간행물
한국환경과학회지 KCI 등재 Journal of Environmental Science International
- 발행기관 한국환경과학회
- 자료유형 학술지
- 간기 월간
- ISSN 1225-4517 (Print)2287-3503 (Online)
- 수록기간 1992 ~ 2023
- 주제분류 자연과학 > 자연과학일반 자연과학 분류의 다른 간행물
- 십진분류KDC 539DDC 628
권호리스트/논문검색
제15권 제3호 (2006년 3월) 12건
1.
2006.03
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Advanced oxidation processes involving O3/H2O2 and O3/catalyst were used to compare the degradability and the effect of pH on the oxidation of 1,4-dioxane. Oxidation processes were carried out in a bubble column reactor under different pH. Initial hydrogen peroxide concentration was 3.52 mM in O3/H2O2 process and 115 g/L (0.65 wt.%) of activated carbon impregnated with palladium was packed in O3/catalyst column.
1,4-dioxane concentration was reduced steadily with reaction time in O3/H2O2 oxidation process, however, in case of O3/catalyst process, about 50～75% of 1,4-dioxane was degraded only in 5 minutes after reaction. Overall reaction efficiency of O3/catalyst was also higher than that of O3/H2O2 process.
TOC and CODCr were analyzed in order to examine the oxidation characteristics with O3/H2O2 and O3/catalyst process. The results of CODCr removal efficiency and ΔTOC/ΔThOC ratio in O3/catalyst process gave that this process could more proceed the oxidation reaction than O3/H2O2 oxidation process. Therefore, it was considered that O3/catalyst advanced oxidation process could be used as a effective oxidation process for removing non-degradable toxic organic materials.
2.
2006.03
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In predicting oxidants concentration, the most important fact is to select a suitable photochemical reaction mechanism. Sensitivity analysis of O3 and other important photochemical oxidants concentrations was conducted by using CBM-IV model.
The predicted oxidants concentration was considerably related with the initial concentration of formaldehyde, [NO2]/[NO],NOx, RH and RCHO. As the initial concentration of formaldehyde increased, concentration of NO2 increased. O3 concentration was proportional to the [NO2]/[NO] ratio. When the initial concentrations of RH and RCHO were high, photochemical reaction was more reactive, including more rapid conversion of NO to NO2 and increased oxidants. Also, the sensitivities of ozone formation to rate constants, Kl,K2andK3 in the NO2 photolysis were studied.
3.
2006.03
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An experimental study on the removal of VOCs gas using a biomembrane reactor were carried out at various inlet gas concentration, specific loading rate, retention time and gas flow rate of volume.
The variations of efficiency and various parameters, which are relevant to gas removal, with mixing of soluble gas and without have been discussed. More than 95% of the toluene and methanol present in the feed was successfully removed in each study.
The elimination of methanol with mixture of soluble compound of about 300 mg/h corresponds to a portion of 21 % if there is a feed stream of 1400 mg/h.
On the contrary the maximum efficiency of about 72% of toluene was reached. This is to be rated as a treatment of sorption that the limiting factor of the dismantling speed could be represented by this difficult degradable component. Nevertheless the elimination capacities for this reactor for toluene were on a very high level.
For substances which show a very high solubility in silicon rubber an advantage of a bio membrane is clearly shown. Therefore a similarly good result is expected for n-hexane, because of its relatively good permeability which was distinguished during permeation experiments.
4.
2006.03
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Oxidative TCE decomposition over TiO2-supported single and complex metal oxide catalysts has been conducted using a continuous flow type fixed-bed reactor system. Different types of commercial TiO2 were used for obtaining the supported catalysts via an incipient wetness technique. Among a variety of titanias and metal oxides used, a DT51D TiO2 and CrOx would be the respective promising support and active ingredient for the oxidative TCE decomposition. The TiO2-based CrOx catalyst gave a significant dependence of the catalytic activity in TCE oxidation reaction on the metal loadings. The use of high CrOx contents for preparing CrOx/TiO2 catalysts might produce Cr2O3 crystallites on the surface of TiO2, thereby decreasing catalytic performance in the oxidative decomposition at low reaction temperatures. Supported CrOx-based bimetallic oxide systems offered a very useful approach to lower the CrOx amounts without any loss in their catalytic activity for the catalytic TCE oxidation and to minimize the formation of Cl-containing organic products in the course of the catalytic reaction.
