간행물
한국환경과학회지 KCI 등재 Journal of Environmental Science International
- 발행기관 한국환경과학회
- 자료유형 학술지
- 간기 월간
- ISSN 1225-4517 (Print)2287-3503 (Online)
- 수록기간 1992 ~ 2023
- 주제분류 자연과학 > 자연과학일반 자연과학 분류의 다른 간행물
- 십진분류KDC 539DDC 628
권호리스트/논문검색
제7권 제6호 (1998년 12월) 19건
1.
1998.12
서비스 종료(열람 제한)
This research emphasizes the necessity of building a multilateral environmental cooperation. The Process and Problems of multilateral environmental cooperation system are discussed, and some policy proposals are suggested. Especially for Northeast Asia, a comprehensive multilateral environmental cooperation system is required because of transborder pollutions. Within the contractual environment, international institutions can help the parties of conference to build up national capacity to cope with environmental threat.
2.
1998.12
서비스 종료(열람 제한)
The well-mixed room model has been traditionally used to predict the concentrations of contaminants in indoor environments. However, this is inappropriate because the flow fields in many indoor environments distribute contaminants non-uniformly, due to imperfect air mixing. Thus, some means used to describe an imperfectly mixed room are needed. The simplest model that accounts for imperfect air mixing is a two-zone model. Therefore, this study on development of computer program for the two-zone model is carried out to propose techniques of estimating the concentration of contaminants in the room. To do this, an important consideration is to divide a room into two-zone, i.e. the lower and upper zone assuming that the air and contaminants are well mixed within each zone. And between the zones the air recirculation is characterized through the air exchange parameter. By this basic assumption, the equations for the conservation of mass are derived for each zone. These equations are solved by using the computational technique. The language used to develope the program is a VISUAL BASIC.
The value of air exchange coefficient(f_12) is the most difficult to forecast when the concentrations of contaminants in an imperfectly mixed room are estimated by the two-zone model. But, as the value of f_12 increases, the air exchange between each zone increases. When the value of f_l2, is approximately 15, the concentrations in both zone approach each other, and the entire room may be approximately treated as a single well-mixed room. Therefore, this study is available for designing of the ventilation to improve the air quality of indoor environments. Also, the two-zone model produces the theoretical base which may be extended to the theory for the multi-zone model, that will be contributed to estimate the air pollution in large enclosures, such as shopping malls, atria buildings, airport terminals, and covered sports stadia.
3.
1998.12
서비스 종료(열람 제한)
In physical and reactive extraction of acrylic acid using various solvents the equilibrium characteristics of extraction were investigated.
The degree of extraction in reactive extraction with Tri-n-octylamine(TOA) was 1.5∼3 times than that in physical extraction. Distribution ratio was constant in methyl isobutyl ketone(MIBK) and n-butylacetate(n-BAc) but was increased with increasing the concentration of acrylic acid in benzene and chloroform. It can be explained by formation of dimers.
Maximum extraction loadings of acrylic acid were three in benzene and were two in MIBK, chloroform and n-BAc, and it was found that acrylic acid was extracted as the form of A_3R in benzene and A_2R in MIBK, chloroform and n-BAc. In effect of solvent, the degree of extraction was increased as the difference of solubility parameter of solvent and solute was decreased, and as dielectric constant of solvent was increased.
4.
1998.12
서비스 종료(열람 제한)
This study was performed to determine the optimum coagulant dosing amount for effective treatment of raw water. The removal rate of turbidity and the variations of water qualities according to various dosage of coagulants such as Alum, PAC and PACS were investigated.
The optimum coagulant dosing amount to make the lowest turbidity of water were 35㎎/ℓ of Alum, 30㎎/ℓ of PAC and l0㎎/ℓ of PACS in case of 5 NTU of raw water turbidity, and 30㎎/ℓ of Alum, 25㎎/ℓ of PAC and l0㎎/ℓ of PACS in case of 10 NTU of that, respectively.
