Having the Seorak mountain National Park as an object of study, this research grasps the problems of the present environmental observatories through the awareness investigations of visitors towards the function of environmental observatories made by the evironmental education. In order to achieve this, a questionaire has been conducted for 26 days, starting from the 25th October 2002, directed towards 100 visitors to the Seorak mountain National Park about the maps and degree of satisfaction of the usage ofthe environment observatory and explanation program. The results of the analysis show that general satisfaction on the environmental observatories are valued very negatively. This informs us that the present environmental observatories under the environment education are not fullfilling entirely their functions. Supporting itself upon the basis of the visitors' questionaire, this research has attempted the resolution of the present problems having as an object of study the scenery and cultural resources present in the Seorak mountain National Park, and proposing an entertaining environmental education of the environment observatory’s constitution.
The Neural Network Models which mathematically interpret human thought processes were applied to resolve the uncertainty of model parameters and to increase the model's output for the streamflow forecast model. In order to test and verify the flood discharge forecast model eight flood events observed at Kumho station located on the midstream of Kumho river were chosen. Six events of them were used as test data and two events for verification. In order to make an analysis the Levengerg-Marquart method was used to estimate the best parameter for the Neural Network model. The structure of the model was composed of five types of models by varying the number of hidden layers and the number of nodes of hidden layers. Moreover, a logarithmic-sigmoid varying function was used in first and second hidden layers, and a linear function was used for the output.
As a result of applying Neural Networks models for the five models, the N10-6model was considered suitable when there is one hidden layer, and the N10-9-5model when there are two hidden layers. In addition, when all the Neural Network models were reviewed, the N10-9-5model, which has two hidden layers, gave the most preferable results in an actual hydro-event.
We have studied the catalytic combustion of soot particulates over perovskite-type oxides prepared by malic acid method. The catalysts were modified to enhance the activity by substitution of metal into A or B site of perovskite oxide. In addition, the reaction conditions such as temperature and O2 concentration were investigated. The partial substitution of alkali metals into A site in the LaMnO3 catalyst, enhanced the catalytic activity in the combustion of carbon particulate and the activity was shown in the order: Cs>K>Na. For the La1-xCsxMnO3 catalysts, the catalytic activity showed the maximum value with x=0.3 but no more increase on the catalytic activity was shown with x>0.3. For the La0.8Cs0.2MnO3 catalyst, the substitution of Fe or Ni increased the ignition temperature. The ignition temperature decreased with an increase of O2 concentration, however, no more increase in the catalytic activity was shown with O2 concentration>0.2. The introduction of NO into reactants showed no effect on the catalytic activity.
Evaluated were household THMs exposure associated with the use of municipal tap water treated with chlorine and with ozone-chlorine. The current study measured the THMs concentrations in the tap water and indoor and outdoor air in the two types of household, along with an estimation of THMs exposure from water ingestion, showering, and the inhalation of indoor air. Chloroform was the most abundant THMs in all three media, yet no bromoform was detected in any sample. Contrary to previous findings, the fall water THMs concentrations exhibited no significant difference between the chlorine and ozone-chlorine treated water. However, the spring median chloroform concentration in the tap water treated with chlorine (17.6 ppb) was 1.3 times higher than that in the tap water treated with ozone-chlorine (13.4 ppb). It is suggested that the effects of the water parameters should be considered when evaluating the advantage of ozone-chlorine disinfection for THMs formation over chlorine disinfection. The indoor air THMs concentration trend was also consistent with the water concentration trend, yet the outdoor air THMs concentrations did not differ significantly between the two types of household. The indoor to outdoor air concentration ratios were comparable with previous studies.
The THMs exposure estimates from water ingestion, showering, and the inhalation of indoor air suggested that, for the residents living in the surveyed households, their exposure to THMs in the home was mostly associated with their household water use, rather than the indoor air. The THMs exposure estimates from tap water ingestion were similar to those from showering.
A new method of automatic recording raingauge is developed to measure rainfall with 0.01mm resolution. This use two different signals to measure rainfall more accurately compare than other raingauges. One is weight of the tipping bucket with rainfall amount and the other is pulse from tipping bucket reverse. New method applied 1 mm tipping bucket mechanism and install loadcell under tipping bucket mechanism for measuring rainfall weight. Loadcell measure weight of rainfall until 1 mm with 0.01 mm resolution and more than 1 mm than bucket reverse and pulse signal generate, after that loadcell measure weight again.
