After analyzing the correlation between air pollution and visibility, TSP and NO2 is responsible for poor visibility in Pusan. After analyzing the correlation between meteorological factors and visibility, general pattern of humidity has clear negative correlation. The variation of wind speed has a positive correlation.
In order to investigate the cause of poor visibility in Pusan area, the Andersen sampler and PM-2.5 are used to collect and analyze aerosol. This study was carried out to monitor the visibility using Forward scattering meter and to find out the characteristics and the cause of good visibility case and poor visibility case by measuring and analyzing a variety of parameters, such as particle size distributions, chemical compositions, and meteorological conditions in Pusan. According to the analysis of intensive sampling, NO3-, NH4+ ion concentration increased together with the mass concentration around 0.5∼2.5㎛ approximately during the case of poor visibility. NH4NO3, NH4Cl, and NaCl were thought to be the major components of fine particles.
In order to simulate and investigate the major characteristics of El Nino/Southern Oscillation(ENSO) and Madden Jullian Oscillation(MJO), an intermediate type atmosphere-ocean coupled model is developed and their results are examined. The atmosphere model is a time-dependent non-linear perturbation moist model which can determine the internal heating for itself. The counterpart of the atmosphere model is GCM-type tropical ocean model which has fine horizontal and vertical grid resolutions.
In the coupled experiment, warm SST anomaly and increased precipitation and eastward wind and current anomalies associated with ENSO and MJO are properly simulated in Pacific and Indian Oceans. In spite of some discrepancies in simulation MJO, the observed atmospheric and oceanic low-frequency characteristics in the tropics are successfully identified. Among them, positive SST anomalies centered at the 100m-depth of tropical eastern-central Pacific due to the eastward advection of warm water and reduced equatorial upwelling, and negative anomalies in the Indian and western Pacific seem to be the fundamental features of tropical low-frequency oscillations.
The flow of non-rotation atmosphere with uniform stratification and wind past an isolated three dimensional topography obstacle is investigated with three-dimensional hydrostatic and non- hydrostatic numerical model. The characteristic of turbulence created the back of topography obstacle is usually defined by Froude number which is the function of upstream wind speed, the height of topography obstacle, and atmospheric stability.
Turbulence tends to be formed more easily at the non-hydrostatic model than hydrostatic model. Especially, the difference between flow patterns of two models generated by isolated obstacle is more clear under low Froude number. The difference of flow patterns can be only seen at relatively low altitude, but at high altitude the patterns of two models are almost same.
In this research, wind velocity in the parameters related with Froude number have great sensitivity at responsibility of numerical models. and slop of obstacle is also important factor at the flow pattern regardless of the species of numerical model
Estimating dimensions of attractors are the most basic tools to analyze properties of chaotical dynamic systems. In this paper, we estimate correlation dimensions of meteorological variables, such as wind speed (v) and temperature (T) observed in Kimhae International Airport when the land-sea breeze circulation is appeared and find low non-integer values that reflect the deterministic chaos characterizing the dynamics. We compare the results with the correlation dimensions of 2-dimensional model that is calculated by finite element method.
Though the correlation dimensions of the calculated wind speed (v) are less than those of the observed wind speed (v), we can suggest that the land-sea breeze circulation has not a unique mechanism. The land-sea breeze phenomenon is a complicated dynamics, which is constructed with various scale motions of atmosphere. In further research, we hope to find more accurate dynamics of land-sea breeze through wide observations and using of more sophisticated prediction models.
The effects of wounding and jasmonic acid(JA) on polyphenol oxidase(PPO) in tomato(Lycopersicon esculentum Mill.) seedlings were investigated. PPO was strongly induced by wounding or JA, and the response was also shown to be systemically induced by wounding. Mechanical wounding in cotyledon or leaf produced a signal that caused the concentration of PPO to increase in the unwounded cotyledon, in the first leaves but not in the second leaves. Severity of wounding and light intensity also affected wound induced change in PPO activity, JA showed a stimulatory effect on the loss of chlorophyll and the rapid increase in PPO activity. The PPO was clearly more active in the wounded leaves than in controls. The potency and specificity of the JA indicate a close relationship between JA and wound-induced changes in PPO in tomato species. JA and abscisic acid(ABA) acted similarly on both unwounded and wounded leaves, but the amount of PPO in the wounded leaves was always more than the respective controls. The highest increase in PPO activity occurred in woundand JA-induced leaves of seedlings kept under bright lighting. Benzyladenine(BA) completely abolished JA- and ABA-induced PPO activity. The results suggest that JA-induced PPO activity is due to de novo PPO synthesis. Histochemical tests for PPO in stems of wound- and JA-treated tomato plants indicate that PPO was localized primarily in the outer cortex and xylem parenchyma. It is concluded that exogenously applied JA acts as stress agents and PPO may be a component of the inducible anti-hervivore defense response.