The removal rates of turbidity at 4 min. and 8 min. of settling time were 10 and 72% of Alum, 44 and 62% of PAC and 25 and 55% of PACS in case of 5 NTU, and 52 and 70% of Alum, 90 and 95% of PAC and 10 and 28% of PACS in case of 10 NTU, respectively.
Judging from the settling capability of floc., the reaction time of floc. formation and removal efficiency of turbidity, PAC was evaluated as more effective coagulant than Alum and PACS. Also PAC was regarded as the most effective coagulant when the water supply was changed sharply and the fluctuation of the surface loading occured with wide and sharp in seettling basin.
pH and alkalinity of the water were decreased with increasing coagulants dosage. But pH and alkalinity were not decreased below 5.8 which is the standard for drinking water quality, and l0㎎/ℓ which is the limit concentration of floc. breakage, respectively.
Residual Al of the treated water was decreased with increasing coagulants dosage in case of 5 and 10NTU of raw water turbidity.
KMnO_4 consumption of the water was decreased with increasing coagulants dosage. The reduction rate of KMnO_4 consumption at the optimum coagulants dosage were 39% of Alum, 18% of PAC and 11% of PACS in case of 5 NTU of raw water turbidity, and 42% of Alum, 27% of PAC and 36% of PACS in case of 10 NTU of that, respectively. Any relationship was not found between the removal rate of turbidity and KMnO_4 consumption.
TOC of the water was a bit decreased with increasing coagulants dosage up to 30㎎/ℓ but not changed above 30㎎/ℓ of coagulants dosage. The degree of TOC reduction was increased in the order of Alum, PAC and PACS treatment.
Zeta potential of the colloidal floc. at the optimum coagulants dosage was in the range of -20∼-15mV in case of 5 NTU of raw water turbidity and 0∼0.5mV in case of 10 NTU of that, respectively. Although the kinds and dosages of coagulants were different, zeta potential range were fixed under the conditions of the best coagulation efficiency.
5.
1998.12
서비스 종료(열람 제한)
The adsorption experiment of phenol(Ph) from aqueous solution on granular activated carbon was studied in order to design the fixed-bed adsorption column. The experimental data were analyzed by unsteady-state, one-dimensional heterogeneous model. Finite element method(FEM) was applied to analyze the sensitivity of parameter and to predict the fixed-bed adsorption column performance on operation variable changes. The prediction model showed similar effect to mass transfer and intraparticle diffusion coefficient changes suggesting that both parameter present mass transfer rate limits for GAC-phenol system. The Freundlich constants had a greater effect than kinetic parameters for the performance of fixedbed adsorption column. FEM solution facilitated prediction of concentration history in solution and within adsorbent particle.
6.
1998.12
서비스 종료(열람 제한)
The objectives of this study were to investigate the characteristics of desulfurization under different experimental conditions and the effects of desulfurization in a fluidized bed combuster installed with the screen. The experimental results were as follows ; First, as the height of fluidized bed combustor becomes higher, the concentrations of SO_2 mainly increased and sulfur retion of paper sludge was higher than that of natural limestone. Second, the desulfurization by natural limestone occurred at in-bed and the desulfurization by paper sludge occurred in the whole of fluidized bed combuster. In additiion, we identified calcium sulfate by the analysis of SEM and XRD. Third, screen at splash region increased sulfur retention 2∼5%, air velocity and anthracite fraction had a little effect on the sulfur retention.
7.
1998.12
서비스 종료(열람 제한)
In this study, the Dilution Method is used to measure river discharge through the hydraulic model test. the dilution method is divided into Constant-Rate-Injection Method and Slug-Injection Method in the river discharge measurement techniques. When the dilution method is applied in the hydraulic model flume, it is analyzied that the estimated error of constant-rate-injection method is less than that of the slug-injection method, and the result shows that floodflow analysis is more efficient than lowflow analysis as compared observed discharge with calculated discharge. The result of statistical error analysis shows that the constant-rate-injection method is appropriate technique for the measurement of the river discharge.
Therefore, the dilution method among the river discharge measurement techniques can be applied for the river basin which can`t be measured with current meter or unsteady-flow regime in the urban-small drainage or hydraulic structure equipment area and can be obtained more exact results than any other discharge measurement techniques.
