간행물
한국환경과학회지 KCI 등재 Journal of Environmental Science International
- 발행기관 한국환경과학회
- 자료유형 학술지
- 간기 월간
- ISSN 1225-4517 (Print)2287-3503 (Online)
- 수록기간 1992 ~ 2023
- 주제분류 자연과학 > 자연과학일반 자연과학 분류의 다른 간행물
- 십진분류KDC 539DDC 628
권호리스트/논문검색
제16권 제3호 (2007년 3월) 15건
1.
2007.03
서비스 종료(열람 제한)
Polycyclic aromatic hydrocarbons (PAHs) are a major concern because of their potential mutagenic and carcinogenic risks to human beings. One of these harmful, yet commonly observed PAHs is pyrene. Pyrene is one of the 16 PAHs listed by the United States Environmental Protection Agency as priority pollutants. The purposes of this research are to develop a method of pretreatment for PAH contaminants prior to a typical biological treatment and to demonstrate the biodegradablity of these compounds. Since pyrene is non-polar, hexane was chosen as a solvent to effectively dissolve pyrene. Pyrene solutions were treated with ozone, as it has high oxidation capacity and electrophilic character. The intermediates and byproducts of pyrene were dissolved in alkaline water at pH 11.4 and neutralized to test for BOD5, COD, and toxicity. These solutions were further ozonated and assessed of biodegradability. The first-order rate constant ko was found to be between 0.121day-1 and 0.081 day-1, depending on the duration of reozonation. The BOD5/COD ratio was found to 0.66. The toxicity test showed that after 10 min of reozonation time, the byproducts and intermediates of pyrene were within the non-toxic range of ± 10% inhibition for E-Coli bacteria.
2.
2007.03
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The photocatalytic decolorization of Rhodamine B (RhB) was studied using packed-bed reactor and immobilized TiO2/UV System. The 20 W UV-A, UV-B and UV-C lamps were employed as the light source. The effect of shape and surface polishing extent of reflector, distance between the reactor and reflector, reactor material were investigated. The results showed that the order of the initial reaction constant with reflector shape was round > polygon > W > rhombus. The optimum distance between the reactor and reflector was 2 cm. The initial reaction constant of quartz reactor was 1.46 times higher than that of the PVDF reactor.
3.
2007.03
서비스 종료(열람 제한)
In this study, the Slab Ocean Model (SOM) is coupled with an Atmospheric General Circulation Model (AGCM) which developed in University of Kangnung based on the land surface model of Biosphere-Atmosphere Transfer Scheme (BATS). The purposes of this study are to understand radiative role of clouds considering of the atmospheric feedback, and to compare the Clouds Radiative Forcing (CRF) come from the analyses using the clear-cloud sky method and CGCM. The new CGCM was integrated by using two sets of the clouds with radiative role (EXP-A) and without radiative role (EXP-B). Clouds in this two cases show the negative effect -26.0 Wm-2 of difference of radiation budget at top of atmosphere (TOA). The annual global means radiation budget of this simulation at TOA is larger than the estimations (-17.0 Wm-2) came from Earth Radiation Budget Experiment (ERBE). The work showed the surface negative effect with -18.6 Wm-2 in the two different simulations of CRF. Otherwise, sensible heat flux in the simulation shows a great contribution with positive forcing of +24.4 Wm-2. It is found that cooling effect to the surface temperature due to radiative role of clouds is about 7.5℃. From this study it could make an accurate of the different CRF estimation considering either feedback of EXP-B or not EXP-A under clear-sky and cloud-sky conditions respectively at TOA. This result clearly shows its difference of CRF -11.1 Wm-2.
4.
2007.03
서비스 종료(열람 제한)
The standard emission rate(ERs) of isoprene was quantitatively measured in situ from Quercus mongolica Fischer that dominates more than about 85% of domestic oak trees. The ERs values in spring and summer were similar to 64.4 and 58.1 (㎍C/gdw/hr), respectively. The ERs in autumn, 7.06(㎍C/gdw/hr), was about 8～9 times lower than those in spring and summer. The coefficient of determination (r2) between ERs and CL․CT ranged from 0.593 to 0.836. The correlation coefficients between the ERs and PAR, the ER and temperature suggested that ERs have strong correlation with PAR(photosynthetically active radiation) and temperature. In addition, the high values of PAR, temperature, and ERs were found in the time zone of 15:00 ～17:00(spring), 15:00 ～ 16:00(summer), and 14:00 ～ 15:00(autumn).