To investigate size distribution and metallic elements of surface sediments in Hampyong Bay, the southwestern coast of Korea, sedimentological and geochemical studies on surface sediments are carried out. The surface sediments of Hampyong Bay are classified into gravel, muddy sandy gravel, gravelly muddy sand, gravelly sandy mud, mud facies in accordance with areal characteristics. The coarse sediments are distributed on the subtidal zone along the main tidal channel and southeast intertidal flat of Hampyong Bay. On the other hand, the fine sediments are dominated in northeast and west intertidal flat of Hampyong Bay. Most metallic elements except for Ba in the sediments are closely interrelated with fine sediments and mutually with each element. Ba is maybe related with sandy sediments and inversely related with carbonate contents. Normalized by Al content, the sediment do not show any remarkable metal enrichments influenced by resonable artificial or environmental factors.
The pollution characteristics of groundwaters in Taegu City and correlation coefficients(r) between water pollution indicators were investigated for two years from January 1996 to December 1997.
Volatile organic compounds such as TCE(tri-chloroethylene), PCE(tetrachloroethylene), 1,1,1-trichloroethane, THM(trihalo-methane), dichloromethane, pesticides such as diazinon, parathion, malathion, and toxic inoganic matters such as As, Hg, Se, Pb, Cd, Cr6+ , CN were not detected in the groundwaters.
Mean values of groundwater pollution indicators were below drinking-water standards, but hardness, KMnO4-C(potassium permanganate consumption), evaporate residues, SO4-2, Fe, NO3- -N, color and turbidity exceeded a little in some samples. As groundwater became deeper, hardness and evaporate residues remarkably increased, but KMnO4-C, NO3- -N, Cl-, color, turbity and bacteria decreased. KMnO4-C, evaporate residues, Cl- and SO4-2 were very high at industrial and commercial areas, and NO3- -N and NH4+-N were very high at agricultural and forest areas.
It showed high positive significances in the relationships between hardness and each of evaporate residues, SO4-2, Zn and Mn, KMnO4-C and each of color, turbidity and Zn, color and each of turbidity, Cu, Zn and Mn, turbidity and each of Fe, Cu, Zn and Mn, and evaporate residues and each of Cl-, SO4-2 and Zn.
The work on the eutropication of Youngsan river was conducted from Jul. 1997 to Jun. 1998. The value of water temperature in the study area varied from 4℃ to 32℃ with an annual mean of 17.5℃. DO varied from 4.0㎎/ℓ to 13.5㎎/ℓ with an annual mean 10.2 ㎎/ℓ. BOD varied from 0.8㎎/ℓ to 6.4㎎/ℓ with an annual mean 3.1㎎/ℓ. COD varied from 4.6㎎/ℓ to 9.0㎎/ℓ with an annual mean 6.38㎎/ℓ. Nitrate varied from 1.58㎎/ℓ to 6.77㎎/ℓ with an annual mean of 3.475㎎/ℓ. Total-nitrogen varied from 2.14㎎/ℓ to 8.38㎎/ℓ with an annual mean of 5.083㎎/ℓ. Total-phosphate varied from 0.035㎎/ℓ to 0.588㎎/ℓ with an annual mean of 0.128㎎/ℓ. Chl.a varied from 1.8㎍/ℓ to 75.0㎍/ℓ with an annual mean of 19.55㎍/ℓ. The euthrophic state index of Carlson^16) were showed 61.8(TP) and 71(SD) value
The Photodegradation efficient of total organic compounds in the drinking water has been studied using the methods of photocatalytic reaction and laser beam irradation.
The results are summarized as follows;
1. The photodegradation efficiency of total organic compounds shows as 50% to 80% as within one hour and after this the efficiency is decreased slowly.
2. The photodegradation efficiency of total organic compounds shows as 65 to 90% within 3.3min. when Nd : YAG beam is irradiated to the water layer.
3. An excellent observation of the organic compound removal efficiency gives revealed in that case of the longest wavelength of 532nm is irradiated among the three kinds of laser beam sources of 532nm, 355nm and 266nm.
4. The organic compound removal efficiency shows high in the case of UV beam irradiation in the thin layer of water. However the efficiency is not depended on the thickness of water layer severely.
5. The removal efficiency of the organic compounds in the direct irradiation shows higher than the indirect irradiation in the case of UV beam, but the efficiency is not depended on the direction of irradiation in the case of Nd : YAG beam irradiation.
