Since prolonged exposure to elevated ozone (O3) concentrations is known to be harmful to human health, appropriate control strategies for ozone are needed for the non-attainment area such as Seoul, Korea. The goal of this research is to assess factors linked with the 1-hour ozone exceedance through a decision tree model. Since ozone is a secondary pollutant, lag times between ozone and explanatory variables for ozone formation are taken into account in the model to improve the accuracy of the simulation. Results show that while ozone concentrations of the previous day and NO2 concentrations in the morning are major drivers for ozone exceedances in the early afternoon, meteorology plays more important role for ozone exceedances in the late afternoon. Results also show that a selection of lag times between ozone and explanatory variables affect the accuracy of predicting 1-hour ozone exceedances. The result analyzed in this study can be used for developing control strategies of ozone in Seoul, Korea.
The government has conducted a plan of total maximum daily loads(TMDL), which divides with unit watershed, for management of stable water quality target by setting the permitted total amount of the pollutant. In this study, BOD concentration trends over the last 10 years from 2005 to 2014 were analyzed in the Geumho river. Improvement effect of water quality throughout the implementation period of TMDL was evaluated using the seasonal Mann-Kendall test and a LOWESS(locally weighted scatter plot smoother) smooth. As a study result of the seasonal Mann-Kendall test and the LOWESS smooth, BOD concentration in the Geumho river appeared to have been reduced or held at a constant. As a result of quantitatively analysis for BOD concentration with exploratory data analysis(EDA), the mean and the median of BOD concentration appeared in the order of GH8 〉GH7 〉GH6 〉GH5 〉GH4 〉GH3 〉GH2 〉GH1. The monthly average concentration of BOD appeared in the order of Apr 〉Mar 〉Feb 〉May 〉Jun 〉Jul 〉Jan 〉Aug 〉Sep 〉Dec 〉Nov 〉Oct. As a result of the outlier, its value was the most frequent in February, which is estimated 1.5 times more than July, and was smallest frequent in July. The outlier in terms of water quality management is necessary in order to establish a management plan for the contaminants in watershed.
In this study, we have investigated to find optimal pre-treatment flocculation condition by analyzing the floc growth rate with mixing conditions and the membrane permeation flux for pre-treatment step of the membrane process. The higher mixing intensity showed a constant floc size index (FSI) values, and lower mixing intensity increased the degree of dispersion of the FSI values. Results of comparing the distribution characteristics of the FSI value and the permeation flux were more effective in increasing flux when the FSI values were 0.2 or higher. The degree of dispersion of FSI was relatively large in 40 rpm mixing condition compared to 120 rpm. In 40 rpm mixing condition, it decreased the permeation flux compared to 120 rpm because various sizes of flocs were distributed. Coagulation-UF membrane process enhanced 30%∼40% of the flux rate compare to UF alone process, and the coagulation-MF process increased up to 5% of the flux rate compare to MF alone process. Pre-treatment, that is, coagulation process, has been found to be less effects on relatively larger pore size for MF membrane. For UF membrane, the flux was a little bit same when applying only the rapid mixing process or rapid mixing with slow mixing processes together. In case of MF membrane, the flux was improved when rapid mixing process applied with slow mixing process together.
This study aims to analyze region-specific trends in changing greenhouse gas emissions in incineration plants of local government where waste heat generated during incineration are reused for the recent five years (2009 to 2013). The greenhouse gas generated from the incineration plants is largely CO2 with a small amount of CH4 and N2O. Most of the incineration plants operated by local government produce steam with waste heat generated from incineration to produce electricity or reuse it for hot water/heating and resident convenience. And steam in some industrial complexes is supplied to companies who require it for obtaining resources for local government or incineration plants. All incineration plants, research targets of this study, are using LNG or diesel fuel as auxiliary fuel for incinerating wastes and some of the facilities are using LFG(Landfill Gas). The calculation of greenhouse gas generated during waste incineration was according to the Local Government's Greenhouse Emissions Calculation Guideline. As a result of calculation, the total amount of greenhouse gas released from all incineration plants for five years was about 3,174,000 tCO2eq. To look at it by year, the biggest amount was about 877,000 tCO2eq in 2013. To look at it by region, Gyeonggido showed the biggest amount (about 163,000 tCO2eq annually) and the greenhouse gas emissions per capita was the highest in Ulsan Metropolitan City(about 154 kCO2eq annually). As a result of greenhouse gas emissions calculation, some incineration plants showed more emissions by heat recovery than by incineration, which rather reduced the total amount of greenhouse gas emissions. For more accurate calculation of greenhouse gas emissions in the future, input data management system needs to be improved.