5.
2007.03
서비스 종료(열람 제한)
The purpose of this study is to analyze seasonal distribution of insects, birds, fishes, and benthos for Gongji stream in Chuncheon and to explore some strategies towards creating a desirable close-to-nature stream. The number of species occurred in the study stream was 23 for butterflies and 149 for other insects, 23 for birds, 15 for fishes, and 47 for benthos. The study stream was dominated by Artogenia rapae, Polygonia caureum, Cyntia cardui for butterflies, and Passer montanus, Anas crecca, Anas platyrhynchos for birds. The dominant species were Rhynchocypris oxycephalus, Zacco platypus, Carassius auratus for fishes, and Limnodrilus sp. 2, Chironomus sp. 2, Hydropsyche KUb for benthos. Attracting insect species of higher density requires planting of host plant species and stabilization of plant coverage against disturbances. To enhance species diversity and density of birds, it is desirable to provide diverse habitats including preservation of downstream wetland and natural vegetation, creation of sand bars and islands with sand and gravel, and restriction of traffic passing and parking. Restoring fish and benthos habitats needs improvement of water quality, layout of gravels and stones on sand-dominant streambed, and use of close-to-nature revetment techniques.
6.
2007.03
서비스 종료(열람 제한)
Increasing carbon dioxide emissions from fossil fuel use and land-use change has been perturbing the balanced global carbon cycle and changing the carbon distribution among the atmosphere, the terrestrial biosphere, the soil, and the ocean. SGCM(Simple Global Carbon Model) was used to simulate global carbon cycle for the IPCC emissions scenarios, which was six future carbon dioxide emissions from fossil fuel use and land-use change set by IPCC(Intergovernmental Panel on Climate Change). Atmospheric CO2 concentrations for four scenarios were simulated to continuously increase to 600～1050ppm by the year 2100, while those for the other two scenarios to stabilize at 400～600ppm. The characteristics of these two CO2-stabilized scenarios are to suppress emissions below 12～13 Gt C/yr by the year 2050 and then to decrease emissions up to 5 Gt C/yr by the year 2100, which is lower than the current emissions of 6.3±0.4 Gt C/yr. The amount of carbon in the atmosphere was simulated to continuously increase for four scenarios, while to increase by the year 2050～2070 and then decrease by the year 2100 for the other two scenarios which were CO2-stabilized scenarios. Even though the six emission scenarios showed different simulation results, overall patterns were such similar that the amount of carbon was in the terrestrial biosphere to decrease first several decades and then increase, while in the soil and the ocean to continuously increase. The ratio of carbon partitioning to the atmosphere for the accumulated total emissions was higher for the emission scenario having higher atmospheric CO2, however that was decreasing as time elapsed. The terrestrial biosphere and the soil showed reverse pattern to the atmosphere.
7.
2007.03
서비스 종료(열람 제한)
It will be necessary to make proper management plans to preserve the air quality in good level for the public. In order to make these plans, source information and detail emission inventories of the city and near industrial areas should be given. However, lack of the source measurements data makes us more difficult to complete the source inventory. VOC source inventory could be utilized for the feasibility study to estimate the contribution of VOC sources presenting to the receptor such as residential area. It may give policy maker an idea how to control the air quality, and improve their social environment in the area. This study shows data that measured VOCs concentrations from the local industrial areas in Jeonju during from May 2005 to January 2006. The samples were collected from the near sources in 7 major factories in the industrial park as well as 5 general sources in near city Jeonju area to elucidate the abundances of speciated VOCs and their spacial and temporal distributions depending on source bases. Industrial sources are as follows; chemical, food, paper, wood, metal, non-metal (glass), and painting (coating) industries. The 5 general sources are sampled from tunnel, gasoline gas station, dry cleaning shop, printing (copy) shop, and road pavement working place in urban area. To understand the near source effect at receptor, samples from the 2 receptor sites (one is at center of the industrial complex and the other site is at distance residential area downwind from the center) were collected and analyzed for the comparison to source concentration. The mass contributions of the speciated VOC to total mass of VOCs measured from the different sources and ambient (2 receptors) were presented and discussed.