5.
2006.03
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Organophosphorus pesticides (OPPs) contents in the sewage sludge derived from the residential and industrial areas were determined in order to characterize contemporary organic contamination levels as a part of the ongoing development of the environmentally sound sewage sludge management strategy in Korea. OPPs were extracted from freeze-dried sludges in a ultrasonic extractor. The extracts were cleaned-up by florisil column and subsequently fed into gas chromatograph/nitrogen phosphorus detector (GC/NPD) for determining OPP contents. Diazinon, dimethoate, disulfoton, EPN, malathion, methyl parathion, parathion, phorate and sulfotep were present in the appreciable amount in the domestic sewage sludges. The sum of the 9 OPPs in the sewage sludge varied from 534.8 to 15552.1 ㎍/kg, dry wt..
6.
2006.03
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The purpose of this research was to investigate the efficiency of coagulants dose after backwashing. The turbidity of initial effluent was high after backwashing in the rapid sand filtration and the high turbidity was almost removed by coagulants dose into filter-sand after backwashing. It was found that the turbidity of initial effluent was well removed by all kinds of the coagulants used in this study.
When filtration was performed input water with differentiated pH's, the turbidity of effluent was low at the range of pH 5 - pH 7. But the removal was not good about over pH 9. This result was considered into the existence forms of aluminium, Al(OH)2+ and Al(OH)2+ at pH 5.
Cryptosporidiums of effluent were 4/ml for ten minutes immediately after back washing and 3/ml until sixty minutes. However, the case of coagulant dose after backwashing, Cryptosporidiums of effluent were 0.5/ml for ten minutes with no detection after twenty minutes.
7.
2006.03
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The emergy concept was used to valuate the contributions of a tidal flat ecosystem included in the fourth stage reclamation plan for the Youngsan River area to the Korean economy. Emergy contributions of the ecosystem were compared with those of economic valuations performed on the same ecosystem. The tidal flat ecosystem contributed 3.55 million Em\/ha annually. This, however, cannot be compared directly with those of the economic valuations because both methodologies approach the valuation of ecosystems in different perspectives. The emergy methodology is a donor-based valuation in which what goes into making a product or service is measured, while the economic valuation is a receiver-based approach in which human receivers determine the value of an ecosystem product or service.
An emergy valuation was conducted for the three ecosystem functions included in the economic valuations to compare the results of both methodologies on the same basis. Fishery production and pollutants removal contributed 9.86 million Em\/ha/yr and 0.88 million Em\/ha/yr, respective1y. The conservation value of the tidal flat ecosystem was 3.55 million Em\/ha/yr. Overall, the emergy valuation that try to include works of both human and nature on the same basis resulted in higher economic contribution of the tidal flat ecosystem than that calculated by the economic methodologies in which only human works are measured based on the willingness-to-pay of people.
This study showed that the emergy concept could provide an alternative tool for policy decision-making regarding utilization and conservation of ecosystems by approaching the ecosystem valuation from a different perspective than that of economic methodologies.
8.
2006.03
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Groundwater recharge from precipitation is affected by the infiltration from ground surface and the movement of soil water. Groundwater recharge is directly related to the groundwater amount and flow in aquifers, and baseflow to rivers. Determining groundwater recharge rate for a given watershed is a prerequisite to estimate sustainable groundwater resources. The estimation of groundwater recharge rate were carried out for three subwatersheds in the Wicheon watershed and two subwatersheds in the Pyungchang River basin and for the period 1990-2000, using the NRCS-CN method and the baseflow separation method. The recharge rate estimates were compared to each other. The result of estimation by the NRCS-CN method shows the average annual recharge rate 15.4-17.0% in the Wicheon watershed and 26.4- 26.8% in the Pyungchang River basin. The average annual recharge rates calculated by the baseflow separation method ranged 15.1-21.1% in the Wicheon watershed, and 25.2-33.4% in the Pyungchang River basin. The average annual recharge rates calculated by the NRCS-CN method is less variable than the baseflow separation method. However, the average annual recharge rates obtained from the two methods are not very different, except NO. 6 subwatershed in Pyungchang River basin.