The validation of new instrument was examined in the room 65 mm/hour rainfall rate total 53 mm range. There is below than 1 % error of absolute rainfall amount and 0.01 mm resolution. The field test of instrument was carried out by comparing its measured values with values recorded by weight type and standard type on June 1 2003 at Terrestrial Environmental Research Center at Tsukuba University in Tsukuba of Japan, when it has recorded total amount of 40.58 mm rainfall by standard raingauge and new raingauge recorded 41.032 mm. Same rainfall intensity pattern observed in field observation with weight type raingauge. Rainfall intensity between weight type and Lee-A type raingauge reached 0.9947 correlation in 3 minute average.
Indoor air quality is affected by source strength of pollutants, ventilation rate, decay rate, outdoor level, and so on. Although technologies measuring these factors exist directly, direct measurements of all factors are not always practical in most field studies. The purpose of this study was to develop an alternative method to estimate these factors by application of multiple measurements. For the total duration of 30 days, daily indoor and outdoor NO2 concentrations were measured in 30 houses in Brisbane, Australia, and for 21 days in 40 houses in Seoul, Korea, respectively. Using a box model by mass balance and linear regression analysis, penetration factor (ventilation divided by sum of air exchange rate and deposition constant) and source strength factor (emission rate divided by sum of air exchange rate and deposition constant) were calculated. Subsequently, the ventilation and source strength were estimated. In Brisbane, the penetration factors were 0.59±0.14 and they were unaffected by the presence of a gas range. During sampling period, geometric mean of natural ventilation was estimated to be 1.10±1.51 ACH, assuming a residential NO2 decay rate of 0.8 hr-1 in Brisbane. In Seoul, natural ventilation was 1.15±1.73 ACH with residential NO2 decay rate of 0.94 hr-1. Source strength of NO2 in the houses with gas range (12.7±9.8 ppb/hr) were significantly higher than those in houses with an electric range (2.8±2.6 ppb/hr) in Brisbane. In Seoul, source strength in the houses with gas range were 16.8±8.2 ppb/hr. Conclusively, indoor air quality using box model by mass balance was effectively characterized.
This paper demonstrates the numerical simulation of three dimensional flow pattern for vehicular exhaust dispersion in the street canyons. The wind flow around buildings in urban is computed by the SIMPLEST method. The convection-diffusion equation was used to compute the NOx concentration level near buildings. Details are given of important boundary conditions and turbulence quantities variations. The simple turbulence model was used for unisotropic viscous effect. A control-volume based finite-difference method with the upwind scheme is employed for discretization equation. The simple turbulence model applied in this study has been verified through comparison between predicted and measured data near buildings. By the predictive results, the updraft induced by the presence of high-rise buildings is important in the transport of street level pollutant out from the street canyons. Our suggestion for reducing ground level pollution is to have high-rise buildings constructed or to reduce the channelling effect of street canyons.
As the concentration of ammonium nitrogen could be reached 2~3 mg/L in the winter in the river. It was clear that the excessive concentration of chlorinated organics could be produced with the increase of chlorine addition to remove ammonium nitrogen. In the innovative ammonium nitrogen removal process, zeolite adsorption is very efficient as substitute for rapid sand filtration without other adverse quality change in the water.
This study is conducted to evaluate the feasibility of ammonium nitrogen removal and regeneration by zeolite adsorption in drinking water treatment. Also, the reuse possibility of zeolite is evaluated to change the removal efficiency of ammonium nitrogen through several times of regeneration.
The ammonium nitrogen was not removed in sand filter, but it was almost removed in zeolite filter during 7 days. The sand and zeolite filters have a similar result of turbidity removal. Therefore, zeolite filtration was confirmed the removal of turbidity and ammonium nitrogen as a media. When compared KCl with NaCl as a chemical for zeolite regeneration, it is demonstrated that KCl was more efficient than NaCl in the ability of zeolite regeneration.
The adsorption rate of ammonium nitrogen was almost not decreased in the results of several times of regeneration. It is indicated that both zeolite and regeneration solution were possible to reuse without variation of regeneration rate through this study.
The objective of this study was to investigate the effects of pH and temperature on the formation of bromate, which is ozonation by-products, during ozonation.
In this experiment, the operating parameters including pH 3~10 and temperature 15~30℃ were studied. Through the study for the bromate formation, reaction rate constant, and ozonation effect index on pH and temperature, the results obtained are as follows. At the same initial pH condition, the increase of pH shown similar trends even if the reaction variables such as temperature and reaction time of ozonation were exchanged. As pH and temperature were increasing, the bromate concentration was increased but bromine(HOBr+OBr-) was decreased with increasing pH from 3 to 10. The activation energy(J/mol) for bromate formation decreased with increasing pH. The rate constants of bromate formation for the reaction of ozone and bromide, and ozone dosage coefficient(Ko) increased with temperature and pH. Ozonation effect index(OI) decreased with increasing temperature and pH.