8.
2007.03
서비스 종료(열람 제한)
We have investigated coarse wind sectors in Busan metropolitan area and simulated detailed wind field using local atmospheric circulation model, RAMS in preceding studies (Part I, Part II). In this study, we divided and analyzed local wind sector in Busan according to the preceding results. We found that Busan metropolitan area is divided into 2 or 3 local wind sector in each coarse wind sector. The 9 coarse wind sectors were classified into 20 local wind sectors in total. But three local wind sectors were finally excluded because of these sectors were located on the complex hill area and the sea. Local wind sectors, therefore, in Busan metropolitan area were defined as 17 regimes. We assessed the location of air quality monitoring sites at Busan metropolitan area using the information of these wind sectors. Most of these were located at proper points, but 6 sites were placed at 3 local wind sectors as a couple and no site was set up at 3 other sectors. Hence the location of these sites was in need of rearrange.
9.
2007.03
서비스 종료(열람 제한)
Polycyclic aromatic hydrocarbons (PAHs) are well known for strong carcinogen. However, the human exposure anslysis of PAHs is quite difficult and unreliable because of hard for estimation of actual expose dose. Then urinary 1-hydroxypyrene (1-OHP) has been a biological marker of exposure to PAHs. The purpose of this study was to investigate total amount from exposure to PAHs acused by indoor occupational exposure, and residence at Seoul metropolitan area and Kyeonggi province in Korea. Thirty-five housewives were included in this study from April 2003 through February 2004. Dietary habit and general characteristics such as age, type of building, existence of passive smoking, period of residence, fuel type for heating and ventilation type were obtained by self administered questionnaire. Urine samples were collected at morning and freeze quickly. Urinary creatinine was measured for converting into 24 hr urine. Concentration of the indoor PAHs was examined by NIOSH method number 5506. Urinary 1-OHP and PAHs were analysed by HPLC. Correlation coefficient between urinary 1-OHP levels and pyrene concentration of indoor air was 0.66 and statistically significant(P<0.01). The difference of urinary 1-OHP level due to dietary habits were not significant. Urinary 1-OHP level of Spring, Summer, Autumn, and Winter were 0.21±0.12, 0.10±0.17, 0.16±0.12, 0.17±0.14 ㎍/g cr, respectively. The arithmetic means of urinary 1-OHP for four season wee 0.16±0.14 ㎍/g cr. There was a trend that urinary 1-OHP level of residents who dwelling in apartment were higher compared with detached home. Comparison of 1-OHP level between heating by kerosene and LPG, Much higher gas heating type than kerosene type (P<0.05). This result implies that the urinary 1-OHP can be applied as the PAHs exposure indices.
10.
2007.03
서비스 종료(열람 제한)
As analyzed the estimated values of the daily delivery loads from thirteen major side streams such as Naesung-river, Keumho-river, Hwang-river, Nam-river during five years (from 1999 to 2003), the daily BOD inflow into the main stream of Nakdong river in 2003 shows the highest quantity as 31.1 ton and the daily BOD inflows in 1999, 2000, 2001, and 2002 are 26.7 ton, 22.5 ton, 21.0 ton, 25.8 ton, respectively. The daily TN inflow into the main stream of Nakdong river in 2003 shows also the highest quantity as 64.9 ton and the daily TN inflows in 1999, 2000, 2001, and 2002 are 55.19 ton, 46.27 ton, 39.5 ton, 53.38 ton, respectively. The daily TP inflow into the main stream of Nakdong river in 2003 shows the highest quantity as 2.70 ton likewise and the daily TP inflows in 1999, 2000, 2001, and 2002 are 2.17 ton, 1.87 ton, 1.60 ton, 2.10 ton, respectively. The rate of BOD loads from each side main stream into the main stream of Nakdong river shows that the BOD loads of Keumho-river are the highest as the values range from 32.8 % (2002) ～ 35.1 % (2003) and the BOD loads of Nam-river, Naesung-river, Hwang-river are high in the order named. The rate of TN loads to the main stream is also similar to the trend of BOD loads. The contribution of the TN loads of Geumho-river to the contamination of the main stream is also the highest having a range from 27.0 % (2002) to 28.8 % (1999) among the main side streams and the TN loads of Naesung-river, Nam-river, and Heachun-river are high in the order named. The rate of TP loads is quite different from the trend of BOD and TN loads. The TP rate of Keumho-river, however, is still the highest as ranging 58.6 % (2002) to 61.7 % (2003) and the river has the biggest portion (over 50%) of the entire pollution to the main stream of Nakdong river.
