The characters of Castanea crenata community which is associated with human activities recently extended around the field of Saengbiryang-myeon at Sanseong-gun in Gyeongsangnam-do. The C. crenata community and its outskirts were investigated for several ecological parameters and the results can be summarized as fellows. C. crenata is prevailing in the plantation area, whereas Pinus densiflora and Quercus mongolica are prevailing in its outskirts. The mean species diversity of plantation was lower than that of natural forests. In stratification of investigated areas, overstory tree layer was dominant in the zone of plantation and dominant layers in the natural forest were understory tree layer, shrub, and herb. Plant biomass and net production which estimated from degree of green naturality were much higher in natural forests than those of the plantation community. Least significant differences (LSD) post hoc analysis revealed that P. densiflora and Q. mongolica community had significantly greater than densities than C. crenata community
Simultaneous removal of NH3, H2S and toluene in a contaminated air stream was investigated over 185 days in a biofilter packed with Zeocarbon granule as microbial support. In this study, multi-microorganisms including Nitrosomonas and Nitrobacter for nitrogen removal, Thiobacillus thioparus (ATCC 23645) for H2S removal, and Pseudomonas aeruginosa (ATCC 15692), Pseudomonas putida (ATCC 17484) and Pseudomonas putida (ATCC 23973) for toluene removal were used simultaneously. The empty bed residence time (EBRT) was 40-120 seconds and the feed (inlet) concentrations of NH3, H2S and toluene were 0.02-0.11, 0.05-0.23 and 0.15-0.21 ppmv, respectively. The observed removal efficiency was 85%-99% for NH3, 100% for H2S, and 20-90% for toluene, respectively. The maximum elimination capacities were 9.3, 20.6 and 17 g/m3/hr for NH3, H2S and toluene, respectively. The results of kinetic model analysis showed that there were no particular evidences of interactions or inhibitions among the microorganisms, and that the three biodegradation reactions took place independently within a finite area of biofilm developed on the surface of the Zeocarbon carrier.
Artichoke extracts are widely used alone or in association with other herbs for embittering alcoholic and soft drinks and to prepare herbal teas or herbal medicinal products in Viet Nam. The objective of this paper was a screening of flavonoids and total phenolic compounds content in the parts of artichoke (Cynara scolymus L.) as flowers, leaves, roots, trunks, stumps. The total phenolic compounds and flavonoids in the parts of artichoke were extracted among 3 extraction methods as methanol extraction (EM1), mixing methanol and water method (EM2) and water extraction method (EM3). Total phenolic compounds and flavonoids were determined by UV/VIS, HPLC techniques. The apigenin 7-O-glucosides, cynarin, narirutin, gallic acid, caffeic acid were found as the main flavonoids constituents in all parts of artichoke. It showed that value of total phenolic compounds and flavonoids by EM3 were higher than that of total phenolic compounds and flavonoids by EM1 and EM2. Furthermore, the results of this study revealed that total phenolic compounds and flavonoids, obtained by these convenient extraction methods, may show the quick efficacy of artichoke in all respects of their quality and quantity.
A large amount of 2.1×106 m3 of polluted sediment was dredged from the Masan Bay and deposited in Gapo confined area, Masan, Korea. The six representative sediments were obtained and analyzed for issue components. The data was discussed with the species of benthos and their distribution. It was judged that toxicological effects of sediment analyzed ranged from ERL to ERM with copper and zinc, and ERL with cadmium, chrome, lead and nickel by the Adverse Biological Effects. The dredging index (DI) of sediments stabilized for 10 years since dumping the confined site was calculated and compared with the DI values of dredged sediment itself. DI values decreased from 0.67 to 0.07 ~ 0.18, which reflects DI value less than 0.2 is good for benthos in the sediment by the natural recovery of dredged materials. The ecological recovery was confirmed in this confined area as a habitat of benthic organisms.
The electro-chemical decolorization of Rhodamine B (RhB) in water has been carried out by electro Fenton-like process. The effect of distance, material and shape of electrode, NaCl concentration, current, electric power, H2O2 and pH have been studied. The results obtained that decrease of RhB concentration of Fe(+)-Fe(-) electrode system was higher than that of other electrode system. The decrease of RhB concentration was not affected electrode distance and shape. Decolorization of electro Fenton-like reaction, which was added H2O2 onto the electrolysis using electrode was higher than electrolysis. Addition of NaCl decreased the electric consumption. The lower pH is, the faster initial reaction rate and reaction termination time observed.
