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SiC-Al2O3 촉매를 이용한 CF4의 마이크로파 열분해 KCI 등재

Microwave Thermal Decomposition of CF4 using SiC-Al2O3

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한국환경과학회지 (Journal of Environmental Science International)
한국환경과학회 (The Korean Environmental Sciences Society)
초록

Tetrafluoromethane(CF4) have been widely used as etching and chemical vapor deposition gases for semiconductor manufacturing processes. CF4 decomposition efficiency using microwave system was carried out as a function of the microwave power, the reaction temperature, and the quantity of Al2O3 addition. High reaction temperature and addition of Al2O3 increased the CF4 removal efficiencies and the CO2/CF4 ratio. When the SA30 (SiC+30wt%Al2O3) and SA50 (SiC+50wt%Al2O3) were used, complete CF4 removal was achieved at 1000℃. The CF4 was reacted with Al2O3 and by-products such as CO2 and AlF3 were produced. Significant amount of by-product such as AlF3 was identified by X-ray powder diffraction analysis. It also showed that the γ-Al2O3 was transformed to α-Al2O3 after microwave thermal reaction.

목차
Abstract
 1. 서 론
 2. 재료 및 방법
 3. 결과 및 고찰
  3.1. 마이크로파 조사에 따른 분해온도 및 CF4 분해효율평가
  3.2. SA함량 및 분해온도에 따른 CO2 전환율
  3.3. 표면분석
 4. 결 론
 참 고 문 헌
저자
  • 최성우(계명대학교 환경과학과) | Sung-Woo Choi (Department of Environmental Science and Engineering, Keimyung University) Corresponding author