11.
2007.03
서비스 종료(열람 제한)
In this paper, estimation of the compressive strength of the concrete incorporating blast furnace slag subjected to high temperature was discussed. Ordinary Portland cement and blast furnace slag cement (BSC;30% of blast furnace slag) were used, respectively. Water to binder ratio ranging from 30% to 60% and curing temperature ranging from 20℃～65℃ were also chosen for the experimental parameters, respectively. At the high temperature, BSC had higher strength development at early age than OPC concrete and it kept its high strength development at later age due to accelerated latent hydration reaction subjected to high temperature. For the strength estimation, the Logistic model based on maturity equation and the Carino model based on equivalent age were applied to verify the availability of estimation model. It was found that fair agreements between calculated values and measured values were obtained evaluating compressive strength with logistic curve. The application of logistic model at high temperature had remarkable deviations in the same maturity. Whereas, the application of Carino model showed good agreements between calculated values and measured ones regardless of type of cement and W/B. However, some correction factors should be considered to enhance the accuracy of strength estimation of concrete.
12.
2007.03
서비스 종료(열람 제한)
Recently, eutrophication or lake and reservoir has become serious problem to man who want use that water for several purpose. In order to solve the eutrophication problem, the trophic state of that eutrophic lake and reservoir should be measured properly. For the purpose of this, various method to indicate the trophic state of lake and reservoir was developed by many researchers. This research was conducted to evaluate characteristics and eutrophication of water qualitymfor small scale reservoir in Kunsan. On-site investigation to 5 reservoirs and laboratory experiment were carried out during four seasons from November, 2003 to July, 2004. Twelve items measured field ana a laboratory. Measured data was analyzed to quantitative method by multivariate approach and eutrophication index. The result is summarized as following. 1) Showing the characteristics of water quality for reservoir in Kunsan, Okgu reservoir and Oknua reservoir was exceeded 4 grades of agricultural water standard in TP, TN and COD. This means that eutrophication was gone much, therefore, water-purity control of reservoir need. While, Mije reservoir that is used to Kunsan citizens' recreation was good in water quality. But, water quality exceeded 4 grades of agricultural Dater standard sometimes. 2) As a results of correlation analysis between variables of water qualify, Interrelation between variables which is connected with eutrophication was expressed good relationship as above 6.000 in correlation coefficients. The correlation coefficient(r) between COD and chlorophyll-a, total phosphorus and chlorophyll-a, total nitrogen and chlorophyll-a were 0.750, 0.720 and 0.600 respectively. Therefore, Change of water quality can grasp according to eutrophication progress degree. 3) If do evaluate to eutrophication by quantitative method which is proposed by OECD, US-EPA and Forsberg & Ryding, in the case of chlorophyll a, Okgu, Oknua and Daewi reservoir was eutrophic state and Mije and Geumgul reservoir was mesotrophic state. But, estimation by TN and TP showed highly eutrophic state (hypereutrophic) in all reservoirs. 4) If do evaluate by eutrophication index which is Carlson's TSI, revised carlson TSI and Walker's index, in the case of chlorophyll a, TSI values of Okgu, Oknua and Daewi reservoir is eutrophic state more than 50 and Mije and Geumgul reservoir was mesotrophic state as range of 40∼50 in TSI value. But, in the case of TP as nutrients, all reservoirs showed highly eutrophic state which was exceed to 70 in TSI value. According to above results, the water quality for small scale reservoirs in Kunsan is progressing by trophic state. therefore, for continuous use as agriculture water, we had better do establishment of management plan about water quality.
