간행물

한국환경과학회지 KCI 등재 Journal of Environmental Science International

권호리스트/논문검색
이 간행물 논문 검색

권호

제10권 제6호 (2001년 12월) 10

1.
2001.12 서비스 종료(열람 제한)
The hydroxyapatite(HAp) as a carrier the for ion exchange agent of Ag+ions was prepared in semiconductor fabrication, The Ca/P molar ratio of the HAp was 1.65. The HAp is molded in shape of the antimcrobial ball and then sintered at 1000℃. Ag-containing HAp(HAp-Ag) was prepared by incorporating Ag+ions in HAp crystals through an ion-exchange reaction in solutions containing 0.01M AgNO3. The antimicrobial effect of HAp-Ag for bacteria such as Escherichia coli and Staphylococcus aureus has been investigated. The concentrations of silver in the antimicrobial ball was determined by inductively coupled plasma and the amount of Ag+ion was 9.0㎍/g. The HAp-Ag exhibited excellent antimicrobial effect for bacteria such as E. coli and S. aureus. The bactericidal activity was considered to be caused by direct contact of bacteria with Ag+ions in the HAp crystals. The HAp would likely to be possible as a carrier of antimicrobial metal ions such as Ag, Cu, and Zn by recycling of waste sludge in the semiconductor fabrication process.
2.
2001.12 서비스 종료(열람 제한)
This study was carried out to evaluate the pollutant removal efficiencies of the advanced drinking water treatment using ozonation. For raw water, Nakdong River was used. By conducting batch ozonation test, the following results were obtained. When ozone dosage of 5㎎/ℓ was used, preozonation of raw water reduced turbidity, KMnO4 consumption, DOC(dissolved organic carbon), UV254 absorbance, THMFP(trihalomethane formation potential) as much as 3.9 NTU, 5.5㎎/ℓ, 1.15㎎/ℓ, 0.112 and 0.065㎎/ℓ, respectively. In case of postozonation of sand filtered water, water quality was also improved with decrease in turbidity, KMnO4 consumption, DOC, UV254 absorbance and THMFP at the amount of 0.08NTU, 2.6㎎/ℓ, 0.88㎎/ℓ, 0.042 and 0.018㎎/ℓ, respectively. On the other hand, contents of dissolved oxygen increased at the level of 1.3㎎/ℓ after preozonation process' and 1.0㎎/ℓ after postozonation process. The effect of ozone dosage was higher than that of its contact time for the removal of the pollutants.
3.
2001.12 서비스 종료(열람 제한)
For the purpose of developing a new process for the elimination of oil components from oily waste water, experimental researches using oil gelling agent were performed. The process is composed of three units, that is, decantator, gelling column and adsorption column. l0g of gelling agent in the gelling column could effectively absorb 15.65g of oil from ship washing waste water and 16.93g of oil from steel industry waste water. COD in waste waters dramatically diminished not in the gelling column but in the adsorption column. The gelling is hindered by other organic components in waste water, and the optimum space time for the gelling column is 20min. lg of gelling agent absorbed 3.7-4.0g of oil from waste waters with 25 min in the batch operation.
4.
2001.12 서비스 종료(열람 제한)
A case of air pollution study of estimation of emission rate for source to railroad rolling stock and emissive character about is unusual. Recent emission rate of railroad rolling stock was estimated with emission factor of EPA in three region(Seoul, Incheon, and Gyeonggido). But this EPA factor could be incorrect because Korea and America have a different railroad environment in the variety of fuel and character of railroad rolling stock. In this study, emission rate of each line, car and region(district) with emission factor of Korean case(National Railroad Administration, 1997) was estimated. In Busan Metropolitan City, railroad rolling stocks were divided accoding to, each line, car and service. Particularly, the idle fuel rate omitted in the preceding study was included in calculation fuel rate. Total emission rate of Busan Metropolitan City was 887.41t/year. Each emission rates of Kyeongbu line, Donghaenambu line, Gaya line, Uam line, Bujeon line, and idle was 489.15t, 196.46t, 33.94t, 12.66t, 6.47t, and 148.72t, respectively.
5.
2001.12 서비스 종료(열람 제한)
