Al2O3 has excellent sintering properties and is important in semiconductor manufacturing processes that require high-temperature resistance and chemical inertness in a plasma environment. In this study, a comprehensive analysis of the chemical characteristics, physical properties, crystal structure, and dispersion stability of three commercially available Al2O3 powders was conducted. The aim was to provide a technological foundation for selecting and utilizing appropriate Al2O3 powders in practical applications. All powders exhibited α-Al2O3 as the main phase, with the presence of beta-phase Na2O-11Al2O3 as the secondary phase. The highest Na+ ion leaching was observed in the aqueous slurry state due to the presence of the secondary phase. Although the average particle size difference among the three powders was not significant, distinct differences in particle size distribution were observed. ALG-1SH showed a broad particle size distribution, P162 exhibited a bimodal distribution, and AES-11 displayed a uniform unimodal distribution. Highconcentration Al2O3 slurries showed differences in viscosity due to ion release when no dispersant was added, affecting the electrical double-layer thickness. Polycarboxylate was found to effectively enhance the dispersion stability of all three powders. In the dispersion stability analysis, ALG-1SH exhibited the slowest sedimentation tendency, as evidenced by the low TSI value, while P162 showed faster precipitation, influenced by the particle size distribution.
본 연구는 최적의 냉해동 조건을 확립하고 설정된 조건에 따라 냉해동이 당근에 미치는 이화학적 분석 및 영양성분의 분석을 진행하였다. 본 실험에서는 강제송풍방식을이용하였으며, 자연대류식(0.2oC/min), 저속(0.4oC/min) 및고속(1.6oC/min)으로 냉동속도를 조절하여 -12oC까지 냉동하였다. 해동조건은 전자레인지를 이용하여 0, 200, 400,800W의 세기로 출력을 조절하여 시료의 중심부 온도가4oC가 될 때까지 해동하여 분석에 사용하였다. 당근의 강도는 냉해동 후 유의적으로 감소하는 경향을 보였으며, 특히 200, 400W 해동 시 냉동 속도가 빠를수록 감소하였다.해동감량의 경우 해동방법에 따른 유의적인 차이는 없었지만 냉동속도가 높을수록 감소하는 경향을 보였다. pH 및색도의 데치기 후 당근과 처리구간의 유의적인 차이는 보이지 않았다. 그러나 전자 현미경 관찰 결과, 냉동속도가빨라질수록 기공의 크기가 작아지는 것을 확인할 수 있었으며 이는 빠른 냉동속도가 식품 조직의 손상을 막는데 영향을 미친다는 것으로 보인다. 비타민 C 및 유기산(oxalicacid, malic acid 및 fumaric acid) 함량의 경우 유의적인차이는 나타나지 않았다. 유리당 함량의 경우에는 sucrose함량은 자연대류 냉동 시 가장 높았고, fructose 및 glucose의 함량은 유의적인 차이가 없었다. 본 연구 결과 냉해동방법에 따른 영양학적 변화는 대부분 데치기 후 당근과 유사하였으나, 당근을 고속으로 냉동할 시 물리적 변화 및조직 손상을 최소화 하였으므로 당근의 품질을 유지하는데효과적인 것으로 판단된다.
일본, 중국 등 인접 지진다발 국가에서 큰 지진동이 전파되어 오는 경우, Lg파가 최대 진폭을 갖게 되어 Lg파의 감쇠상수(Q-1)는 매우 중요한 의미를 갖게 된다. 지진연구협의회(IRIS)의 자료를 바탕으로 관측점간 경로거리가 긴 자료에 대하여 두관측점법을 이용하여 Lg파의 감쇠상수 값을 도출한 결과, 지진활동도에 상응하는 감쇠값을 얻었다. 일본지역을 잇는, 해양지각을 통과하는 경로는 높은 감쇠값을 보여서 지진활동도 및 지각의 감쇠특성을 잘 나타내고 있으며, 또한 큰 지진이 많았던 중국 상해지역을 잇는 경로도 일본지역 다음으로 높은 감쇠값을 보인다. 반면, 한반도 및 만주지역을 잇는 경로는 지진활동상황과 상응하는 매우 낮은 값을 보였다.