This study was to assess the lifetime cancer and non-cancer risk of exposure of worker and user at public facilities in Korea to volatile organic compounds (VOCs). We measured the concentrations of two aldehydes and five VOCs in indoor air at 424 public buildings that 8 kinds of public facilities (70 movie theaters, 86 offices, 86 restaurants, 70 academies, 22 auditoriums, 30 PC-rooms, 30 singing-rooms and 30 bars) all over the country. There were estimated the human exposure dose and risks with averages of the using-time and frequency for facility users and office workers, respectively. Carcinogens (formaldehyde, acetaldehyde, and benzene) were estimated the lifetime excess cancer risks (ECRs). non-carcinogens (toluene, ethylbenzene, xylene, and styrene) were estimated the hazard quotients (HQs). The average ECRs of formaldehyde and benzene for facility worker and user were 1×10-3~1×10-4 and 1×10-4~1×10-5 level, respectively, in all facilities. HQs of four non-carcinogens did not exceed 1.0 for all subjects in all facilities. The estimated ECRs for restaurant and auditorium were the highest, and the PC-room and bar were the next higher facilities. Furthermore, people in a smoking facility had the highest cancer risk. Higher ECRs of formaldehyde and benzene were observed in indoor smoking facilities such as restaurant and auditorium. Higher HQs of toluene and xylene were observed at the restaurant and office building.
The frequency analysis and the probability plot were applied to heavy metal contents of soils collected from the Goseong Cu mine area as a statistic method for the determination of the threshold value which was able to partition a population comprising largely dispersed heavy metal contents into the background and the anomalous populations. Almost all the heavy metal contents of soil showed a positively skewed distributions and their cumulative percentage frequencies plotted as a curved lines on logarithmic probability plot which represent a mixture of two or more overlapping populations. Total Cu, Pb and Cd data and extractable Cu and Pb data could be partitioned into background and anomalous populations by using the inflection in each curve. The others showed a normally distributed population or an largely overlapped populations. The threshold values obtained from replotted frequency distributions with the partitioned populations were Cu 400 mg/kg, Pb 450 mg/kg and Cd 3.5 mg/kg in total contents and Cu 40 mg/kg and Pb 12 mg/kg in extractable contents, respectively. The thresholds for total contents are much higher than the tolerable level of soil pollution proposed by Kloke(Cu 100 mg/kg, Pb 100 mg/kg, Cd 3 mg/kg), but those for extractable contents are not exceeded the worrying level of soil pollution proposed by Ministry of Environment(Cu 50 mg/kg, Pb 100 mg/kg). When the threshold values were used as the criteria of soil pollution in the study area, 9~19% of investigated soil population was in polluted level. The spatial distributions of heavy metal contents greater than threshold values showed that polluted soils with heavy metals are restricted within the mountain soils in the vicinity of abandoned mines.
Adsorption process is largely influenced by pore structures of adsorbents and physical properties of adsorbates and adsorbents. The previous studies of this laboratory was focused on the role of pore structures of adsorbents. And we found some pores of adsorbates which have larger pore diameters than the diameter of adsorbate are filled with easily. In this study the effects of physical and chemical properties of adsorbates and adsorbents, such as pore size distribution, vapor pressure on adsorption were investigated more thoroughly at the concentration of adsorbate of 1000 ppm. The adsorption in the pore ranges of 2~4 times of adsorbates's diameter could be explained by space filling concept. But there was some condensation phenomena at larger pore ranges. The errors between the adsorbed amount of non-polar adsorbates and the calculated amounts by considering factors were found to be 44.46%, positively, and -142%, negatively. When vapor pressure is considered, the errors between the adsorbed amount of non-polar adsorbates and the calculated amounts were in the range of 1.69%~32.25% positively, and negatively -1.08%~-63.10%.
The purpose of this study was to develop the national park visitor counting system using the ubiquitous sensor network. This system is composed of a sensor node, sink node, gateways, CDMA module, server, and clients. The results of the study were: 1) stable data transmission distance was possible within 100 meters between sensor nodes, 2) the developed counting sensor system showed a network communication stability level of 88.3 percent in 1.2m wide trails. When installed in concentrate use areas or forks of national parks, the visitor counting system will not only contribute to provide reliable visitor counting, but also to improve the quality of national park visitor service, to manage park facilities and natural resources more efficiently, to achieve an information oriented national park system.
Temporal and spatial variabilities of chlorophyll a (Chl-a) in the northern East China Sea (ECS) are described, using both 8-day composite images of the SeaWiFS (Sea-viewing Wide Field-of-view Sensor) and in-situ data investigated in August and September during 2000-2005. Ocean color imagery showed that Chl-a concentrations on the continental shelf within the 50 m depth in the ECS were above 10 times higher than those of the Kuroshio area throughout the year. Higher concentrations (above 5 mg/m3) of yearly mean Chl-a were observed along the western part of the shelf near the coast of China. The standard deviation also showed the characteristics of the spatial variability near 122-124°E, where the western region of the East China Sea was grater than that of the eastern region. Particularly the significant concentration of Chl-a, up to 9 mg/m3, was found at the western part of 125°E in the in-situ data of 2002. The higher Chl-a concentrations of in-situ data were consistent with low salinity waters of below 30 psu. It means that there were the close relationship between the horizontal distribution of Chl-a and low salinity water.
This study examined the contaminated soils with an indicator of TPH using SVE (Soil Vapor Extraction) and biological treatments. Their results are as follows.
