The photocatalytic decolorization of Rhodamine B (RhB) was studied using packed-bed reactor and immobilized TiO2/UV System. The 20 W UV-A, UV-B and UV-C lamps were employed as the light source. The effect of shape and surface polishing extent of reflector, distance between the reactor and reflector, reactor material were investigated. The results showed that the order of the initial reaction constant with reflector shape was round > polygon > W > rhombus. The optimum distance between the reactor and reflector was 2 cm. The initial reaction constant of quartz reactor was 1.46 times higher than that of the PVDF reactor.