8.
1998.12
서비스 종료(열람 제한)
Heavy metal ions in water were removed using algal biomass as adsorbents. Absorbents were dried for 3 days, ground them by 40∼60 mesh and then were swelled in a buffer solution for 1hr. After being packed in the column, commercially available standard solution of Cd(Ⅱ) and Pb(Ⅱ) ions were diluted to get the suitable concentration and then it was eluted with the rate of 1 ㎖/min. Heavy metals on the adsorbents were recovered with nitric acid.
More amounts of Cd(Ⅱ) or Pb(Ⅱ) ions in green algae, Ulva pertusa, than in brown algae, Sargassum hornerl, were adsorbed. Pb(Ⅱ) ion was adsorbed more than Cd(Ⅱ) ion in both algae. The pH effect of adsorbed amounts of Cd(Ⅱ), Pb(Ⅱ) ions on the biomass was shown the following order ; pH 10.5 > 8.5 > 7.0 > 5.5 > 3.5. Recovery ratio of metal ions from algae is shown higher in acidic or neural conditions than It in alkalis ones. Pb(Ⅱ) ion is recovered relatively more than Cd(Ⅱ) ion in our system.
9.
1998.12
서비스 종료(열람 제한)
Currently in Korea, standard operating procedure for the analyses of phenolic compounds in water is the spectrometric comparison of colors developed by 4-amino antipyrin with phenolic compounds. It is however that this method cannot identify individual compound and that some phenolic compounds do not react with 4-amino antipyrin. Spectrometric determinations of phenolic compounds were compared with chromatographic analyses of gas chromatography (GC) and high pressure liquid chromatography (HPLC) of various phenolic compounds. Individual phenolic compounds could be determined by both chromatographic methods but HPLC methods were more precise with lower detection levels in general.
10.
1998.12
서비스 종료(열람 제한)
A three-dimensional ecosystem model is applied to the Suyoung Bay, located at the southeastern part of Korea, to study of the material distribution in the time scale of several tens days. The model has included of the DIN(Dissolved Inorganic Nitrogen), DIP(Dissolved Inorganic Phosphate), phytoplankton, zooplankton and detritus, and also was coupled with the physical processes. The spatial distribution of chlorophyll-a and primary productivity in the model is determined by the physical and chemical-biological parameters. The horizontal distributions of the DIN, DIP and chlorophyll-a are decreased from the coast to the off-shore, though the nutrients show some more complicated pattern than the chlorophyll-a. The nutrient contents in the off shore are low, and thus a relatively low productivity(chlorophyll-a) are presented. On the whole, the distribution of the results of model are smoother than the observed ones and some small scale variation in the observed data cannot be reproduced by the model due to the resolution limits of model. However, the basic pattern and the quantitavities has been reproduced by the model well.
11.
1998.12
서비스 종료(열람 제한)
Statistical SO_2 forecasting technique by multiple regression analysis was designed and developed to predict SO_2 concentration in Wonju City.
SO_2 concentration data measured from air pollution monitoring system and meteorological factors data such as : wind speed, atmospheric stability, surface temperature, relative humidity and precipitation were used in Wonju City during the 1996∼1997.
As the results, correlation model for forecasting was well fitted with some parameters including minimum temperature, wind speed and the SO_2 concentration of the previous day.
12.
1998.12
서비스 종료(열람 제한)
It is noted that the red tides and the oxygen-deficient water mass are extensively developed in Masan Bay during summer. The nutrients mass balance was calculated in Masan Bay, using the three-dimensional numerical hydrodynamic model and the material cycle model.