9.
2006.03
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In this study, an optimization technique was developed from the application of allocation rule. The results obtained from the water supply analysis and reliability indices analysis of Andong dam and Imha dam which are consist of parallel reservoir system are summarized as the followings;
Allocation rule(C) is effective technique at the parallel reservoir system because results of the water supply analysis, storage analysis and reliability indices analysis is calculated reasonable results. Also, reliability indices analysis results are not sufficient occurrence based reliability or quantity based reliability. Thus reliability indices analysis are need as occurrence based reliability, quantity based reliability vulnerability, resilience, average water supply deficits and average storage. And water supply condition is better varying water supply condition than constant water supply condition.
10.
2006.03
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To investigate the variations of physico-chemical factors and microbial population, in ten stations at water region of coastal area of Chagwi-Do, Nutritive salts, water temperature, transparency, suspended solid, salinity, COD, DO, pH, heterotrophic bacteria, coliform group and Vibrio spp. were analysed three times in September, November in 2004 and February in 2005.
Heterotrophic bacteria in surface water was 3.5×101～1.16×103 cfu/ml, 1.0×102～5.2×101 cfu/ml, 2.0×101～7.6×101 and bottom water counted 7.0×102～1.0×103 cfu/ml, 1.4×101～2.5×102 cfu/ml, 2.0×102～4.2×101 cfu/ml in September, November in 2004 and February in2005, respectively. The cell number of total coliform bacteria in the surface water amounted to 0～4.3×102 cfu/ml, 0～6.0×101 cfu/ml, 0～1.0×101 cfu/ml and bottom water amounted 0～2.2×102 cfu/ml, 0～5.4×102 cfu/ml, 0～2.0×101 cfu/ml in September, November in 2004 and February in 2005, respectively. As for Vibrio spp., the cell number in the surface water was 1.0×101～2.5×102 cfu/ml, 1.0×101～2.0×101 cfu/ml, 0 cfu/㎖ and bottom water counted 1.0×101～5.2×102 cfu/ml, 0 cfu/㎖, 2.0×101 cfu/ml in September, November in 2004 and February in 2005, respectively.
11.
2006.03
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Electrokinetic technique was considered in removing arsenic from the abandoned mining tails. In order to estimate the removal characteristics of arsenic, the sequential extraction analysis and desorption experiment were carried out prior to the application of electrokientic process.
The result of sequential extraction analysis indicated that the water soluble and exchangeable fraction, easily leachable to ground water, were very low as much as about 2.5% and the fraction except residual (38.3%), possibly extractable under very acidic or alkalic environment, was about 59%.
In the result of desorption test using four different kinds of electrolytes, the mixture of citric acid and sodium dodecyl sulfate (SDS) showed the highest desorption efficiency as much as 77.3%. The removal efficiencies of arsenic from mining tailings by electrokinetic process under the different electrolyte environments were slightly low and resulted in the following order: citric acid + SDS (18.6%) > 0.1 NHNO3 (8.1%) > HAc (7.4%) > Distilled water(6.6%). Also, arsenic in soil matrix was moved favorably in the direction of anodic rather than cathodic region, which is opposite trend with cationic metal ions generally existing in soil, because anionic form of arsenic is dominated in acidic soil caused by the movement of acid front form anode.
12.
2006.03
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The purpose of this paper is to evaluate the noise level and source, reduce the subway lineⅡ noise. As a result of measurement of subway line Ⅱ in Busan the highest value section of uproad line was from Jigegol to Motgol by 89 dB(A). The sections of conversation and listening interference(over 80 dB(A)) were 21 sections(55%) of 38 sections. Among these sections, 15 sections(71%) were produced rolling noise, 3 sections(14%) squeal noise, 2 sections(10%) braking noise and 1 section(5%) fan noise, and then a main noise source was the rolling noise.
In case of downroad line, the highest value section was from Busan Metro Art Museum to Centum city, Motgol to Jigelgol by 88 dB(A). The sections of conversation and listening interference(over 80 dB(A)) were 18 sections(47%) of 38 sections. Among these sections, 15 sections(83%) produced rolling noise, 2 sections(11%) squeal noise and 1 section(6%) braking noise were investigated in this study. and then a main noise source was the rolling noise.