This study was conducted to remove organics and nutrients using 2 stage intermittent aeration reactor. First reactor, using suspended microbial growth in intermittent aeration instead of anaerobic reactor in the typical BNR process, used minimum carbon source to release P, and it was possible to reduce ammonia loading going to second reactor. In the second reactor, using moving media intermittent aeration, it was effective to reduce nitrate in non-aeration time by attached microorganisms having long retention time. In aeration time, nitrification and P uptake were taken place simultaneously.
From the experiment, two major results were as follows.
First, the removal of organics was more than 90%, and optimum aeration/non-aeration time ratio for organic removal was corresponded with aeration/non-aeration time ratio for nitrogen removal.
Second, in the first reactor, optimum aeration/non-aeration time ratio was 15/75 (min.) because it was necessary to maintain 75 min. of non-aeration time to suppress of impediment of return nitrate and to lead release of phosphate. In the second reactor, optimum aeration/non-aeration time ratio was 45/90 (min.).
This study was focused on the manufacturing method of a dewatering aid, which would reduce the water content of the sludge cake by enhancing the dewaterability of sewage sludge. The pretreatment technology for sludge by using radiation and among diverse discarded resources were starfish selected as the material to manufacture the dewatering aid. Starfish went through the process of washing, drying, and pulverizing. The starfish powder made in this process was applied to the digested sludge generated at the sewage treatment plant of D City, and its effects were investigated.
The starfish powder that was 300 μm in particle size was added to the irradiated digested sludge. After the application of the condensation process, the sludge with the starfish powder added was dewatered using the belt press and centrifuge, which were the traditional pressure dewatering devices. As the result, it reduced the water content of the sludge 20% higher than the dewatered cake with no dewatering aid added and irradiation. When the powder was added, it contributed to less use of the coagulant added. The more irradiation dose, the lower water content did the dewatered cake have and the more coagulant was needed for condensation, which seems to be a disadvantage that can be compensated for by the starfish dewatering aid.
A small-scaled treatment of the study to a radiation technology and dewatering aid using a discarded resource confirmed the potential of dewaterability. Based on the results saying that the dewatering aid and radiation technology can improve dewatering effects using the traditional dewatering devices, this pretreatment technology will be expected to be applied to sewage treatment plants.
The properties of biosorption of dye(Rhodmine B) was investigated to figure out the effects of temperature as a function of dye concentration and sludge concentration by the Langmuir and Lagergen adsorption model. It was found that the uptake capacity of biosorption was increased at low temperature. The Langmuir adsorption model was found suitable for describing the biosorption of the dye. The experimental results indicated that the dye uptake process followed the pseudo-first-order kinetics.
Most of methane gas result from waste matter in landfill, therefore the persons concerned take an increasing interest in management of gases in landfill. Infrared Gas Analyzer was used to measure components of gases, CH4, CO2, O2, through gas exhausted pipe. To measure amount of the gas flow meter(Portable Hot-Line Current Meter) was used and it was set at right angles with direction of the flow. In this research the total amount of methane gas produced in Beck-Suk Landfill was calculated through FOD method suggested by IPCC. This research found that in Chon-An Beck-Suk Landfill anaerobic resolution was made actively and the amount of methane gas produced there was 54.14%, which is higher than common figure, 50%, in other researches. The components of reclaimed waste matter, especially, organic waste matter can have a great effect of the amount of the greenhouse gases produced in landfill. We can expect that the amount of greenhouse gas will decrease from 2005, when it will be prohibited from carrying kitchen refuse and sludge into landfill.
Petroleum refineries have been considered as an important emission source for atmospheric volatile hazardous air pollutants(HAPs). The emission source includes petroleum refinery processes and process equipment. The control strategy for volatile HAPs requires emission estimations of these pollutants. However, systematic methods of volatile HAPs emission from petroleum refineries have not yet been established. Accordingly, present study surveyed the estimation method of volatile HAPs emitted from the petroleum refinery processes and process equipment. The emission estimation methods for the petroleum refinery processes are applied for 11 petroleum refining facilities: fluidized catalytic cracking, thermal cracking, moving bed catalytic cracking, compressed engine, blowdown system, vacuum distilled column condensator, natural gas or distilled boiler, natural gas or distilled heater, oil boiler, oil heater and flare. Four emission estimation methods applied for the petroleum refinery process equipment are as follows: average emission factor approach, screening ranges approach, EPA correlation approach and unit-specific correlation approach. The process equipment for which emission factors are available are valves, pump seals, connectors, flanges and open-ended lines.