The fundamental experiments on the phosphorus removal from water were carried out by the batch and continuous reactors which used aluminium and copper plate. In this systems, the phosphorus was removed by aluminium ion generated with the electrochemical interaction (pitting corrosion) of aluminium and copper. In the batch experiments, the efficiencies of phosphorus removal increased when the surfaces of aluminium and copper plate were brushed. The phosphorus removal by aluminium ion was affected the copper plate and NaCl in this system. The optimal pH values were 5 and 6 for the phosphorus removal. The efficiency of phosphorus removal increased with increasing NaCl concentration, surface area of aluminium and copper plate. The CuSO4·5H2O instead of copper plate could be used as Cu source. The effluent PO4-P concentration as low as 2㎎/ℓ could have been obtained during the continuous experiment at HRT of 48 hrs.
This research explored the feasibility of preparing and utilizing a preformed polymeric solution of Al(Ⅲ) for coagulation in water treatment. Slow base(NaOH) injection into supersaturated aluminum chloride and aluminum sulfate solutions did produce high yields of Al polymers useful to water treatment applications. The method of characterization analysis was based on timed spectrophotometer with ferron as a color developing reagent. The hydrolytic Al species were divided into monomeric(Ala), polymeric(Alb), and precipitate(Alc) from the difference in reaction kinetics.
The analysis of PACㅣ's characteristics showed that the quantity of polymeric Al produced at value of r(OHadded/Al) = 2.2 was 83% of the total aluminum in solution, as showing maximum contents and precipitated Al was dramatically increased when r was increased above 2.35. In addition, the characteristics of polyaluminum sulfate (PAS) showed that polymeric Al contained at r = 0.75 was 18% of the total aluminum in solution. The synthesized PACl and PAS were stable during storing period, as indicating negligible aging effect.
The effect of sulfate ion on PACl was dependent on the concentration of sulfate ion. That is, polymeric species decrease and precipitate species increase as sulfate ion concentration increased. It can be concluded that the sulfate cause the formation of Al(OH)3(s) at low pH. However, The effect of calcium ion was negligible for distribution of Al species.
This experiment was performed on three parts with prepared coagulants. (1) The characterization of coagulation for PACl coagulants. (2) Comparison of the characterization of coagulation with PAS and PACl coagulants. And (3) Comparison of the characterization of coagulation for the addition of calcium with PACl. Coagulation experiments were conducted with several dosages and pH for each coagulants. For the characterization of coagulation with PACl coagulants, coagulation of Nakdong river waters with three PACls (r=2.0, 2.2, 2.35) showed that the effectiveness of the three coagulants can be considered as r=2.2 > 2.0 > 2.35 which are also the order of higher polymeric aluminum contents. For the comparison of the characterization of coagulation for PAS and PACl coagulants, PAS (r=0.75) coagulants was more effective than other coagulant for the removal of organic matters by sweep floc mechanism with Al(OH)3(s). For comparison of the characterization of coagulation for the addition of calcium with PACl, the presence of divalent cation like Ca2+ was supposed to influence the complex formation of organic anions. From the result of test on coagulation at various pH ranges, the PACl was least affected by the coagulation pH, and the addition of calcium to PACl was very effective for the removal of turbidity and organic materials over broader pH range (pH 4-9).
The advanced oxidation process (AOP) using ozone combined with hydrogen peroxide and ultraviolet treatment were evaluated for biodegradable dissolved organic carbon (BDOC) formation and dissolved organic carbon (DOC) removal. Oxidation treatment were conducted alone or combination with ozone, hydrogen peroxide and ultraviolet processes.
Ozone dosage of ozone process was varied from 0.5㎎/ℓ·min to 5㎎/ℓ·min. Ozone/hydrogen peroxide process was done using 20㎎/ℓ of hydrogen peroxide concentration. Ozone/ultraviolet process was irradiated with 12mW/㎠ of density and 254nm. Ozone dosage was varied from 0.5㎎/ℓ·min to 5㎎/ℓ·min at the ozone/hydrogen peroxide and ozone/ultraviolet processes too. Contact time of all the process was 20 minutes. Oxidation treatment were performed on microfiltration effluent samples.
BDOC formation was reached to an optimum at ozone dosage of 1.5㎎/ℓ·min in the ozone/hydrogen peroxide process and 1㎎/ℓ·min in ozone/ultraviolet process, after which BDOC formation was decreased at higher ozone dosages. But BDOC formation was increased with ozone dosages increasing in ozone process. The efficiency of DOC removal was higher AOPs than ozone process. Ozone/ultraviolet proces was the highest for DOC removal efficiency in each process. THMFP removal efficiency by ozone/ultraviolet process was higher than that by each of ozone process and ozone/hydrogen peroxide process.