13.
2007.03
서비스 종료(열람 제한)
This study was conducted to evaluate water quality in coastal sea of Kunsan using multivariate analysis. The analysis data in Coastal Sea of Kunsan use of surveyed data by the NFRDI from April 2000 to November 2002. Twelve water quality parameter were determined on each sample. The results was summarized as follow ; Water quality in coastal sea of Kunsan could be explained up to 62.782% by four factors which were included in loading of nitrogen-nutrients by Keum river(24.688%), suspended solids variation (12.180%), seasonal climate variation (18.367%) and variation of DIP (10.546%). To analyze spatially and monthly variation by factor score, it was divided by inner area and outer area spatially, and spring and summer monthly. The result of time series analysis by factor score, inner area of Kunsan coastal sea(St.1 and St. 2) was the most affected by nitrogen-nutrient and suspended solids due to runoff by Keum river. It could be suggested from these results that it is important to reduce the pollution loads from Kuem river for the control of the water quality in coastal sea of Kunsan.
14.
2007.03
서비스 종료(열람 제한)
In this study, the relationship between the pore size distribution and the adsorption amount of adsorbates is investigated in detail. Adsorption amounts of non-polar adsorbates were greater than those of polar adsorbates because of slight negative charge on surfaces of adsorbents. The adsorption of benzene on the surface of absorbents was largely influenced by the specific pore size of 2～4 times of benzene diameter. But in case of toluene, the adsorption of toluene was affected by pore sizes of 2～4 times as well as 4～6 times of the diameter of toluene. Both acetone and MEK were examined by the same method. The adsorption of acetone was influenced by pore sizes of 2～4 times of the diameter of acetone. But acetone does not look to be built up multi-layer on those pore sizes. Since acetone molecule is small and its mobility is so fast, it is assumed that the adsorption and desorption of acetone is simultaneously occurred at the same time even at room temperature. In case of MEK, MEK was effected by pore sizes of 2～4 times of the diameter of MEK.
15.
2007.03
서비스 종료(열람 제한)
Currently, portable equipment for recycling of waste asphalt concrete (ASCON) has been used. However, any air pollution control devices are not attached in the simple portable one. Thus, a lot of air pollutants have been produced from recycling processes of waste ASCON which resulted from aging of paved roads or repavement of roads. This study deals with a preliminary result of concentration analysis of air pollutants obtained from a pilot and a real recycling processes of waste ASCON using simple portable recycling equipment. Air pollutants were taken from 4 steps of the pilot recycling process including an initial heating by liquid petroleum gas (LPG), intermediate heating and melting (H&M) process, final H&M process, and pavement processes using recycled ASCON at the recycling site. Also, air pollutants were taken front 4 steps of the real recycling processes including an initial H&M, final H&M and mixing, loading of recycled ASCON to dump trucks, and at the recycling site after leaving the loaded dump trucks for real pavement sites. The air pollutants measured in this study include volatile organic compounds (VOCs), aldehydes, particulate matter (PM: PM1, PM2.5, PM7, PM10, TSP (total suspended particulate)). The identified concentrations of VOCs increased with increasing time or degree for H&M of waste ASCON. In particular, very high concentrations of the VOCs at the status of complete melting, which is exposed to the air, of the waste ASCON just before paving tv the recycled ASCON at the recycling site. Also, considerable amount of VOCs were identified from the recycling equipment after the dump trucks leaded by recycled ASCON leaved the recycling site for the pavement sites. The relative level of formaldehyde exceeded 80% of the aldehydes Identified in the recycling processes. This is because the waste ASCON is exposed to direct flame of LPG during H&M processes. The PM concentrations measured in the winter recycling processes, such as the loading and rotation processes of waste ASCON into/in the recycling equipment for H&M, were much higher than those in the summer ones. In particular, the concentrations of coarse particles such as PM7 and PM10 during the winter recycling were very high as compared those during the summer one.