To predict annual energy production (AEP) accurately in the wind farm where located in Seongsan, Jeju Island, Equivalent wind speed (EQ) which can consider vertical wind shear well than Hub height wind speed (HB) is calculated. AEP is produced by CFD model WindSim from National wind resource map. EQ shows a tendency to be underestimated about 2.7% (0.21 m/s) than HB. The difference becomes to be large at nighttime when wind shear is large. EQ can be also affected by atmospheric stability so that is classified by wind shear exponent (). AEP is increased by 11% when atmosphere becomes to be stabilized ( > 0.2) than it is convective ( < 0.1). However, it is found that extreme wind shear ( > 0.3) is hazardous for power generation. This results represent that AEP calculated by EQ can provide improved accuracy to short-term wind power forecast and wind resource assessment.
We analyzed diurnal variations in the surface air temperature using the high density urban climate observation network of Daegu in summer, 2013. We compared the time elements, which are characterized by the diurnal variation of surface air temperature. The warming and cooling rates in rural areas are faster than in urban areas. It is mainly due to the difference of surface heat capacity. In addition, local wind circulation also affects the discrepancy of thermal spatiotemporal distribution in Daegu. Namely, the valley and mountain breezes affect diurnal variation of horizontal distribution of air temperature. During daytimes, the air(valley breeze) flows up from urban located at lowlands to higher altitudes of rural areas. The temperature of valley breeze rises gradually as it flows from lowland to upland. Hence the difference of air temperature decreases between urban and rural areas. At nighttime, the mountains cool more rapidly than do low-lying areas, so the air(mountain breeze) becomes denser and sinks toward the valleys(lowlands). As the result, the air temperature becomes lower in rural areas than in urban areas.
Ground echo is radar return from stationary targets such as buildings and trees. Wind vectors from the wind profile radar in Gangneung are affected by ground echoes due to the complex mountainous terrain located to the west and the south. These ground echoes make a spurious peak close to the direct current (DC) line signal in Doppler spectra. Wind vectors polluted by ground clutters were determined from spectra of oblique beams. After eliminated the terrain echoes, the accuracy of wind vector compared with radiosonde was improved about 68.4% and its relative coefficient was increased from 0.58 to 0.97.
After analyzing of heating value of four kinds of RDF, the RDF-D has the highest heating value, was chosen to be mixed with carbonized sludge by different ratio. The 85%:15% ratio, which has the highest efficiency, was analyzed with thermogravimetric and pyrolysis kinetics. Applying of Kissinger method, activation energy was obtained from slope which is calculated from relation of ln(β/T2 m) and 1/Tm. The kinetic parameters obtained from Kissinger method were 46.06 kJ/mol of RDF, 55.99 kJ/mol of carbonized sludge and 40.68 kJ/mol of mixture of RDF and carbonized sludge. The mixture of RDF and carbonized sludge has the lowest activation energy and frequency factor, during thermal decomposition reaction it has the slowest reaction rate and needs the lowest energy. Although activation energy with pyrolysis of RDF was irregularly scattered, it showed that activation energy was stabilized by co-pyrolysis of RDF and additives(Carbonized Sludge).
In this study, we examined the impact of transplant timing of mother plants for seedling strawberry on growth and development of daughter plants and field stage. The leaf growth of treated mother plants and crown thickness were low when transplant was performed on April 10th. Based on the results collected until July 13th, the numbers of daughter plants with more than two leaves were 20.6 and 19.5 for March 10th and March 25th, and these values decreased by April 10th and April 25th showing values of 15.1 and 11.8, respectively. After seedling growth was complete, leaf area and fresh weight of the saplings were remarkably low beginning from the transplant on April 10th. Crown thickness of saplings was generally lower when transplant timing was late. After 45 days of transplant leaf length and width were noticeably lower than the transplant on April 10th and 25th. First cluster was 100% for both the March 10th and 25th transplant, followed April 10th and 25th with values of 66% and 43%. The results revealed that transplant on March 10th and 25th had a greater positive impact on the growth and development of the strawberry cultivar ‘Seolhyang’. A supplementary study will have to be conducted to determine the relationship between the harvest period of the first cluster and the yield of marketable strawberries depending on the transplanting time of mother plants.