The material cycle model was calibrated with the data obtained on the field of the study area in June 1993. The nutrients mass balance calculated by the combination of the residual currents and material cycle model results showed nutrients of surface and middle levels to be transported from the inner part to the outer part of Masan Bay, and nutrients of bottom level to be transported from outer part to inner part of Masan Bay. The uptake rate of DIN in the box A1(surface level of inner part) was found to be 337.5㎎/㎥ ·day, the largest value in all 9 boxes and that of DIP was found to be 18.6㎎/㎥·day in box A1, and the regeneration rate of DIN was found to be 78.2㎎/㎥· day in the box A3(bottom level of inner part), and that of DIP was found to be 18.6㎎/㎥· day in box A1. The regenerations of DIN and DIP in the water column of the entire Bay were found to be 7.66ton/day and 760㎏/day, respectively. And the releases of DIN and DIP from the sediments of the entire Bay were found to be 2.86ton/day and 634㎏/ day, respectively. The regeneration rate was 2.5 times as high as the release rate in DIN, and 1.2 times in DIP.
The results of mass balance calculation showed not only the nutrients released from the sediments but the nutrients regenerated in water column to be important in the control and management of water quality in Masan Bay.
13.
1998.12
서비스 종료(열람 제한)
In order to manage the water quality from the flowing streams in Cheju Island, the characteristics of water quality was investigated from August, 1996 to May, 1997 and the pollutant loadings for future were estimated from the watershed at each stream.
Comparing the mean concentrations of each water quality with the criterion of water quality in river, it was under I class except for Changgo Stream, for DO, under I class at the whole station for SS and under Ⅱ class for BOD.
As the pollutant loadings at each stream in 2020 is compared with those in 1996, the estimated results are as follows : 1) for BOD, 59% at Donghong Stream, 24% at Yeonoe Stream, 44% at Ohngpo Stream and 57% at Changgo Stream. 2) for T-N, 91% at Donghong Stream, 76% at Yeonoe Stream, 63% at Ohngpo Stream and 89% at Changgo Stream. 3) for T-P, 69% at Donghong Stream, 42% at Yeonoe Stream, 45% at Ohngpo Stream and 73% at Changgo Stream
The point source loadings discharged through combined sewer could be treated at sewage treatment plant. However, the expected slow decreasing rate of BOD, T-N, and T-P loadings is due to the part of untreated nonpoint source loadings. Nonpoint source loading overflow typically occurs when the flow of stormwater combined with sewage exceeds the capacity of the interceptor sewers. Since most of the sewers used in Cheju Island are the combined sewers, the combined overflow sewage is bypassed into the receiving water area after a rainstorm. Therefore, a means to control nonpoint source loadings should be considered for the river and marine water quality management.
14.
1998.12
서비스 종료(열람 제한)
Purification of the isocitrate lyase extracted from Microbacterium laevaniformans was investigated. The isocitrate lyase was purified 43.6 folds by the following continuous treatment with ammonium sulfate fraction, DEAE-cellulose, DEAE-sephacel and Sephadex G-200 chromatography. The purified isocitrate lyase was showed to be a single protein band by polyacrylamide gel electrophoresis. The molecular weight of the purified isocitrate lyase was estimated 54,000 Da by the SDS-polyacrylamide gel electrophoresis. The Km and Vmax values for isocitrate were estimated to be 0.83mM and 0.33units/㎖, respectively. Activity of isocitrate lyase was inhibited by cystein-HCl and glutathione.
15.
1998.12
서비스 종료(열람 제한)
The analysis of groundwater quality in Kyungnam Province was conducted using monitoring results obtained during 1994. According to the analysis, most heavy metals and pesticides listed in Korean drinking water standards were not detected in Kyungnam Province groundwater, but arsenic and volatile organics such as TCE and PCE were detected. Four inorganic contaminants were detected and frequency of violating the standards was in order of NO_3-N, F^+, As, NH_3-N. Of organics, TCE and PCE were the only contaminants detected. TCE more frequently violated the standards than PCE. Correlation was investigated among contaminants detected in Kyungnam Province groundwater. The correlation results showed that high correlation existed among dissolved solids, hardness, and SO_4^2-.
16.
1998.12
서비스 종료(열람 제한)
17.
1998.12
서비스 종료(열람 제한)
18.
1998.12
서비스 종료(열람 제한)
-연구노트-
19.
1998.12
서비스 종료(열람 제한)