In this study, we used an electronic nose to measure odor intensity and odor quality against an absolute scale. The major feature of this device is that it automatically corrects for differences in sensor sensitivity and smell sensitivity due to odor quality, which allows the intensity of any odor quality to be determined at olfactory sensitivity. In addition to determining the odor intensity as an odor index value, in the standard mode, the device can determine the odor quality by separating and displaying the overall odor on nine category axes (sulfur, amines, organic acids, aldehydes, aromatics, esters, hydrocarbons, hydrogen sulfide and ammonia). This device achieves these results by subjecting the signals from the ten oxide-semiconductor odor-sensor elements to our unique absolute value representation analysis. This study applied electronic nose system of sensor type that can evaluate odor characteristics by real time in leather industry spot and investigated problem that can happen odor sensory method and instrumental analysis method. Also, by evaluation correlation between each measurement method, groped efficient odor evaluation method, and evaluated the effectiveness, Usually, because measurement surrounding and consistency according to measurer"s state of olfactory method are apt to be been lacking, error range is large. If take into account these problem, odor sensor"s result that examine in this research is judged that there is inter-relationship enough with olfactory method result. In comparison between odor sensory test result and instrument analysis result, odor characteristics estimation that can bring synergy effect more than equality in box judge.
본 연구에서는 노심지지배럴을 축솜형의 원통형 쉘로 이상화하여, 그의 모드 특성을 고찰하였다. 쉘의 모드 해석은 사용코드인 ANSYS를 이용하였으며, 일반적으로 사용하고 있는 요소인 SHELL61과 SHELL63을 이용하여 해석을 수행하였고 이들의 특성을 비교하였다. 또한 두께에 따른 모드 특성을 검토하여 쉘 요소의 사용 한계를 규정하였다. 한편 구멍이 있는 쉘과 없는 쉘의 모드 특성을 조사하여 구멍 및 그의 위치가 모드 특성에 미치는 영향을 파악하였다. 이들 모든 결과를 실험 및 이론에 의한 결과와 비교하였다.
이 논문은 압축성 유체로 채워진 원통형 탱크의 고유진동 특성을 파악하기 위한 해석적 방법을 제시하고 있다. 탱크의 동적거동은 유한 Fourier 급수전개 방법으로 전개하였으며, 압축성 유체는 선형 포텐셜 이론으로 전개하였다. 해석방법의 타당성을 검증하기 위하여 물로 채워진 양단고정의 경계조건을 갖는 원통형 탱크의 고유진동수를 해석적 방법으로 구한 다음, 상용 유한요소해석 프로그램인 ANSYS 5.2를 이용하여 검증하였다. 그 결과, 유한요소해석결과와 이론적인 방법으로 구한 이론해가 잘 일치하고 있음을 확인하였다. 또한 유체의 밀도와 압축성이 탱크의 고유진동수에 미치는 영향을 정규화된 무차원 고유진동수를 통해서 평가하였다. 유체의 밀도는 탱크의 모든 진동 모드의 고유진동수에 영향을 주지만, 유체 압축성의 영향은 저차 원주방향 모드의 진동수에서 더 크게 나타나고 있음을 확인할 수 있었다.
As the impacts of climate change have been emerged all the way through society, the potential risks specifically on agricultural water and facilities are recently getting concerned. Evaluating vulnerability of agriculture to climate change on is a time-tested strategy. While a number of researches on the adaption and mitigation of climate change were performed in various aspects for sustainable agricultural production, the vulnerability of management system for agricultural water and infrastructure has not been investigated yet. This study is aimed to clarify the definition of vulnerability to climate change, find the major indicators able to presume the vulnerability, and finally determine the relative importance of the indicators based on the specialist questionnaire survey and its analyses. The lists of indicators for major parts of agricultural water management such as, water use, flood control, reservoir related issues, and pumping and drainage systems are initialized referring to the related precedent studies. The primary survey was conducted in the form of Delphi to complement the list and methods and the main survey was then conducted using AHP(Analytic Hierarchy Process) technique to quantitatively prioritize the indicators. The results derived in this study would be directly adopted in weighting importance of indicators to investigate the indicator-based vulnerability analysis to climate change in agricultural water and infrastructure management.