The vertical structure of atmosphere was observed to investigate the variation of surface ozone concentration by vertical downward mixing of residual ozone in the atmospheric boundary layer at the Busan coastal area. Airsonde and pilot balloon measurements were made at Gamcheondong and the Kimhae airport for April 26∼27, 1996. The vertical profile of potential temperature showed a residual layer between 510m and 1800m from 2100LST April 26 to 0900LST April 27. The downward mixing of ozone in the residual layer of the atmospheric boundary layer was confirmed from vertical profile of mixing ratio near 600m in the morning. The thickness of the sea breeze layer was 900m at 1500LST April 26. Thereafter, it become to be lowered with time. A low level jet was measured near 900m at 0300LST on April 27 from a pibal measurement. Early morning sharp increase of surface ozone concentration at the Busan coastal area was caused by vertical downward mixing of ozone concentration rather than by photochemical reaction in the atmospheric boundary layer.
6.
2001.12 서비스 종료(열람 제한)
Satellite data, with sea surface temperature(SST) by NOAA and sea level(SL) by Topex/poseidon, are used to estimate characteristics on the variations and correlations of SST and SL in the East Asian Seas from January 1993 through May 1998. We found that there are two climatic characteristics in the East Asian seas: the oceanic climate, the eastern sea of Japan, and the continental climate, the eastern sea of China, respectively. In the oceanic climate, the variations of SL have the high values in the main current of Kuroshio and the variations of SST have not the remarkable seasonal variations because of the continuos compensation of warm current by Kuroshio. In the continental climate, SL has high variations in the estuaries(the Yellow River, the Yangtze River) with the mixing the fresh water and the saline water in the coasts of continent and SST has highly the seasonal variations due to the climatic effect of continents. In the steric variations of summer, the eastern sea of Japan, the East China Sea and the western sea of Korea is increased the sea level about 10∼20㎝. But the Bohai bay in China have relatively the high values about 20∼30㎝ due to the continental climate. Generally the trends of SST and SL increased during all periods. That is say, the slopes of SST and SL is presented 0.29℃/year and 0.84㎝/year, respectively. The annual and semi-annual amplitudes have a remarkable variations in the western sea of Korea and the eastern sea of Japan. In the case of the annual peaks, there appeared mainly in the western sea of Korea and the eastern sea of Japan because of the remarkable variations of SL associated with Kuroshio. But in the case of the semi-annual peaks, there appeared in the eastern sea of Japan by the influence of current, and in the western sea of Korea by the influence of seasonal temperature, respectively. From our results, it should be believed that SST and SL gradually increase in the East Asian seas concerning to the global warming. So that, it should be requested to the international co-operation against to the change of the abnormal climate.
7.
2001.12 서비스 종료(열람 제한)
Variations in phytoplankton concentrations result from changes of the ocean color caused by phytoplankton pigments. Thus, ocean spectral reflectance for low chlorophyll waters are blue and high chlorophyll waters tend to have green reflectance. In the Korea region, clear waters and the open sea in the Kuroshio regions of the East China Sea have low chlorophyll. As one moves even closer to the northwestern part of the East China Sea, the situation becomes much more optically complicated, with contributions not only from higher concentrations of phytoplankton, but also from sediments and dissolved materials from terrestrial and sea bottom sources. The color often approaches yellow-brown in the turbidity waters (Case Ⅱ waters). To verify satellite ocean color retrievals, or to develop new algorithms for complex case Ⅱ regions requires ship-based studies. In this study, we compared the chlorophyll retrievals from NASA's SeaWiFS sensor with chlorophyll values determined with standard fluorometric methods during two cruises on Korean NFRDI ships. For the SeaWiFS data, we used the standard NASA SeaWiFS algorithm to estimate the chlorophyll a distribution around the Korean