Water content in the polluted soils slowly decreased from 15% during the initial experimental condition to 10% during the final condition. Purification of polluted soils by Bioventing system is likely to hinder the microbial activity due to decrease of water content. Removal rate of TPH in the upper reaction chamber was a half of initial removal rate at the 25th day of the experiment. The removal rate in the lower reaction chamber was 45% with concentration of 995.4 mg/kg. When the Bioventing is used the removal rate at the 14th day of the experiment was 53%, showing 7 day shortenting. Since the Bioventing method control the microbial activity due to dewatering of the polluted soil, SVE mehtod is likely to be preferable to remove in-situ TPH. The reactor that included microbes and nutrients showed somewhat higher removal rate of TPH than the reactor that included nurtients only during experimental period. In general, the concentration showed two times peaks and then decreased, followed by slight variation of the concentration in low concentration levels. Hence, in contrast to SVE treatment, the biological treatment tend to show continuous repetitive peaks of concentration followed by concentration decrease.
A study on the enhancement of environmental durability of EPDM rubber materials for the aerator membrane was performed using a butyl rubber as a modifier. A conventional EPDM rubber formulation was evaluated as having about 26.0 wt% or more oil content from the chloroform immersion test. These oils would be gradually and continuously deleted from the aerator membrane when directly exposed to a waste-water or chemically corrosive fluids, making the membrane less flexible and the performance worse. To improve this, a butyl rubber (IIR) was utilized as the modifier for a low-ENB type of EPDM rubber formulation with low-oil content. The environmental durability of the IIR-modified EPDM rubber material was expected to be greatly enhanced compared to the conventional one. However, the mechanical and performance properties such as elongation, tensile strength, and air bubble size, etc. were still maintained as good as in the conventional one. Furthermore, TGA analysis of the IIR-modified EPDM material showed that there would be partially compatible between IIR and EPDM. It also showed that the initial degradation temperature of the IIR-modified EPDM could be somewhat increased, exhibiting the enhanced compatibility among the components and, thereby, more enhanced environmental durability.
6~13 ㎎/L base water concentration on monthly BOD has been kept at the Geukrak bridge point for this research target and it indicates the water quality under the existed rank. Due to this present condition of water quality, the demage of ecology from the upper stream to the lower one of the bridge could be conjectured. Moreover, nonstructural extinction of the ecology seems to have gotten worse between both the streams of Yeoungsan River. On this research, eco-corridor between the upper stream and the lower stream of the river should be ensured, the ecological demage needs to be cut off, a dispersed discharge method which the existed method of the 1st sewage plant in Gwangju was enhanced to should be inducted for the procuring of various water ecosystem, and the conditions by the scenario suggested from this research could be applied to a water quality model. then, analysis the improvement effect of the water quality adjacent the river. From the test result, Case3-Type1 scenario is thought to be the best one. From the test result with Case3-Type1, when the concentrated discharge was never done, 0.07 mg/L of BOD concentration was increased at the lower stream where Yeoungbon B point (Haksan Bridge) is but the water improvement effect of 0.24~2.87 mg/L is thought to have been done at the area of water deterioration.
Laboratory analytical results of 22 sets of hydrophobic adsorbent coils containing surface soil-vapor and two soil samples collected by conventional intrusive method from each boring location at two active dry cleaning facilities in the State of Illinois, U.S.A, were presented to evaluate the performance of soil-vapor survey. The most critical factor to determine the effectiveness of soil-vapor survey is the distance from the soil-vapor sampling device to the actual contamination, which is a function of soil porosity, permeability, primary lithology, and other geological and hydrogeological site-specific parameters. Also this factor can be affected by the history of contaminant-generating operations. The laboratory analytical results in this study showed longer drycleaning operation history (i.e., 50 years) and presence of fine sand at the beneath Site B allow the contaminants to migrate farther and deeper over a fixed time compared to Site A(i.e., 35 years and silty clay) so that the soil-vapor survey is not likely the most effective environmental site investigation method alone for Site B. However, for Site A, the soil-vapor survey successfully screened the site to identify the location reporting the highest soil concentration of chlorinated solvents.
This study is an endeavor to evaluate the safety of medicines from heavy metals, prescribed on the basis of herbal medicinal system and oriental medical prescription which are circulated much recently. For that, three globular types, four extract granular types and four liquid types of herbal medicine were bought to compare and analyze the content of heavy metals, such as As, Pb, Cd and Hg, which are harmful to human body. The concentration of Pb was found to be 0.552 ppm in Sachiltang, 2.552 ppm in Anjungjogiwhan and 1.735 ppm in Cheongsangbohwawhan in case of pill type herbal medicine, and liquid type herbal medicine, Maekmundongtang was 0.002 ppm, Galgeuntang was 0.003 ppm, Sangwhatang was 0.004 ppm, 20jeon Daebotang was 0.0185 ppm. And the concentration of Pb was found to be 0.322 ppm in Banhasasimtang, 0.47 ppm in Eungjosan, 0.29 ppm in Yukmijihwangtang, 0.64 ppm in Socheongryongtang in case of granular type. It was found that the liquid types herbal medicines were relatively safer than three pill types of, four granular types of and four liquid types herbal medicines were tested for concentration of heavy metals. It is considered that is required in the stage of raw material treatment, manufacturing and packaging because those herbal medicines are directly taken in and absorbed into human body through the final treatment process.