Existing agricultural reservoirs are considered as alternative source for the water welfare of rural area. In this study, domestic water supply potential of 476 reservoirs, which has storage capacity more than one million cubic meter, out of 3,377 agricultural reservoirs managed by Korean Rural Community Corporation (KRC) were investigated. Among them water quality of 136 reservoirs met the criteria of domestic water source which show less than COD 3 ppm. Available amount for domestic water of reservoirs, which meet the water quality, for ten year return period of drought was analyzed with reservoir water balance model. The results showed that 116 reservoirs has potential for supplementary domestic water supply while satisfying irrigation water supply. Finally, economic analysis using Net Present Value (NPV), Benefit–Cost (B/C) ratio, Internal Rate of Return (IRR), and Profitability Index (PI) methods was also conducted. The analysis showed that 19 reservoirs satisfied economic feasibility when water is provided from reservoir outlet but only 9 reservoirs meet the economic feasibility if water delivered from a reservoir to treatment plant by newly built conveyance canal. In order to supply the domestic water through the agricultural reservoirs managed by KRC, it is necessary to flexibly interpret and operate the ‘Rearrangement of Agricultural and Fishing village Act’. Also, it is reasonable to participate in the water service business when there is a supply request from other Ministries. In addition, the KRC requires further effort to change the crop system for saving water and improve efficiency of irrigation systems.
이 논문은 南冥 曺植(1501-1572)의 4종 神道碑文 중 尤庵 宋時烈(1607-1689)의 「南冥曺先生神道碑銘」을 총체적으로 연구한 결과물이다. 한 명의 인물을 대상으로 당대 최고 문사들이 각각 신도비문을 남기고 그 작품들이 모두 현전하는 경우는 남명신도비문이 유일하다.
송시열이 찬술한 남명신도비문은 남명 조식 사후 100여 년 만에 찬술된 것으로 이전 정인홍ᆞ조경ᆞ허목 보다 학문적 연원이나 사승 관계가 멀다 할 수 있고, 오히려 사후 정치적 상황을 염두에 둔다면 조식과 송시열은 가장 대치적 관계에서 지어진 작품이다. 그러나 송시열은 정치적ᆞ학문적 입장을 뒤로하고 조식의 不朽한 功業과 序其爲人의 독특한 찬술자세로 남명신도비문을 찬술하였다.
송시열의 남명신도비문은 가장 비지문 창작이 왕성했던 60세 전후에 찬술된 작품이며 영남유림과 조식의 자손들 부탁으로 찬술되었음을 확인하였다. 특히 10년 전에 지어진 초고본을 다시 찾아 주변 지인들의 조언을 바탕으로 퇴고를 거듭 하며 남명신도비문에 많은 공력을 기울였다.
송시열은 조식의 공로에 대해 세 가지(①貴義賤利, ②可尙恬退’, ③可羞貪冒)로 요약했고 그의 성품에 대해서는 일화를 통해 간략하지만 강렬한 인상을 남도록 기술하였다. 조식의 출처관에 대해서는 이황의 말을 인용하며 미화로 여겨질 수 있는 여지를 남겨두지 않았다. 나아가 조식을 성리학자로 최고의 위상이라 할 수 있는 육군자의 반열과 병렬시킨 것은 송시열 이외에 어떤 사람도 하지 못한 일이며 당시 노론 영수로 후대까지 막강한 영향력을 행사했던 송시열에게 이루어졌다는 점이 주목할 만하였다. 송시열은 이황을 포함한 육군자는 조식의 위상과 차이가 없다 생각하였고 바로 이점으로 자신이 조식을 백세의 스승, 영원한 스승으로 삼았던 것이다. 당시까지 조식을 당파적 영수로 여겨왔다면, 송시열은 당파적, 정치적 외형에서 탈피하여 한 시대의 영원한 師表로 승화시켰다. 바로 이점이 기존 3종의 남명신도비문과의 변별점이며 송시열의 남명신도비문이 지닌 위상이라 할 수 있다.