In this study, changes in daily temperature range were investigated using daily maximum and minimum temperatures of Busan and Daegu for last 81 years (1934-2014), and also characteristics of daily temperature range and seasonal fluctuations by urbanization were examined. First, elapsing changes showed a lower decreasing trend in Busan (0.32℃) than Daegu (1.2 8℃) for last 81 years. Daily temperature range showed the highest rise in winter in both Busan and Daegu. Second, daily temperature range due to urbanization showed that Busan had a pronounced decreasing trend before urbanization meanwhile Daegu showed the same trend after urbanization. On seasonal changes, the results of Busan showed a decreasing trend in summer before urbanization, and in autumn after urbanization. For Daegu, the results showed a decreasing trend in spring before urbanization, and in winter after urbanization. Seasonal fluctuations of Busan showed little difference in the pre and post-urbanization, except in winter and summer. There was large difference in daily temperature range in winter after urbanization, and in summer before the urbanization. The results in Daegu showed that there was decreasing trend of daily temperature range in all seasons after urbanization.
This study reduced and built Street Canyons created by skyscrapers in order to verify effect of Street Canyons by green wall within the city centre and analysed influence factors on temperature reduction according to applicative types of green wall in the lab. Applicative types were divided into three types such as non- greening type(Case A), one-side greening type(Case B), both side greening type(Case C). The result of analysis of each types showed that average temperature of Case B and Case C is respectively 1.0℃ and 1.7℃ lower than Case A. The result of analysis of WBGT was that the highest temperature was given by Case A(40.2℃) and second one was from Case B(39.8℃) and third one was from (39.1℃) and in UTCI Case A records the highest temperature of 34.7℃ and Case B provided the second highest temperature of 33.9℃ and Case B gave the lowest temperature of 32.7℃. In PMV the highest temperature of 2.65 was from Case B and second one of 2.61 was from Case A and third one of 2.54 was from Case C. Duncan analysis of each types based on solar radiation and thermal comfort generated that there was analytical significance between Case A and Case B and Case B in terms of each types of average temperature reduction. The significance of thermal comfort in WBGT, MRT, PMV showed non-significance but, In UTCI it was analysed that there was significance between Case C and Case A.
In this study, the applicability of MBR process was evaluated to improve processing of personal sewage treatment facilities of 50 m3/day or less. As result of the research, stable discharge water quality could be secured as result of the MBR effector operation according to rate of inflow and inflow load and treatment efficiency of 98% or higher was shown by the membrane filtering method operation for SS, BOD5. it was found that high treatment efficiency of 99% or higher. It is judged that detention time can be designed until 6.9 hr when applying MBR process on personal sewage treatment facilities with high pollution load and that cutback of pollution load can be possible through this study. It was shown that MBR process application reduces an annual cost of 4,829,600 won based on the basic unit calculation results and solves burden of amount of borne by causers according to excess of discharge water quality standards.
In this study the optimum conditions for recovery of valuable metal in Electric Arc Furnace Dusts were investigated. 2M of H2SO4, 1~5 of solid/liquid ratio, 0~180 min of leaching time has been established for leaching condition, and for electrowinning, each of Pt, C, Zn, Pb anode and Zn, Cu cathode was compared respectively at pH 2, 4 and 6. The result of elemental analysis of Zn crystal, a lagre quantity of Fe and H has been observed with Zn and other heavy metal, therefore, impurities removing process would be requir for enhancing purity of Zn. As the result, about 60% of Zn has been recovered under condition of 2 M of H2SO4, 1:2 of S/L ratio at 120 min, and Pt or Pb for anode, Zn for cathode has been shown the highest efficiency of electrowinning at pH 6.