring the importance of Ag deposition on CN. The enhanced photocatalytic performance and photocurrent generation were primarily ascribed to the Schottky junction formed at the Ag/CN interface, greater visible-light absorption efficiency, and improved charge separation associated with the nanoroll morphology of CN. Ag would act as an electron sink/trapping center, enhancing the charge separation, and also serve as a good co-catalyst. Overall, the synergistic effects of these features of Ag/CN improved the photocatalytic conversion of nitrobenzene to aminobenzene.

TECHNICAL NOTE

10.
2020.01 서비스 종료(열람 제한)
Asthmatics are more susceptible to fine particulate matters (PM2.5), compared to the general population. It has been reported that indoor PM2.5 is mainly generated by combustion of fossil fuels, meat or fish In particular, asthmatics are known to be more susceptible to indoor PM2.5 because 65 ∼ 95% of child or adult asthmatics stay inside the house. Thus, understanding the association between indoor activity patterns and variations in indoor PM2.5 levels is important. The purpose of this study is to determine the distribution of hourly indoor PM2.5 concentrations in asthmatics’ homes, and to evaluate its association with pan-frying cooking activity patterns, the most common PM2.5 emission related activity. From November 2017 to February 2018, real-time PM2.5 concentrations were measured in the living room of each asthmatic’s house (n = 35) for three weeks at 1 minute intervals. At the same time, self-reported daily activity patterns, hourly proportion (%) of cooking activities, were also recorded every hour over three weeks for each patient. In this study, we provided quantitative evidence that the distribution patterns of indoor hourly PM2.5 concentrations were associated with indoor cooking activities, especially in the homes of adult asthmatics. In addition, we observed that PM2.5 emitted by pan-frying could maintain even over up to 2 hour lagtime.

SHORT COMMUNICATION

11.
2020.01 서비스 종료(열람 제한)
The effects of liquid potassium permanganate (KMnO4) on the litter quality of poultry were investigated. Two-hundred -forty 0-day-old broiler chickens (Arbor Acres) were randomly assigned to two treatments with four replicated pens of 30 chickens each. Treatment liquid KMnO4 at a rate of 50 g of liquid KMnO4/kg of poultry litter was sprayed onto the litter surface using a small hand pump; others served as a control that was applied without liquid KMnO4 additions. Compared with controls, the treatment liquid KMnO4 showed no differences in pH, total nitrogen and ammonia concentration. It was concluded that liquid KMnO4 did not significantly increase poultry litter quality. Mechanisms relating to increasing litter pH and ammonia using liquid KMnO4 are an oxidant agent (not acid-foaming agents).