The pilot plant experiment was performed to investigate phosphorus and nitrogen removal from domestic wastewater by MLE process combined with aluminum corrosion reactor. When operating 0.5Q and 1Q to internal recycle and sludge recycle in the MLE process, the effluent CODMn concentration of internal recycle 0.5Q were higher than internal recycle 1Q, the removal efficiency rates of NH3-N in the internal recycle 0.5Q were was higher than internal recycle 1Q. Denitrification rates were about 86.8% in internal recycle and sludge recycle 0.5Q. When operating 0.5Q to internal recycle and sludge recycle in the MLE process, the removal efficiency rates of total nitrogen was the highest. The removal efficiency rates of total phosphorus was about 91.5% in the aluminum corrosion reactor.
The present study was conducted to judge the applicability of field quality control by children's goods manufacturers by assessing the contents of heavy metals such as Pb and Cd in outdoor play goods for children through measurement using Portable XRF and comparing the results through detailed analyses using ICP. Heavy metal contents of 711 part samples of 505 products were measured using XRF. According to the results, the ratio of products that exceeded the Pb and Cd content standards specified under the Quality Management and Safety Control of Industrial Products Act were 2.4% and 2.6%.
Many products certified for self-regulated safety exceeded the standards and thus it was considered that harmful chemical material centered safety management systems would be necessary. Detailed ICP analyses of some products were compared and the results showed deviations of 0.9~80.8% from XRF results. The reasons for this are deviations in the characteristics of measured cross sections and the homogeneity of samples resulting from sample preparation methods, etc.
Therefore, it is considered that field quality control will be applicable if measuring methods are efficiently established based on product characteristics and calibration curve preparation methods are established through quality control.
This paper presents a sensitivity optimization of a MEMS (microelectromechanical systems) gyroscope for a magnet-gyro system. The magnet-gyro system, which is a guidance system for a AGV (automatic or automated guided vehicle), uses a magnet positioning system and a yaw gyroscope. The magnet positioning system measures magnetism of a cylindrical magnet embedded on the floor, and AGV is guided by the motion direction angle calculated with the measured magnetism. If the magnet positioning system does not measure the magnetism, the AGV is guided by using angular velocity measured with the gyroscope. The gyroscope used for the magnet-gyro system is usually MEMS type. Because the MEMS gyroscope is made from the process technology in semiconductor device fabrication, it has small size, low-power and low price. However, the MEMS gyroscope has drift phenomenon caused by noise and calculation error. Precision ADC (analog to digital converter) and accurate sensitivity are needed to minimize the drift phenomenon. Therefore, this paper proposes the method of the sensitivity optimization of the MEMS gyroscope using DEAS (dynamic encoding algorithm for searches). For experiment, we used the AGV mounted with a laser navigation system which is able to measure accurate position of the AGV and compared result by the sensitivity value calculated by the proposed method with result by the sensitivity in specification of the MEMS gyroscope. In experimental results, we verified that the sensitivity value through the proposed method can calculate more accurate motion direction angle of the AGV.
The adsorption behavior of nitrate nitrogen was investigated from aqueous solution using char prepared from oak chip. The removal rate of nitrate nitrogen was found to be dependent on temperature and it is increased as the temperature increase. Adsorption equilibrium data of nitrate nitrogen on oak char. reasonably fitted Langmuir and Freundlich isotherm models. The adsorption energy obtained from D-R model was 12.5 kJ/mole at 20℃ indicating an ion exchange process as primary adsorption mechanism. Thermodynamic parameters such as △Go,, △Ho, and △So were -23.76 kJ/mole, 26.1 kJ/mole and 89.7 J/K·mole at 20℃, respectively, indicated that the nature of nitrate nitrogen adsorption is spontaneous and endothermic.