waters using Orbview/ SeaWiFS satellite data acquired by our HPRT station at NFRDI. We studied to find out the relationship between the measured chlorophyll a from the ship and the estimated chlorophyll a from the SeaWiFS satellite data around the northern part of the East China Sea, in February, and May, 2000. The relationship between the measured chlorophyll_a and the SeaWiFS chlorophyll_a shows following the equations (1) in the northern part of the East China Sea. Chlorophyll_a=0.121Ln(X) + 0.504, R2 = 0.73 (1) We also determined total suspended sediment mass (SS) and compared it with SeaWiFS spectral band ratio. A suspended solid algorithm was composed of in-situ data and the ratio (LWN(490 nm)/LWN(555 nm)) of the SeaWiFS wavelength bands. The relationship between the measured suspended solid and the SeaWiFS band ratio shows following the equation (2) in the northern part of the East China Sea. SS=-0.703 Ln(X) + 2.237, R2 = 0.62 (2) In the near future, NFRDI will develop algorithms for quantifying the ocean color properties around the Korean waters, with the data from regular ocean observations using its own research vessels and from three satellites, KOMPSAT/OSMI, Terra/MODIS and Orbview/SeaWiFS.
8.
2001.12 서비스 종료(열람 제한)
The characteristic features of surface ozone concentration and the forecasting procedure of high ozone days have been studied. The ozone concentration was continuously measured during 3 years (1997∼1999) at air quality monitoring stations in five major cities in Korea. The diurnal variation of surface ozone concentration on high ozone days is characterized by low ozone concentration at night. The ozone concentration increases continuously after sunrise, to reach a peak at 1500∼1600 LST. Thereafter it decreases steadily to a low concentration at sunset. The diurnal and annual maximum of the surface ozone concentration at Seoul were observed in May and June, respectively. The favorable synoptic condition for the high ozone day is divided into 4 different synoptic weather patterns: a high-pressure system from the Sea of Okhotsk, the Pacific subtropical high extending westward, a moving high-pressure system covering the Korean peninsula, and a synoptic system in front of a typhoon. Most of high ozone days occur under the high pressure system in Korea.
9.
2001.12 서비스 종료(열람 제한)
This study was carried out to investigate the correlation between toluene in air and hippuric acid in human urine, which is based on the results of the health check-in and the measure of working environment, was investigated for two years. The concentration of toluene in air for the five working places in Yang-San area were ranged from 39.05±10.31 ppm to 4.04±3.38ppm and the mean value of those was 16.89±14.76ppm. The mean value was 16.89±14.76ppm which is below the permissible limit of toluene. The concentration of hippuric acid(HA) in the worker's urine were between 0.47g/ℓ and 0.76g/ℓ. There was mutual correlation (r=0.94) between the concentration of toluene in air and that of hippuric acid in urine. In case of male workers, the mean value of hippuric acid in urine was 0.56g/ℓ and the female workers was 0.57g/ℓ that showed higher than the male's. However, there was no relationship between the workshop and the distinction of sex. From the mean value of toluene in air(T) and that of hippuric acid(H), we obtained the formula, H= 0.3log T+0.235
10.
2001.12 서비스 종료(열람 제한)
Adsorption characteristics of triadimefon and diniconazole(pesticide) by natural zeolite(CLIN) and several synthetic zeolites were investigated. The synthetic zeolites used in this study were as follows: Faujasite synthesized from coal fly ash(FAUF); Zeolite synthesized from the mixture of FAU and Na-Pl synthesized from the ratio of Cheju scoria 6 to coal fly ash 4 by weight((FAU + Na-Pl)SF); Waste fluid catalytic cracking catalyst(FCCw). The distribution coefficient, KD and Freundlich constant, KF decreased in the following sequence : FCCW>FAUF>(FAU+Na-Pl)SF > CLIN among the zeolites. The distribution coefficient and the adsorption capacity of (FAU + Na-Pl)SF for pesticides were 4.4 and 2.6 times higher for triamefon, and 2.0 and 2.4 times higher for diniconazole than those of CLIN, respectively.